Intermolecular Forces Quiz
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Questions and Answers

Which type of intermolecular force is present between ALL molecules?

  • Permanent dipole-dipole forces
  • Hydrogen bonds
  • London forces (correct)
  • Ionic bonds
  • Permanent dipole-dipole forces are present between non-polar molecules.

    False (B)

    What is the primary characteristic that facilitates the formation of hydrogen bonds?

    Hydrogen bonded to F, N, or O

    Instantaneous dipoles are caused by the movement of ___________ in atoms or molecules.

    <p>electrons</p> Signup and view all the answers

    Match the intermolecular force with the molecules that it commonly occurs between:

    <p>London forces = Non-polar molecules Permanent dipole-dipole forces = Polar molecules Hydrogen bonds = Molecules containing H bonded to F, N, or O</p> Signup and view all the answers

    Which of the following best describes London forces?

    <p>Temporary partial charges leading to induced dipoles (A)</p> Signup and view all the answers

    Hydrogen bonds are stronger than both London forces and permanent dipole-dipole interactions.

    <p>True (A)</p> Signup and view all the answers

    List two factors that increase the strength of London forces.

    <p>Large atoms, longer molecule chains</p> Signup and view all the answers

    In contrast to London forces, dipole-dipole interactions are formed between molecules with permanent ______.

    <p>dipoles</p> Signup and view all the answers

    Match the following intermolecular forces with the types of molecules most likely to exhibit them:

    <p>London forces = Alkanes, noble gases Permanent Dipole-Dipole Interactions = HCl, HBr, HI, aldehydes Hydrogen bonds = HF, H2O, NH3, alcohols</p> Signup and view all the answers

    Flashcards

    London Forces

    Attraction forces between induced or instantaneous dipoles in all molecules, especially non-polar ones.

    Dipole-Dipole Forces

    Attraction forces between permanent dipoles of polar molecules with uneven charge distribution.

    Hydrogen Bonds

    Structured bonds formed between H atoms bonded to F, N, or O and lone pairs on these electronegative atoms.

    Permanent Dipoles

    Regions in polar molecules where charge is uneven due to electronegativity differences.

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    Instantaneous Dipoles

    Temporary dipoles formed when electrons randomly distribute unevenly in atoms or molecules.

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    Induced Dipoles

    Temporary dipoles created in neighboring molecules due to instantaneous dipoles.

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    Strength of Intermolecular Forces

    Rank from weakest (London) to strongest (Hydrogen bonds), still weaker than ionic/covalent bonds.

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    Effect of Size on London Forces

    London forces increase with larger and longer molecule chains.

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    Study Notes

    London Dispersion Forces

    • Attraction forces between induced or instantaneous dipoles
    • Act between all molecules, but most significant in nonpolar molecules or very large nonpolar segments
    • Electrons in atoms/molecules are constantly moving, creating temporary uneven distributions
    • This uneven distribution creates temporary partial charges (instantaneous dipoles)
    • These temporary dipoles induce dipoles in neighboring molecules
    • Strength increases with larger atoms and longer molecules due to increased polarizability

    Permanent Dipole-Dipole Forces

    • Attraction forces between permanent dipoles
    • Present between polar molecules containing atoms with partial charges
    • Dipoles are created by differences in electronegativity between atoms in a molecule
    • Oppositely charged partial charges in neighbouring molecules attract each other

    Hydrogen Bonds

    • Structured bonds between permanent dipoles
    • Involve a hydrogen atom bonded to a highly electronegative atom (Fluorine, Oxygen, or Nitrogen)
    • Strongest intermolecular force; about 20 times weaker than a covalent or ionic bond
    • The electronegative atom attracts electrons, causing a partial positive on the hydrogen
    • The lone electron pairs on the electronegative atom attract the partially positive hydrogen atom of a neighbouring molecule, forming a hydrogen bond.
    • Strength increases with increasing electronegativity of the atom bonded to the hydrogen atom.

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    Description

    Test your understanding of intermolecular forces, including London dispersion forces, permanent dipole-dipole forces, and hydrogen bonds. This quiz covers their characteristics, significance, and the conditions under which they occur. Enhance your knowledge of molecular interactions and their implications in chemistry.

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