Group 2 Elements Quiz
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Questions and Answers

Describe the trend in ionization energy down group 2.

Ionization energy decreases down group 2 due to added electron shells, increased shielding, and greater distance between outer electrons and the nucleus.

Describe and explain the trend of atomic radius as you go down group 2.

Atomic radius increases down group 2 because extra electron shells are added.

What ions do group 2 elements form when they react?

+2

Group 2 elements react with water to produce what? Give the general equation and the ions in the product.

<p>Hydroxides. General equation: M(s) + 2H₂O(l) → M(OH)₂(aq) + H₂(g). Ions: M²⁺ and OH⁻.</p> Signup and view all the answers

Group 2 elements burn in oxygen to form what? Give the general equation and the ions in the product.

<p>Oxides. General equation: 2M(s) + O₂ → 2MO(s). Ions: M²⁺ and O²⁻.</p> Signup and view all the answers

Group 2 elements react with chlorine to form what? Give the general equation and the ions in the product.

<p>Chlorides. General equation: M(s) + Cl₂(g) → MCl₂(s). Ions: M²⁺ and Cl⁻.</p> Signup and view all the answers

Magnesium reacts with steam to form what? Give the equation.

<p>Magnesium oxide and hydrogen gas. Equation: Mg(s) + H₂O(g) → MgO(s) + H₂(g).</p> Signup and view all the answers

Explain the trend in reactivity of Group 2 down the group.

<p>Reactivity increases down the group because ionization energy decreases, making it easier for them to react.</p> Signup and view all the answers

Which group 2 oxide is insoluble?

<p>Beryllium oxide</p> Signup and view all the answers

Group 2 oxides react with H₂O to form what? Give the general equation.

<p>Hydroxides. General equation: MO(s) + H₂O(l) → M(OH)₂(aq)</p> Signup and view all the answers

Group 2 metals react with dilute hydrochloric acid to form what? Give the general equation.

<p>Metal chloride and hydrogen gas (MCl₂, and H₂). General equation: M + 2HCl → MCl₂ + H₂</p> Signup and view all the answers

Group 2 metals react with dilute sulfuric acid to form what? Give the general equation.

<p>Metal sulfate and hydrogen gas (MSO₄, H₂). General equation: M + H₂SO₄ → MSO₄ + H₂</p> Signup and view all the answers

Group 2 oxides react with dilute hydrochloric acid to form what? give the general equation

<p>Metal chloride and water (MCl₂, and H₂O). General equation: MO + 2HCl → MCl₂ + H₂O</p> Signup and view all the answers

Group 2 oxides react with dilute sulfuric acid to form what? give the general equation

<p>Metal sulfate and water (MSO₄, H₂O). General equation: MO + H₂SO₄ → MSO₄ + H₂O</p> Signup and view all the answers

What type of reaction occurs between group 2 hydroxides and dilute acid?

<p>Neutralization reaction, producing salt and water.</p> Signup and view all the answers

Hydroxides react with dilute hydrochloric acid to form what? Give the general equation.

<p>Metal chloride and water (MCl₂) and H₂O. General equation: M(OH)₂ + 2HCl → MCl₂ + 2H₂O</p> Signup and view all the answers

Hydroxides react with dilute sulfuric acid to form what? Give the general equation.

<p>Metal sulfate salt and water (MSO₄) and H₂O. General equation: M(OH)₂ + H₂SO₄ → MSO₄ + 2H₂O</p> Signup and view all the answers

Describe the solubility trend of the hydroxides down group 2.

<p>Solubility increases.</p> Signup and view all the answers

How can magnesium hydroxide be used in medicine?

<p>As an antacid for indigestion, to neutralize HCl in the stomach.</p> Signup and view all the answers

Describe the solubility trend of the group 2 sulphates.

<p>Decreases.</p> Signup and view all the answers

Which group 2 sulphate is insoluble?

<p>Barium sulfate</p> Signup and view all the answers

What can barium sulfate be used for due to it's insoluble nature and why?

<p>Barium meals (medical tracer for internal imaging). It doesn't enter the bloodstream because it's insoluble so its toxicity is not a danger to the patient</p> Signup and view all the answers

What is the test for sulfate ions? Give the equation

<p>Acidified barium chloride (BaCl₂). Reacts to form barium sulfate as a white precipitate when sulfate ions are present. Ba²⁺(aq) + SO₄²⁻(aq) → BaSO₄(s)</p> Signup and view all the answers

Define thermal stability.

