Introduction to Energy Sources
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Questions and Answers

What is the cetane number range for good diesel?

  • 45-50 (correct)
  • 60-65
  • 75-80
  • 30-35
  • Which of the following processes is used to obtain synthetic petrol?

  • Bergius process (correct)
  • Meyer process
  • Fischer-Tropsch process (correct)
  • Kraft process
  • What is the primary component mixture used in the Fischer-Tropsch process?

  • Water gas and carbon dioxide
  • Methanol and water
  • Natural gas and hydrogen gas
  • Water gas and hydrogen gas (correct)
  • At what temperature range is the Fischer-Tropsch process typically maintained?

    <p>200 - 300 °C (A)</p> Signup and view all the answers

    Which catalyst component is NOT used in the Fischer-Tropsch process?

    <p>Copper (Cu) (D)</p> Signup and view all the answers

    What type of gas classification does natural gas fall under?

    <p>Primary fuels (B)</p> Signup and view all the answers

    What is the end product obtained from the upper fraction of a fractionating column during crude oil distillation?

    <p>Gasoline fraction (C)</p> Signup and view all the answers

    What is a common gaseous fuel that is considered a secondary fuel?

    <p>Coal gas (C)</p> Signup and view all the answers

    What is one of the products obtained from further fractionation of heavy oil?

    <p>Lubricating oil (D)</p> Signup and view all the answers

    What is the primary purpose of the cracking process?

    <p>To convert larger hydrocarbon molecules into smaller ones (A)</p> Signup and view all the answers

    Which type of cracking involves the use of a catalyst?

    <p>Catalytic Cracking (D)</p> Signup and view all the answers

    How is the fixed carbon percentage in coal calculated?

    <p>100 - (% of moisture + % of volatile matter + % of ash) (A)</p> Signup and view all the answers

    In fluidized-bed catalytic cracking, what enhances the mixing of catalyst and feed stock vapours?

    <p>Agitation by gas streams (B)</p> Signup and view all the answers

    What is a key advantage of fluidized-bed catalytic cracking over fixed-bed cracking?

    <p>Continuous regeneration of the catalyst (D)</p> Signup and view all the answers

    What represents the elemental analysis known as ultimate analysis in coal?

    <p>Determination of carbon and hydrogen, nitrogen, sulfur, and oxygen (B)</p> Signup and view all the answers

    Which method is used to determine the nitrogen percentage in coal?

    <p>Kjeldahl method (D)</p> Signup and view all the answers

    At what temperature is the fluidized-bed catalytic cracking process typically maintained?

    <p>5500 C (C)</p> Signup and view all the answers

    What are the products formed when coal is burned in pure oxygen?

    <p>Carbon dioxide and water (B)</p> Signup and view all the answers

    Which of the following describes thermal cracking?

    <p>It converts heavier hydrocarbons at high temperatures without a catalyst. (D)</p> Signup and view all the answers

    In the Kjeldahl method, what is the role of K2SO4?

    <p>To catalyze the reaction (B)</p> Signup and view all the answers

    What type of hydrocarbons are primarily produced from the cracking process?

    <p>Light hydrogen-rich hydrocarbons (C)</p> Signup and view all the answers

    Why is the increase in weight of KOH and CaCl2 significant in determining carbon and hydrogen?

    <p>It allows calculation of carbon and hydrogen percentages (B)</p> Signup and view all the answers

    What does a higher percentage of carbon and hydrogen in coal imply?

    <p>Higher quality of coal and calorific value (C)</p> Signup and view all the answers

    What calculation yields the percentage of carbon in coal after combustion?

    <p>Increase in weight of KOH divided by weight of coal (D)</p> Signup and view all the answers

    What is one reason that excess methanol needs to be used in the reaction?

    <p>To ensure complete reaction with triglycerides. (D)</p> Signup and view all the answers

    Which of the following is a disadvantage of producing biodiesel?

    <p>Variation in quality of biodiesel. (D)</p> Signup and view all the answers

    What occurs when water is added to biodiesel during production?

    <p>It promotes unwanted side reactions. (D)</p> Signup and view all the answers

    What is the primary function of lipases in the biodiesel production process?

    <p>They act as a catalyst yet require alcohol. (B)</p> Signup and view all the answers

    What product is formed when triglycerides react with methanol?

    <p>Fatty acid methyl ester. (D)</p> Signup and view all the answers

    What happens to the glycerol after biodiesel is produced?

