Laboratory Techniques in Chemistry
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Questions and Answers

What is the principle of dialysis?

  • Separation of colloidal particles based on electrical charges
  • Separation of particles based on their size and shape
  • Separation of particles based on their chemical properties
  • Separation of micromolecular impurities based on diffusibility (correct)

What is the purpose of stirring in dialysis?

  • To increase the concentration of colloidal particles
  • To change the pH of the solution
  • To decrease the concentration of micromolecular impurities
  • To maintain a high concentration gradient across the membrane (correct)

What is the main difference between dialysis and ultrafiltration?

  • Dialysis uses pressure while ultrafiltration uses suction
  • Dialysis is faster than ultrafiltration
  • Dialysis separates based on diffusibility while ultrafiltration separates based on size (correct)
  • Dialysis is used for colloidal particles while ultrafiltration is used for micromolecular particles

What is the purpose of the electric potential in electrodialysis?

<p>To accelerate the movement of ionic impurities through the dialyzing membrane (B)</p> Signup and view all the answers

What is the effect of electrical repulsion and particle adsorption on ultrafiltration?

<p>They decrease the correlation between particle and pore sizes (D)</p> Signup and view all the answers

Study Notes

Dialysis

  • Colloidal particles are too large to pass through membranes like collodion or cellophane, but smaller molecules can.
  • Dialysis separates micromolecular impurities from colloidal dispersions based on diffusibility.
  • Stirring is necessary to maintain a high concentration gradient across the membrane, which hastens the process.

Ultrafiltration

  • Uses pressure or suction to force solvent and small particles across a membrane while retaining larger colloidal particles.
  • Membrane filters with known pore sizes can determine colloid particle sizes.
  • Membrane permeability is influenced by factors like electrical repulsion and particle adsorption, affecting the correlation between particle and pore sizes.

Electrodialysis

  • Applies an electric potential to accelerate the movement of ionic impurities through a dialyzing membrane.
  • Enhances purification speed, termed electrodecantation, by concentrating charged colloidal particles on one side of the membrane.

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Description

This quiz covers laboratory techniques used in chemistry, including dialysis and ultrafiltration, to separate particles and molecules based on their size and properties.

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