Iodine-Starch Interactions

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Questions and Answers

What is the observable result of the reaction between iodine and starch under neutral conditions?

  • A green solution
  • A yellow precipitate
  • A colorless solution
  • A deep blue-black complex (correct)

In an alkaline environment, what happens to iodine when it interacts with starch?

  • It forms a deep blue-black complex.
  • It remains unchanged and the solution stays colorless.
  • It forms iodide and iodate ions instead of the typical blue complex. (correct)
  • It produces a bright green precipitate.

What accounts for the yellow coloration observed in a starch-iodine test conducted in an alkaline medium?

  • Formation of triiodide ions ($I_3^−$) or residual iodine. (correct)
  • Formation of the typical starch-iodine complex.
  • Creation of complex carbohydrate polymers.
  • Presence of unreacted starch.

How does the reaction between iodine and starch differ in acidic versus alkaline conditions?

<p>In acidic conditions, a blue-black complex forms, while in alkaline conditions, iodide and iodate ions are produced. (B)</p> Signup and view all the answers

In the reaction $3I_2 + 6OH^- → 5I^- + IO_3^- + 3H_2O$, what role does hydroxide ($OH^−$) play?

<p>It provides the alkaline medium necessary for iodine to form iodide and iodate ions. (D)</p> Signup and view all the answers

What visual indication suggests that a starch-iodine test was performed under alkaline instead of neutral conditions?

<p>A yellow or yellow-brown color appears, and no blue-black color is observed. (D)</p> Signup and view all the answers

Why might a starch-iodine test yield a yellow color even if starch is present in the sample?

<p>The starch has completely reacted, leaving only iodine in the solution. (A)</p> Signup and view all the answers

If a starch-iodine test in an alkaline solution does not produce a blue-black color, what ions are likely being formed instead?

<p>Iodide and iodate (A)</p> Signup and view all the answers

In an alkaline medium, how does the form of iodine change as it reacts with hydroxide ions?

<p>It converts into iodide ($I^−$) and iodate ($IO_3^−$) ions. (C)</p> Signup and view all the answers

Why is it essential to control the pH when performing a starch-iodine test?

<p>To dictate whether the iodine forms a complex with starch or reacts to form other ions. (B)</p> Signup and view all the answers

What is the role of $H_2O$ in the reaction $3I_2 + 6OH^- → 5I^- + IO_3^- + 3H_2O$?

<p>It is a product formed as a result of the reaction. (A)</p> Signup and view all the answers

If a starch-iodine test turns yellow-brown and no starch is present, what is the most likely reason?

<p>The yellow color is due to the presence of residual iodine. (D)</p> Signup and view all the answers

How does the presence of an alkaline medium affect the interaction between iodine and starch at a molecular level?

<p>It prevents iodine from interacting with starch, leading to the formation of iodide and iodate ions. (D)</p> Signup and view all the answers

What would be the expected outcome if you added iodine to a solution of starch that also contained a strong base like NaOH?

<p>A yellow solution might form, with no blue color present. (D)</p> Signup and view all the answers

Iodine, starch, and $KOH$ are mixed. What chemical species can be expected?

<p>Iodide and iodate (D)</p> Signup and view all the answers

Which conditions will prevent the formation of the blue-black complex in the iodine-starch test?

<p>Alkaline conditions (A)</p> Signup and view all the answers

Which of the following describes the iodine when an alkaline is tested with starch?

<p>Excess iodine may form traiodide ions. (D)</p> Signup and view all the answers

What type of reaction occurs between iodine and hydroxide ($OH^−$) ions?

<p>Redox (D)</p> Signup and view all the answers

What would happen if starch reacts with iodine under acidic conditions?

<p>A dark blue-black solution would form. (D)</p> Signup and view all the answers

What happens to iodine in an alkaline solution?

<p>Iodine forms iodide and iodate. (C)</p> Signup and view all the answers

Flashcards

Starch-Iodine Test Result

In neutral or acidic conditions, iodine (I₂) reacts with starch, creating a deep blue-black complex.

Iodine Reaction in Alkaline Conditions

In alkaline conditions, iodine forms iodide (I⁻) and iodate (IO₃⁻) instead of the typical blue complex.

Reaction of Iodine in Alkaline Medium

Iodine reacts with hydroxide ions to form iodide and iodate ions.

Yellow Precipitate in Alkaline Solution

Excess iodine forming triiodide ions (I₃⁻).

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Study Notes

  • Iodine interacts with starch to create a deep blue-black complex under neutral or acidic conditions.
  • In alkaline environments (NaOH/KOH), iodine's reaction changes, producing iodide (I⁻) and iodate (IO₃⁻) rather than the blue complex.
  • The alkaline reaction between iodine (I₂) and hydroxide ions (OH⁻) is represented by the equation: 3I₂ + 6OH⁻ → 5I⁻ + IO₃⁻ + 3H₂O.
  • An excess of iodine can lead to the formation of triiodide ions (I₃⁻), which may manifest as a yellowish solution or precipitate.
  • Without starch, the solution might exhibit a yellow-brown tint as a result of leftover iodine.

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