    <p>It requires neutralization with acid. (A)</p> Signup and view all the answers

    Which factor is NOT mentioned as an advantage of biodiesel?

    <p>Enhanced engine efficiency. (B)</p> Signup and view all the answers

    What is a consequence of using biodiesel in terms of environmental impact?

    <p>Slight increase in nitrogen oxide emissions. (A)</p> Signup and view all the answers

    What is released during the digestion process as a result of oxidizing organic substances with sulphuric acid?

    <p>Ammonium sulphate (A)</p> Signup and view all the answers

    What is the primary purpose of adding potassium sulphate during the digestion process?

    <p>To increase the boiling point of the medium (C)</p> Signup and view all the answers

    Which reaction takes place when sodium hydroxide is added during the distillation step?

    <p>(NH4)2SO4 + 2 NaOH → 2 NH3 + Na2SO4 + 2 H2O (C)</p> Signup and view all the answers

    What is the purpose of back titration in the analysis of nitrogen?

    <p>To calculate the amount of unreacted acid remaining (D)</p> Signup and view all the answers

    Which substance is formed after the reaction of sulphur with oxygen and electrons?

    <p>Sulfate ion (SO42-) (D)</p> Signup and view all the answers

    What is the significance of measuring sulfur percentage in a sample?

    <p>To analyze calorific value and assess pollution impact (A)</p> Signup and view all the answers

    Which ions are commonly used as catalysts during the digestion process?

    <p>Copper and mercury (D)</p> Signup and view all the answers

    In the formula for calculating the percentage of nitrogen, which of the following is considered as the denominator?

    <p>Weight of coal (A)</p> Signup and view all the answers

    What makes LPG a popular choice for domestic cooking?

    <p>It is cheaper than other fuels. (B)</p> Signup and view all the answers

    Which applications utilize LPG?

    <p>Health, industrial, construction, and residential use. (B)</p> Signup and view all the answers

    What is one characteristic of CNG compared to other fuels?

    <p>It is odorless, tasteless, and non-toxic. (A)</p> Signup and view all the answers

    How is natural gas converted into Compressed Natural Gas (CNG)?

    <p>By cooling it to -165 °C or compressing at 100 atm pressure. (C)</p> Signup and view all the answers

    What is one major drawback of using LPG as a vehicle fuel?

    <p>It has a lower energy efficiency compared to petrol. (A)</p> Signup and view all the answers

    Which statement about CNG's environmental impact is true?

    <p>It is an environmentally clean alternative fuel. (C)</p> Signup and view all the answers

    What is the energy density of CNG?

    <p>53.6 MJ/kg or 9 MJ/L. (D)</p> Signup and view all the answers

    What is the ignition temperature characteristic of CNG?

    <p>It has a low flammability range and high ignition temperature. (B)</p> Signup and view all the answers

    Flashcards

    What is cracking?

    The process of breaking down large hydrocarbon molecules into smaller ones, typically producing lighter hydrocarbons and unsaturated compounds.

    Define Thermal Cracking.

    A type of cracking where larger hydrocarbon molecules are converted into smaller ones using heat.

    Define Catalytic Cracking.

    A type of cracking where larger hydrocarbon molecules are converted into smaller ones using a catalyst.

    What is Fixed-bed Cracking?

    A type of catalytic cracking where the catalyst is in a fixed bed and the feedstock passes through it.

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    What is Fluid-bed (Moving-bed) Cracking?

    A type of catalytic cracking where the catalyst is finely divided and kept agitated by a gas stream, allowing it to behave like a fluid.

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    What is the catalyst used in Fluid-bed Cracking?

    The finely divided catalyst used in fluidized-bed cracking, typically composed of alumina (Al2O3) and silica (SiO2).

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    What is a Cracking Chamber?

    The chamber where the cracking process takes place in fluidized-bed cracking, where heavy oil or gas oil is converted at a high temperature (550°C).

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    What is Catalyst Regeneration?

    The process of regenerating the deactivated catalyst in fluidized-bed cracking, allowing it to be used again.

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    Digestion (in chemical analysis)

    A method that breaks down organic material in a sample using sulfuric acid and heat. The process aims to convert nitrogen to ammonium sulfate.

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    Oxidation of organic material during digestion

    A chemical reaction where sulfuric acid oxidizes organic material in a sample, reducing nitrogen to ammonium sulfate.

