Hydrocarbon Water Wash Process

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Questions and Answers

What is the primary purpose of the water wash system described in the text?

To remove entrained caustic and/or aluminates from the vapor hydrocarbon stream.

Explain the role of E-350 (Water Wash Heater) in the water wash process and what heats the water?

E-350 heats the circulating water before it is routed to M-350. The water is heated on the shell side of E-350 by 100 psig steam on the tube side.

Describe the function of P-350A/B (Water Wash Circulation Pumps) and their operational setup.

P-350A/B recirculate the water wash stream, with one pump normally in service and the other in standby.

How does E-351 (Water Wash Vapor Cooler) contribute to the water wash process, and what is the purpose of E-351B?

<p>E-351 cools the vapor hydrocarbon stream, condensing the water in the vapor hydrocarbon prior to being routed to D-360. E-351B is a spare cooler placed in service when E-351 is being cleaned.</p>
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Trace the path of the wastewater after it separates in D-350 (Water Wash Settler), and indicate its final destination as described in the text.

<p>After separating in D-350, the wastewater flows to D-353 (Wastewater Degassing Drum) before being drained to the Oily Water Sewer (OWS).</p>
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Flashcards

P-350A/B Function

Circulate water wash stream from D-350, used in the water wash process.

E-350 (Water Wash Heater)

A shell and tube exchanger that heats circulating water using 100 psig steam.

E-350 Purpose

Heats the circulating water before it goes to M-350.

T-350 Function

Ensures the vapor hydrocarbon is free of any entrained caustic and/or aluminates, also minimizing the liquid hydrocarbon.

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E-351 Function

Cools the vapor hydrocarbon, condensing water prior to D-360.

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Study Notes

  • The skimmed hydrocarbon stream from D-340 and the water from the bottom of T-340 go to M-350 (Water Wash Static Mixer).
  • P-350A/B (Water Wash Circulation Pumps) circulate a water wash stream from the bottom of D-350 (Water Wash Settler).
  • The water wash stream is heated in the shell side of E-350 (Water Wash Heater) by 100 psig steam on the tube side.
  • The heated water wash stream joins the three-phase stream before being routed to and mixing in M-350.
  • The resulting three-phase stream from M-350 goes to the bottom of T-350.
  • In T-350, the vapor hydrocarbon separates from the liquid phases and rises through the packed bed.
  • The vapor hydrocarbon is scrubbed with process water to remove any entrained caustic and/or aluminates and minimize liquid hydrocarbon.
  • The scrubbed vapor hydrocarbon is routed to the shell side of E-351 (Water Wash Vapor Cooler) and cooled by cooling water on the tube side.
  • Cooling in E-351 condenses the water in the vapor hydrocarbon prior to routing to D-360.
  • E-351B (Water Wash Vapor Cooler) is used when E-351 is out of service for cleaning.
  • The two liquid phases drop into D-350 and separate.
  • Most of the water is recycled by P-350A/B to mix with the hydrocarbon again.
  • Wastewater flows to D-353 before being drained to the Oily Water Sewer (OWS).
  • Skimmed hydrocarbon is routed to the Debutenizer System.

Equipment Details

  • P-350A/B (Water Wash Circulation Pumps) are single-stage centrifugal pumps driven by 25 HP 1750 RPM horizontally-mounted, induction electric motors
  • P-350 A/B recirculate the water wash stream.
  • Normally, one pump is in service and the other is on standby.
  • E-350 (Water Wash Heater) is a shell and tube exchanger that heats circulating water on the shell side using 100 psig steam on the tube side.
  • M-350 (Wash Water Static Mixer) has 2 carbon steel fixed elements.
  • M-350 mixes the circulating process water with the hydrocarbon stream from D-340.
  • T-350 (Water Wash Vapor Scrubber) is 2’D x 23’L.
  • T-350 separates the vapor from the two liquid phases.
  • The three-phase stream enters the side bottom of T-350.
  • Fresh process water enters the side top of the scrubber.
  • Overhead vapor exits from the top, and the two liquid phases exit from the bottom, going directly into D-350.
  • E-351 (Water Wash Vapor Cooler) is a shell and tube exchanger that cools overhead vapor on the shell side with cooling water on the tube side.
  • E-351 condenses water in the vapor before it's routed to D-360.
  • E-351B (Water Wash Vapor Cooler) is a hairpin heat exchanger.
  • E-351B cools the T-350 overhead vapor stream while E-351 is out of service.
  • The process side of E-351B remains blinded and hydrocarbon-free when out of service to prevent contamination and thermal over-pressurization.
  • D-350 (Water Wash Settler) is 7’D x 28’L and separates the two liquid phases into a recycled water stream and a skimmed hydrocarbon stream.
  • A skim system removes any rag layer developed at the interface.
  • The skim system has a skim pan that spans across the drum at 42-44% of the range of the interface float column
  • The rag layer is periodically removed to D-353.
  • D-353 (Wastewater Degassing Drum) is 3’D x 8’L.
  • D-353 receives wastewater, separates the hydrocarbon vapor from the wastewater, and routes the hydrocarbon vapor to the LP Flare before the wastewater goes to the Oily Water Sewer.
  • The liquid seal in D-353 must be maintained at all times.
  • Failure to maintain the liquid seal will result in hydrocarbon vapor being released to the atmosphere.

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