Ionic and Molecular Compounds

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Questions and Answers

A compound is found to be insoluble in water, but soluble in benzene. It also has a low melting point. Which type of compound is it MOST likely to be?

  • Ionic
  • Nonpolar molecular (correct)
  • Metallic
  • Polar molecular

Which of the following characteristics is LEAST indicative of an ionic compound?

  • Electrical conductivity when melted
  • High melting point
  • Low boiling point (correct)
  • Solubility in water

When nonmetals share electrons equally, the resulting compound is classified as?

  • Metallic
  • Polar molecular
  • Nonpolar molecular (correct)
  • Ionic

Element X is in the same period as element Y, but is located several groups to the left of element Y. Which statement regarding their electronegativity is MOST likely true?

<p>Element Y has a higher electronegativity than element X (A)</p> Signup and view all the answers

Which element has the LOWEST ionization energy?

<p>Cesium (C)</p> Signup and view all the answers

Arrange the following elements in order of INCREASING atomic radius: Cl, S, P, Si.

<p>Cl &lt; S &lt; P &lt; Si (C)</p> Signup and view all the answers

Which statement accurately compares the ionic radius of a cation to its neutral atom?

<p>A cation is smaller than its neutral atom due to decreased electron repulsion. (C)</p> Signup and view all the answers

Moving down a group of metals, reactivity generally increases. Which factor contributes MOST to this trend?

<p>Increase in atomic radius (D)</p> Signup and view all the answers

Element A and Element B are in the same group, but Element A is located higher in the group than Element B. Which of the following statements is MOST likely true regarding their reactivity as nonmetals?

<p>Element A is more reactive than Element B. (A)</p> Signup and view all the answers

Which of the following BEST describes the effect of inner electrons on the attraction between the nucleus and valence electrons?

<p>Inner electrons decrease the attraction by shielding the valence electrons from the full nuclear charge. (C)</p> Signup and view all the answers

How does the effective nuclear charge (ENC) change as you move across a period from left to right, and why?

<p>ENC increases because of more protons and constant shielding. (A)</p> Signup and view all the answers

In a lab setting, you observe that potassium (K) reacts more vigorously with water than sodium (Na). What explains this difference in reactivity?

<p>Potassium has a larger atomic radius, making it easier to lose an electron. (B)</p> Signup and view all the answers

Why are transition metals generally LESS reactive than alkali metals or alkaline earth metals?

<p>Transition metals have a stronger nuclear charge, holding onto their electrons more tightly. (C)</p> Signup and view all the answers

Consider the elements oxygen (O) and fluorine (F). Which statement is FALSE?

<p>Fluorine has a lower ionization energy than oxygen. (D)</p> Signup and view all the answers

Consider the elements lithium (Li) and sodium (Na). Which statement is TRUE?

<p>Sodium has a lower electronegativity than lithium. (D)</p> Signup and view all the answers

Which of the following statements correctly compares the properties of sodium (Na) and magnesium (Mg)?

<p>Sodium has a lower ionization energy and is more reactive than magnesium. (D)</p> Signup and view all the answers

Which of the following compounds would you predict to have the HIGHEST lattice energy?

<p>MgO (B)</p> Signup and view all the answers

Which of the following represents a polar molecule?

<p>$NH_3$ (D)</p> Signup and view all the answers

Which of the following elements would you expect to have the GREATEST difference between its first and second ionization energies?

<p>Na (A)</p> Signup and view all the answers

Predict the products when potassium metal reacts with chlorine gas.

<p>KCl (s) (B)</p> Signup and view all the answers

Flashcards

Ionic Compounds

Formed when metals transfer electrons to nonmetals, creating positive (cation) and negative (anion) ions.

Properties of Ionic Compounds

High melting and boiling points, soluble in water (usually), conduct electricity when dissolved or melted, hard and brittle.

Molecular Compounds

Formed when nonmetals share electrons (covalent bonding).

Polar Molecular Compounds

Unequal sharing of electrons; have partial positive and negative sides (dipoles); usually soluble in water; do not conduct electricity.

