Ions, Ionic Bonds, and Valence Electrons
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Questions and Answers

Explain why sodium (Na) readily forms a $1^+$ cation, while chlorine (Cl) readily forms a $1^-$ anion. Relate your answer to the octet rule.

Sodium needs to lose one electron to achieve a full octet whereas chlorine needs to gain one electron to achieve a full octet.

How does the concept of electronegativity relate to the formation of ionic bonds?

A large difference in electronegativity between two atoms leads to an ionic bond as one atom strongly attracts electrons from the other.

Predict the chemical formula of the ionic compound formed between aluminum ($Al$) and oxygen ($O$). Explain the reasoning behind your prediction.

The chemical formula would be $Al_2O_3$ because Aluminum forms a $3^+$ cation and Oxygen forms a $2^-$ anion. To balance the charges we need two aluminum ions for every three oxide ions.

Consider a hypothetical ionic compound, $AB_2$, where A is a metal and B is a non-metal. If element A typically forms a $2^+$ cation, what charge would you expect element B to have as an anion?

<p>Element B would have a $1^-$ charge.</p> Signup and view all the answers

Explain why ionic compounds generally have higher melting and boiling points compared to molecular compounds.

<p>Ionic compounds have strong electrostatic forces between ions throughout the crystal lattice, requiring more energy to overcome, while molecular compounds have weaker intermolecular forces.</p> Signup and view all the answers

Ammonium phosphate, $(NH_4)_3PO_4$, is an ionic compound containing two polyatomic ions. Identify the polyatomic ions present and describe the role they play in forming the compound.

<p>The polyatomic ions are ammonium ($NH_4^+$) and phosphate ($PO_4^{3-}$). Three ammonium cations bond to one phosphate anion, creating an electrically neutral formula unit.</p> Signup and view all the answers

Describe what happens to the electrical conductivity of solid, crystalline NaCl when it is dissolved in water? Explain why this change occurs.

<p>Solid NaCl is a poor conductor of electricity, but when dissolved in water it becomes a good conductor, because the ions are free to move and carry charge.</p> Signup and view all the answers

If a solid sample of an unknown compound is found to conduct electricity and has a high melting point, would you predict it is likely an ionic compound or a molecular compound? Explain.

<p>I would expect the compound to be ionic. Ionic compounds conduct electricity when melted or dissolved and have high melting points due to the strong electrostatic forces.</p> Signup and view all the answers

Flashcards

Cation

A positively charged ion formed when an atom loses electrons.

Anion

A negatively charged ion formed when an atom gains electrons.

Valence Electrons

Electrons in the outermost energy level of an atom.

Octet Rule

Atoms tend to gain, lose, or share electrons to achieve a full outer shell of eight electrons.

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Ionic Bond

The electrostatic attraction between oppositely charged ions.

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Ionic Compound Formula

Chemical formulas contain a metal (or $NH_4^+$) ion at the beginning.

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Polyatomic Ion

A group of atoms bonded together that carries an overall charge.

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Ionic Compound Formula Meaning

The ratio of cations to anions in the crystal lattice structure.

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Study Notes

  • A neutral atom loses one or more electrons to form a cation.
  • Calcium (Ca) becomes a calcium cation ($Ca^{2+}$) by losing two electrons.
  • A neutral atom gains one or more electrons to form an anion.
  • Oxygen (O) becomes an oxide anion ($O^{2-}$) by gaining two electrons.
  • Valence electrons are at the outermost occupied energy level, higher in energy, and have the same charge and mass as any other electron.
  • Neutral atoms have the following number of valence electrons:
  • Sodium (Na): 1
  • Nitrogen (N): 5
  • Argon (Ar): 8
  • Magnesium (Mg): 2
  • Sulfur (S): 6
  • Chlorine (Cl): 7
  • Using the octet rule, the charge of the following atoms when they become ions:
  • Sodium (Na): 1+
  • Nitrogen (N): 3-
  • Argon (Ar): 0
  • Magnesium (Mg): 2+
  • Sulfur (S): 2-
  • Chlorine (Cl): 1-
  • Oppositely charged cations and anions attract one another, holding ionic bonds together.
  • Ionic compounds show a metal (or $NH_4^+$) ion at the beginning, while molecular compounds show only two nonmetals.
  • A polyatomic ion is multiple atoms bonded together that function as an individual ion.
  • The chemical formula for an ionic compound, such as $Fe_2O_3$, tells the ratio of cations to anions in the larger crystal lattice structure, describing the composition of the substance in detail.
  • Ionic compounds are electrically neutral because the ratio of cations to anions will always be such that the positive charges exactly cancel the negative charges.
  • A compound that is a liquid at room temperature, has a melting point of -25°C, and does not conduct electricity is most likely made of molecules because its low melting point suggests that it is not a solid at room temperature.

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Understand ions and ionic bonds, including the formation of cations by losing electrons and anions by gaining electrons. Learn about valence electrons and predicting ionic charges using the octet rule. Identify ionic compounds with metal cations and molecular compounds with nonmetals.

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