Isomerism: Structural and Stereoisomers

Compounds with the same molecular formula but different structural arrangements.

Isomers that differ in how constituent atoms are connected.

Structural isomers differing in the arrangement of the carbon chain.

Structural isomers differing in the placement of the functional group.

Structural isomers differing in the type of functional group present.

Isomers where functional groups are in dynamic equilibrium, interconverting.

Isomers with different arrangements of atoms in 3D space.

Stereoisomers resulting from the possibility of free rotation around a single bond.

Stereoisomers that cannot be interconverted without breaking bonds.

Configurational isomers with different arrangements around a double bond or ring.

A system for naming alkenes based on priority of groups attached to the double bond.

Isomers that rotate plane-polarized light.

A carbon atom bonded to four different groups.

Isomers that are non-superimposable mirror images.

A mixture containing equal amounts of both enantiomers.

Separation of a racemic mixture into its component enantiomers.

A technique where a column contains a ligand that binds one enantiomer.

Properties of enantiomers that are identical.

An instrument for measuring the rotation of plane-polarized light by a substance.

A group of atoms that determines a molecule's properties.

A compound formed by addition of an alcohol to an aldehyde.

A compound formed by addition of an alcohol to a ketone.

A compound formed by reaction of an aldehyde with two alcohols.

A compound formed by reaction of a ketone with two alcohols.

A reaction where a nucleophile attacks a carbonyl carbon.

Energy transformation and reaction spontaneity.

The system and its surroundings.

System that exchanges matter and energy with surroundings.

System that exchanges energy but not matter.

System with surroundings exchanges neither matter nor energy.

Energy transferred via temperature differences.

It is a function that is path independent.

Property dependent on the quantity of material.

Property independent of the amount of substance.

The measure of heat evolved during a reaction.

Measure of disorder in a system.

The energy to do work, constant Temp and Pressure.

Linked reactions; a favorable linked an unfavorable

Compounds releases high free energy when hydrolyzed.