Ionic Equilibrium Class 11: Acid-Base Theories
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Questions and Answers

What is the formula to calculate pH from pOH?

  • pH = pOH / 14
  • pH = pOH + 14
  • pH = 14 - pOH (correct)
  • pH = 14 * pOH

Which components are essential for a solution to act as a buffer?

  • A weak base and its conjugate acid (correct)
  • A strong acid and its conjugate base
  • A strong base and its conjugate acid
  • A weak acid and its conjugate base (correct)

What does buffer capacity refer to?

  • The physical state of the buffer in the solution
  • The total volume of a buffer solution
  • The amount of acid or base a buffer can neutralize without significant pH change (correct)
  • The ability of a buffer to resist pH changes with high temperatures

How can pH be calculated for a buffer solution using the Henderson-Hasselbalch equation?

<p>pH = pKa + log ([conjugate base]/[weak acid]) (B)</p> Signup and view all the answers

What is the optimal pH range for a buffer to effectively resist pH changes?

<p>±1 pH unit of the pKa (C)</p> Signup and view all the answers

Which statement accurately describes the Arrhenius Theory of acids and bases?

<p>Acids produce H+ ions in aqueous solutions. (D)</p> Signup and view all the answers

What is the relationship between solubility and the solubility product constant (Ksp)?

<p>Higher Ksp values indicate higher solubility. (A)</p> Signup and view all the answers

Which best describes the Common Ion Effect?

<p>It decreases the solubility of a sparingly soluble salt when a common ion is introduced. (B)</p> Signup and view all the answers

What is pH defined as?

<p>pH = -log[H+] (A)</p> Signup and view all the answers

How do you calculate the solubility of a salt from its Ksp value?

<p>By taking the square root of Ksp for salts with one-to-one dissociation. (A)</p> Signup and view all the answers

Which of the following correctly defines a weak acid in relation to pH calculations?

<p>Calculations require an ICE table to find equilibrium concentrations. (D)</p> Signup and view all the answers

What distinguishes the Brønsted-Lowry theory from the Arrhenius theory?

<p>Brønsted-Lowry theory expands on the idea of proton donation and acceptance. (C)</p> Signup and view all the answers

Which statement is true regarding the Lewis Theory of acids and bases?

<p>It includes substances that do not contain protons. (A)</p> Signup and view all the answers

Flashcards

Arrhenius Theory

Acids produce H+ ions in aqueous solutions, while bases produce OH- ions.

Brønsted-Lowry Theory

An acid is a proton (H+) donor and a base is a proton acceptor.

Lewis Theory

An acid is an electron pair acceptor, and a base is an electron pair donor.

Solubility Equilibrium

Dynamic equilibrium between a solid and its dissolved ions in a saturated solution.

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Solubility Product Constant (Ksp)

A constant for a sparingly soluble salt at a given temperature representing the equilibrium between the solid and its ions..

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Common Ion Effect

Solubility of a sparingly soluble salt decreases when a soluble salt with a common ion is added.

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pH

pH = -log[H+]

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pH Calculation (Strong Acids)

Direct calculation using the concentration of H+ ions.

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pH Calculation (Weak Acids)

Calculation based on Ka (acid dissociation constant) and initial concentration using ICE table.

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pH of Strong Bases

Calculate pOH from [OH-], then use pH + pOH = 14 to find pH.

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Weak Bases Calculations

Use approximations to find ion concentrations in equilibrium equations.

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pH and pOH

Inverse relationship in water; pH + pOH = 14

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Buffer Solution

Resists pH change with acid/base addition.

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Buffer Components

Weak acid + conjugate base (or weak base + conjugate acid).

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Buffer Action

Weak acid/base neutralize added H+/OH- ions

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Henderson-Hasselbalch Equation

pH = pKa + log ([conjugate base]/[weak acid])

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Buffer Capacity

Amount of acid/base a buffer neutralizes before pH changes.

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Buffer Range

pH range where buffer effectively resists change.

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Study Notes

Calculating pH from pOH

  • pH + pOH = 14

Buffer Components

  • A weak acid and its conjugate base
  • Or a weak base and its conjugate acid

Buffer Capacity

  • The amount of acid or base a buffer can neutralize before a significant change in pH occurs

Henderson-Hasselbalch Equation

  • pH = pKa + log([A-]/[HA])
  • Where:
    • pKa: The negative logarithm of the acid dissociation constant (Ka)
    • [A-]: The concentration of the conjugate base
    • [HA]: The concentration of the weak acid

Optimal Buffer pH Range

  • A buffer works best within ± 1 pH unit of its pKa

Arrhenius Theory of Acids and Bases

  • Acids produce hydrogen ions (H+) in water, and bases produce hydroxide ions (OH-) in water

Solubility & Ksp Relationship

  • Ksp is the product of the ion concentrations at equilibrium in a saturated solution
  • A higher Ksp value indicates greater solubility

Common Ion Effect

  • The solubility of a sparingly soluble salt decreases when a soluble compound containing a common ion is added to the solution

pH Definition

  • pH is the negative logarithm of the hydrogen ion concentration ([H+]) in a solution

Calculating Salt Solubility from Ksp

  • Use the equilibrium constant expression for the dissolution of the salt and solve for the solubility of the salt

Weak Acid Definition

  • A weak acid ionizes only partially in solution, resulting in a pH higher than that of a strong acid at the same concentration

Brønsted-Lowry vs. Arrhenius Theory

  • Brønsted-Lowry theory defines acids as proton donors (H+) and bases as proton acceptors, whereas Arrhenius theory focuses on the production of H+ or OH- in aqueous solutions

Lewis Theory of Acids and Bases

  • Lewis acids accept electron pairs, and Lewis bases donate electron pairs. This definition encompasses both proton-based interactions and electron-pair sharing interactions.

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Description

This quiz explores the foundational concepts of ionic equilibrium and various acid-base theories as part of the Class 11 chemistry curriculum. It covers the Arrhenius, Brønsted-Lowry, and Lewis theories, along with the solubility product and its significance. Test your understanding of these critical chemical principles.

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