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    Distillation of ammonia

    A process that converts ammonium sulfate to ammonia gas, which is collected in a special solution for measurement.

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    Titration in nitrogen analysis

    A technique used to determine the amount of ammonia (and hence nitrogen) in a sample.

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    Conversion of ammonium sulfate to ammonia

    The process of adding sodium hydroxide to convert ammonium sulfate to ammonia gas during distillation.

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    Nitrogen percentage calculation

    The percentage of nitrogen in a sample is calculated based on the volume of hydrochloric acid used to trap the ammonia during distillation.

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    Reaction of ammonia with sulfuric acid

    A chemical reaction where sulfuric acid (H2SO4) reacts with ammonia (NH3) to form ammonium sulfate (NH4)2SO4.

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    Gravimetric determination of sulfur

    The process of adding barium chloride to a solution containing sulfate ions to form a precipitate of barium sulfate (BaSO4).

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    Fixed Carbon Percentage in Coal

    The percentage of fixed carbon in coal indicates its potential for combustion. Higher fixed carbon content usually means greater calorific value (energy released during burning).

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    Ultimate Analysis

    A method used to determine the elemental composition of coal, focusing on essential components like carbon, hydrogen, nitrogen, sulfur, and oxygen.

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    Carbon and Hydrogen Determination

    The process where a known weight of coal is burned in pure oxygen to convert carbon to CO2 and hydrogen to H2O. These gases are then absorbed by chemicals, and the weight increase reveals the original amounts of carbon and hydrogen.

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    CO2 Absorption by KOH

    The absorption of CO2 by potassium hydroxide (KOH) leading to an increased weight in the KOH tube.

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    H2O Absorption by CaCl2

    The absorption of H2O by calcium chloride (CaCl2) resulting in an increased weight of the CaCl2 tube.

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    Kjeldahl Method

    A method for determining nitrogen content in coal, involving digestion, distillation, and titration.

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    Digestion Step in Kjeldahl Method

    The first step in the Kjeldahl method, where nitrogen in coal is converted to ammonium sulfate ((NH4)2SO4) using sulfuric acid and potassium sulfate as a catalyst.

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    Significance of Carbon and Hydrogen Percentage

    The quality of coal is generally higher with a greater percentage of carbon and hydrogen. This results in a higher calorific value, meaning more energy released during combustion.

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    LPG Knock Resistance

    LPG is highly resistant to knocks, making it suitable for use in engines.

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    LPG's Economic Benefits

    LPG is widely used in homes and industries for cooking and heating because it's cheaper than other fuels.

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    LPG as Vehicle Fuel

    LPG is used in cars as a clean and economical fuel alternative to petrol. However, it's less efficient, making it less popular.

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    CNG: Compressed Fuel Gas

    CNG is a fuel gas like petrol or diesel, created by compressing natural gas to high pressure.

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    CNG Safety

    CNG is safer in case of leaks because it disperses quickly in the air.

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    CNG Composition

    CNG is made up of methane, nitrogen, carbon dioxide, propane, and traces of ethane. The main component is methane.

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    CNG Calorific Value

    CNG has a high calorific value, meaning it burns efficiently and releases a lot of energy.

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    CNG Flammability

    CNG is highly flammable and has a high ignition temperature, making it a potential safety hazard.

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    Octane Number

    A measure of a gasoline's resistance to knocking (uncontrolled combustion) in an engine.

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    Cetane Number

    A measure of a diesel fuel's ignition quality, or how easily it ignites under compression.

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    Bergius Process

    A process that converts coal into synthetic petroleum by mixing hydrogen gas (H2) and water gas (CO + H2) in the presence of a catalyst at high temperatures and pressures.

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    Fischer-Tropsch Process

    This process uses water gas and hydrogen gas to produce synthetic hydrocarbons (including gasoline) through a series of chemical reactions with catalysts.

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    Natural Gas

    Gas that is naturally found above oil deposits in well, and can also exist in underground reservoirs without oil under it.

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    Fire Damp

    A gas with a high methane content, often found alongside oil in wells.

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    Coal Gas

    A type of gaseous fuel derived from coal through a heating process, but can also be produced by other means.

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    Producer Gas

    A type of gas produced when air is passed over hot burning coal in a specially designed reactor, resulting in a mixture of carbon monoxide, nitrogen, and hydrogen.

