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Questions and Answers
What is the observable result of the reaction between iodine and starch under neutral conditions?
What is the observable result of the reaction between iodine and starch under neutral conditions?
- A green solution
- A yellow precipitate
- A colorless solution
- A deep blue-black complex (correct)
In an alkaline environment, what happens to iodine when it interacts with starch?
In an alkaline environment, what happens to iodine when it interacts with starch?
- It forms a deep blue-black complex.
- It remains unchanged and the solution stays colorless.
- It forms iodide and iodate ions instead of the typical blue complex. (correct)
- It produces a bright green precipitate.
What accounts for the yellow coloration observed in a starch-iodine test conducted in an alkaline medium?
What accounts for the yellow coloration observed in a starch-iodine test conducted in an alkaline medium?
- Formation of triiodide ions ($I_3^−$) or residual iodine. (correct)
- Formation of the typical starch-iodine complex.
- Creation of complex carbohydrate polymers.
- Presence of unreacted starch.
How does the reaction between iodine and starch differ in acidic versus alkaline conditions?
How does the reaction between iodine and starch differ in acidic versus alkaline conditions?
In the reaction $3I_2 + 6OH^- → 5I^- + IO_3^- + 3H_2O$, what role does hydroxide ($OH^−$) play?
In the reaction $3I_2 + 6OH^- → 5I^- + IO_3^- + 3H_2O$, what role does hydroxide ($OH^−$) play?
What visual indication suggests that a starch-iodine test was performed under alkaline instead of neutral conditions?
What visual indication suggests that a starch-iodine test was performed under alkaline instead of neutral conditions?
Why might a starch-iodine test yield a yellow color even if starch is present in the sample?
Why might a starch-iodine test yield a yellow color even if starch is present in the sample?
If a starch-iodine test in an alkaline solution does not produce a blue-black color, what ions are likely being formed instead?
If a starch-iodine test in an alkaline solution does not produce a blue-black color, what ions are likely being formed instead?
In an alkaline medium, how does the form of iodine change as it reacts with hydroxide ions?
In an alkaline medium, how does the form of iodine change as it reacts with hydroxide ions?
Why is it essential to control the pH when performing a starch-iodine test?
Why is it essential to control the pH when performing a starch-iodine test?
What is the role of $H_2O$ in the reaction $3I_2 + 6OH^- → 5I^- + IO_3^- + 3H_2O$?
What is the role of $H_2O$ in the reaction $3I_2 + 6OH^- → 5I^- + IO_3^- + 3H_2O$?
If a starch-iodine test turns yellow-brown and no starch is present, what is the most likely reason?
If a starch-iodine test turns yellow-brown and no starch is present, what is the most likely reason?
How does the presence of an alkaline medium affect the interaction between iodine and starch at a molecular level?
How does the presence of an alkaline medium affect the interaction between iodine and starch at a molecular level?
What would be the expected outcome if you added iodine to a solution of starch that also contained a strong base like NaOH?
What would be the expected outcome if you added iodine to a solution of starch that also contained a strong base like NaOH?
Iodine, starch, and $KOH$ are mixed. What chemical species can be expected?
Iodine, starch, and $KOH$ are mixed. What chemical species can be expected?
Which conditions will prevent the formation of the blue-black complex in the iodine-starch test?
Which conditions will prevent the formation of the blue-black complex in the iodine-starch test?
Which of the following describes the iodine when an alkaline is tested with starch?
Which of the following describes the iodine when an alkaline is tested with starch?
What type of reaction occurs between iodine and hydroxide ($OH^−$) ions?
What type of reaction occurs between iodine and hydroxide ($OH^−$) ions?
What would happen if starch reacts with iodine under acidic conditions?
What would happen if starch reacts with iodine under acidic conditions?
What happens to iodine in an alkaline solution?
What happens to iodine in an alkaline solution?
Flashcards
Starch-Iodine Test Result
Starch-Iodine Test Result
In neutral or acidic conditions, iodine (I₂) reacts with starch, creating a deep blue-black complex.
Iodine Reaction in Alkaline Conditions
Iodine Reaction in Alkaline Conditions
In alkaline conditions, iodine forms iodide (I⁻) and iodate (IO₃⁻) instead of the typical blue complex.
Reaction of Iodine in Alkaline Medium
Reaction of Iodine in Alkaline Medium
Iodine reacts with hydroxide ions to form iodide and iodate ions.
Yellow Precipitate in Alkaline Solution
Yellow Precipitate in Alkaline Solution
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Study Notes
- Iodine interacts with starch to create a deep blue-black complex under neutral or acidic conditions.
- In alkaline environments (NaOH/KOH), iodine's reaction changes, producing iodide (I⁻) and iodate (IO₃⁻) rather than the blue complex.
- The alkaline reaction between iodine (I₂) and hydroxide ions (OH⁻) is represented by the equation: 3I₂ + 6OH⁻ → 5I⁻ + IO₃⁻ + 3H₂O.
- An excess of iodine can lead to the formation of triiodide ions (I₃⁻), which may manifest as a yellowish solution or precipitate.
- Without starch, the solution might exhibit a yellow-brown tint as a result of leftover iodine.
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