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Nonpolar Molecular Compounds

Equal sharing of electrons; no charge separation (no dipoles); insoluble in water, soluble in nonpolar solvents.

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Electronegativity

The ability of an atom to attract electrons.

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Electronegativity Trend

Increases across a period, decreases down a group.

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Ionization Energy

Energy required to remove an electron.

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Ionization Energy Trend

Increases across a period, decreases down a group.

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Atomic Radius

Size of an atom.

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Atomic Radius Trend

Decreases across a period, increases down a group.

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Shielding Effect

Inner electrons block the pull of the nucleus on outer electrons.

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Effective Nuclear Charge (ENC)

Net positive charge felt by valence electrons.

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Alkali Metals (Group 1)

Most reactive, reactivity increases down the group.

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Metal Reactivity

Metals react by losing electrons.

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Reactivity Trend (Metals)

Increases down a group (metals), larger atoms easily lose electrons.

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Reactivity Trend (Nonmetals)

Increases across a period, electrons held tighter.

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Cations

Positive ions; smaller than their atoms as they've lost electrons.

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Anions

Negative ions; larger than their atoms as they've gained electrons.

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Study Notes

  • Ionic compounds involve electron transfer from metals to nonmetals, creating cations (positive ions) and anions (negative ions).

Properties of Ionic Compounds

  • High melting and boiling points are characteristic.
  • Usually soluble in water.
  • Conduct electricity when dissolved or melted.
  • Hard and brittle crystalline solids due to strong electrostatic forces.

Molecular Compounds

  • Formed by nonmetals sharing electrons through covalent bonding.

Polar Molecular Compounds

  • Unequal sharing of electrons results in partial positive and negative sides (dipoles).
  • Usually soluble in water.
  • Do not conduct electricity.
  • Exhibit medium melting/boiling points.

Nonpolar Molecular Compounds

  • Equal sharing of electrons means no charge separation (no dipoles).
  • Insoluble in water but soluble in nonpolar solvents like oil or benzene.
  • Low melting/boiling points.

Identifying Mystery Compounds

  • Conductivity in water: High conductivity indicates an ionic compound.
  • Solubility in water: Soluble suggests ionic or polar; insoluble suggests nonpolar.
  • Melting/boiling points: High for ionic, medium for polar, low for nonpolar.
  • Physical state at room temperature: Solid suggests ionic, liquid/gas suggests molecular.
  • Definition: An atom's ability to attract electrons.
  • Trend: Increases across a period, decreases down a group.
  • Reason: More protons increase attraction; added energy levels (shielding) weaken it.
  • Highest: Fluorine (F).
  • Lowest: Cesium (Cs).
  • Definition: The energy needed to remove an electron.
  • Trend: Increases across a period, decreases down a group.
  • Reason: Across a period, more protons hold electrons tighter; down a group, more shielding makes removal easier.
  • Definition: The size of an atom.
  • Trend: Decreases across a period, increases down a group.
  • Reason: Across a period, more protons pull electrons in tighter; down a group, more energy levels increase size.
  • Cations (positive ions) are smaller than their atoms due to lost electrons reducing repulsion.
  • Anions (negative ions) are larger than their atoms due to gained electrons increasing repulsion.
  • Increases down a group (larger atoms lose electrons easily).
  • Decreases across a period (more protons make it harder to lose electrons).
  • Increases across a period and up a group.
  • Fluorine is the most reactive nonmetal.

Shielding Effect

  • Inner electrons block the nucleus's pull on outer electrons.
  • Trend: Increases down a group due to more inner electrons.
  • Stays constant across a period.

Effective Nuclear Charge (ENC)

  • Net positive charge felt by valence electrons.
  • Trend: Increases across a period due to more protons with the same shielding.
  • Decreases down a group as more shielding reduces attraction.

Reactivity of Metals

  • Metals react by losing electrons.
  • Alkali Metals (Group 1) are the most reactive; reactivity increases down the group.
  • Alkaline Earth Metals (Group 2) are also reactive, but less so than Group 1.
  • Transition Metals are less reactive due to a stronger nuclear charge.

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