Ionic Equilibrium Class 11: Acid-Base Theories
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Ionic Equilibrium Class 11: Acid-Base Theories

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Questions and Answers

What is the formula to calculate pH from pOH?

  • pH = pOH / 14
  • pH = pOH + 14
  • pH = 14 - pOH (correct)
  • pH = 14 * pOH
  • Which components are essential for a solution to act as a buffer?

  • A weak base and its conjugate acid (correct)
  • A strong acid and its conjugate base
  • A strong base and its conjugate acid
  • A weak acid and its conjugate base (correct)
  • What does buffer capacity refer to?

  • The physical state of the buffer in the solution
  • The total volume of a buffer solution
  • The amount of acid or base a buffer can neutralize without significant pH change (correct)
  • The ability of a buffer to resist pH changes with high temperatures
  • How can pH be calculated for a buffer solution using the Henderson-Hasselbalch equation?

    <p>pH = pKa + log ([conjugate base]/[weak acid])</p> Signup and view all the answers

    What is the optimal pH range for a buffer to effectively resist pH changes?

    <p>±1 pH unit of the pKa</p> Signup and view all the answers

    Which statement accurately describes the Arrhenius Theory of acids and bases?

    <p>Acids produce H+ ions in aqueous solutions.</p> Signup and view all the answers

    What is the relationship between solubility and the solubility product constant (Ksp)?

    <p>Higher Ksp values indicate higher solubility.</p> Signup and view all the answers

    Which best describes the Common Ion Effect?

    <p>It decreases the solubility of a sparingly soluble salt when a common ion is introduced.</p> Signup and view all the answers

    What is pH defined as?

    <p>pH = -log[H+]</p> Signup and view all the answers

    How do you calculate the solubility of a salt from its Ksp value?

    <p>By taking the square root of Ksp for salts with one-to-one dissociation.</p> Signup and view all the answers

    Which of the following correctly defines a weak acid in relation to pH calculations?

    <p>Calculations require an ICE table to find equilibrium concentrations.</p> Signup and view all the answers

    What distinguishes the Brønsted-Lowry theory from the Arrhenius theory?

    <p>Brønsted-Lowry theory expands on the idea of proton donation and acceptance.</p> Signup and view all the answers

    Which statement is true regarding the Lewis Theory of acids and bases?

    <p>It includes substances that do not contain protons.</p> Signup and view all the answers

    Study Notes

    Calculating pH from pOH

    • pH + pOH = 14

    Buffer Components

    • A weak acid and its conjugate base
    • Or a weak base and its conjugate acid

    Buffer Capacity

    • The amount of acid or base a buffer can neutralize before a significant change in pH occurs

    Henderson-Hasselbalch Equation

    • pH = pKa + log([A-]/[HA])
    • Where:
      • pKa: The negative logarithm of the acid dissociation constant (Ka)
      • [A-]: The concentration of the conjugate base
      • [HA]: The concentration of the weak acid

    Optimal Buffer pH Range

    • A buffer works best within ± 1 pH unit of its pKa

    Arrhenius Theory of Acids and Bases

    • Acids produce hydrogen ions (H+) in water, and bases produce hydroxide ions (OH-) in water

    Solubility & Ksp Relationship

    • Ksp is the product of the ion concentrations at equilibrium in a saturated solution
    • A higher Ksp value indicates greater solubility

    Common Ion Effect

    • The solubility of a sparingly soluble salt decreases when a soluble compound containing a common ion is added to the solution

    pH Definition

    • pH is the negative logarithm of the hydrogen ion concentration ([H+]) in a solution

    Calculating Salt Solubility from Ksp

    • Use the equilibrium constant expression for the dissolution of the salt and solve for the solubility of the salt

    Weak Acid Definition

    • A weak acid ionizes only partially in solution, resulting in a pH higher than that of a strong acid at the same concentration

    Brønsted-Lowry vs. Arrhenius Theory

    • Brønsted-Lowry theory defines acids as proton donors (H+) and bases as proton acceptors, whereas Arrhenius theory focuses on the production of H+ or OH- in aqueous solutions

    Lewis Theory of Acids and Bases

    • Lewis acids accept electron pairs, and Lewis bases donate electron pairs. This definition encompasses both proton-based interactions and electron-pair sharing interactions.

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    Description

    This quiz explores the foundational concepts of ionic equilibrium and various acid-base theories as part of the Class 11 chemistry curriculum. It covers the Arrhenius, Brønsted-Lowry, and Lewis theories, along with the solubility product and its significance. Test your understanding of these critical chemical principles.

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