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    Transesterification

    A chemical reaction where a triglyceride (fat) reacts with an alcohol (methanol or ethanol) in the presence of a catalyst (usually a base like sodium hydroxide or potassium hydroxide). This reaction produces biodiesel (fatty acid methyl or ethyl esters) and glycerol as byproducts.

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    Washing biodiesel

    A chemical reaction where water is added to biodiesel to separate out unwanted byproducts like glycerol.

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    Glycerol

    The by-product of transesterification, along with biodiesel. It is a viscous, sweet-tasting liquid used in various industries.

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    Catalyst

    The substance used to speed up the chemical reaction of transesterification, typically sodium hydroxide (NaOH) or potassium hydroxide (KOH).

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    Biodiesel

    A renewable fuel derived from vegetable oils or animal fats. It is biodegradable and can be used in diesel engines, but can have some drawbacks.

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    Methanol

    The alcohol used in transesterification. This reaction is usually catalyzed by a base, but can be performed with a lipase enzyme.

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    Dehydration of Biodiesel

    The process of removing water from biodiesel to improve its quality and prevent microbial growth.

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    Saponification

    The reaction between free fatty acids and water to form soap, an unwanted side reaction in biodiesel production.

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    Study Notes

    Introduction to Energy Sources

    • Energy is essential for all countries
    • Fuels provide energy through combustion
    • Combustion is oxidation with heat and light
    • Not all oxidations are combustions, e.g., rusting

    Fuels and Classification

    • Fuels are broadly categorized as primary (natural) and secondary (artificial)
    • Primary fuels are natural fuels
    • Secondary fuels are artificial fuels
    • Fuels can be further classified by state (solid, liquid, gas)

    Solid Fuels

    • Slow combustion, easy to control
    • Difficult to transport
    • Safe storage
    • Relatively low calorific value
    • Slow combustion
    • High ash content
    • Higher pollution

    Liquid Fuels

    • Quick combustion, hard to control
    • Easy to transport via pipes
    • Higher risk of storing
    • Relatively higher calorific value
    • Quick combustion
    • No ash content
    • Low pollution

    Gaseous Fuels

    • Rapid combustion, easy to control
    • Easy to transport via pipes and containers
    • Higher risk of storing
    • Highest calorific value
    • Very fast combustion
    • No ash content
    • Low pollution

    Calorific Value

    • Total heat released when a unit mass of fuel is completely burned in air/oxygen
    • Measured in calories, kilocalories, British Thermal Units (BTUs) and centigrade Thermal Units (CTUs)
    • Two types: Gross (HCV) and Net (LCV)
    • Gross calorific value (HCV): includes latent heat of water vapor produced during combustion
    • Net calorific value (LCV):Excludes the latent heat of water vapor released
    • Relationship: LCV = HCV - (mass of hydrogen × 9 × latent heat of water vapor formed)
    • Formula for calculation of HCV: HCV= [(8080C) + (34500H) + (2240S)]/ 100 (Where C, H, O, S are the percentages of carbon, hydrogen, oxygen and sulfur respectively).

    Coal Analysis

    • Proximate Analysis: Simplest form of analysis to determine coal quality by calculating percentage of moisture, volatile matter, ash, and fixed carbon.

      • Moisture content is the loss in weight of coal when heated to 110°C
      • Volatile matter is the loss in weight of coal when heated to 950°C in the absence of air
      • Ash content is the residue remaining after complete combustion
    • Ultimate Analysis: Determine the elemental composition (percentage of carbon, hydrogen, nitrogen, sulfur, and oxygen) and calculates the percentage of all elements in coal.

    Liquid Fuels (Petroleum)

    • Petroleum is a mixture of hydrocarbons
    • Classified into paraffinic, asphaltic, and mixed
    • Refining involves separating water, removing impurities, and fractional distillation to obtain different components
    • Fractional distillation separates components based on boiling points
    • Different fractions include petroleum ether, gasoline, kerosene, diesel oil, heavy oil, lubricating oil, grease, petrol jelly

    Cracking of Fuels

    • Cracking converts larger hydrocarbon molecules into smaller ones
    • Two types: thermal and catalytic cracking
    • Catalytic cracking produces gasoline

    Knocking

    • Knocking is a measure of engine efficiency
    • Higher the compression ratio, better the engine
    • Octane number is a measure or performance of fuel in an engine; it is a measure of resistance to knocking

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