<p>A measure of the extent to which a compound decomposes. A compound that doesn't decompose at all is VERY thermally stable.</p> Signup and view all the answers

Explain why thermal stability increases down group 2.

<p>As the ionic radius of the cation gets larger, they cause less distortion of the anion, due to the lower charge density, thus making the carbonate/nitrate compound more stable.</p> Signup and view all the answers

Why are group 2 compounds less thermally stable than group1.

<p>They have a higher charge (so greater charge density) thus they cause greater distortion to the anion, meaning the less stable the carbonate/nitrate compound becomes.</p> Signup and view all the answers

Group 1 carbonates decompose to form what?

<p>They are thermally stable and do not decompose. Exception: Lithium carbonate (Li₂CO₃) decomposes to form Lithium oxide and carbon dioxide (Li₂O + CO₂).</p> Signup and view all the answers

Group 1 nitrates decompose to form what?

<p>Metal nitrite and oxygen (MNO₂ + O₂), If brown fumes are observed (lithium nitrate) metal oxide, nitrogen dioxide and oxygen (MO + NO₂ + O₂).</p> Signup and view all the answers

What does the observation of brown fumes mean when heating group 1 and 2 nitrates?

<p>Greater decomposition.</p> Signup and view all the answers

What is the overall pattern for decomposition in the group 1 and 2 nitrated and carbonates? Explain why...

<p>Decomposition occurs when the cation has a 2+ charge (group 2 elements), or the cation has a 1+ charge and is also the smallest group 1 cation (lithium). This is because there is an increased charge density meaning the negative ion can be polarised, the less heat is required to separate the 2 ions meaning the the larger cations form more stable carbonates and nitrates.</p> Signup and view all the answers

How would you measure the thermal stability of nitrates?

<p>Measure the time it takes for a certain amount of oxygen or brown NO₂ gas to be produced.</p> Signup and view all the answers

How would you test the thermal stability of carbonates?

<p>Measure the time it takes for carbon dioxide to be produced. Carbon dioxide, when bubbled through limewater, turns it cloudy.</p> Signup and view all the answers

What is the flame colour of Lithium?

<p>Red</p> Signup and view all the answers

What is the flame colour for potassium?

<p>Lilac</p> Signup and view all the answers

What is the flame colour for rubidium?

<p>Red/purple</p> Signup and view all the answers

What is the flame colour for beryllium?

<p>no colour</p> Signup and view all the answers

What is the flame colour for mangnesium?

<p>no colour</p> Signup and view all the answers

What is the flame colour of Strontium?

<p>Crimson red</p> Signup and view all the answers

How would you carry out the flame test?

<ol> <li>Mix a small amount of the compound being tested with hydrochloric acid. 2. Heat a platinum or nichrome wire in the blue part of the Bunsen flame. 3. Dip the wire into the solution and hold it in the blue part of the flame. 4. Note color produced.</li> </ol> Signup and view all the answers

Why do we see colours in the flame test?

<p>The energy absorbed from the flame causes the electrons to move to higher energy levels. When the electrons fall back down to lower energy levels, releasing energy in the form of light. The difference between the higher and lower energy levels determines the wavelength of the light which determines the colour of the light.</p> Signup and view all the answers

What are the 2 main problems with flame tests?

<ul> <li>many compounds contain small amounts of sodium compounds as impurities, so the sodium colour can mask other colours.</li> <li>describing colours is subjective</li> </ul> Signup and view all the answers

What is the test for ammonium ions? Give the equation

<p>Add sodium hydroxide solution, warm mixture, ammonia gas is released which turns damp red litmus paper blue. Equation: NH₄⁺ + OH⁻ → NH₃ + H₂O</p> Signup and view all the answers

Flashcards

Ionisation Energy Trend in Group 2

Ionisation energy decreases down group 2 due to added electron shells and shielding.

Atomic Radius Trend in Group 2

The atomic radius increases down group 2 due to the addition of extra electron shells.

Group 2 Ions Formation

Group 2 elements form +2 ions when they react.

Group 2 Reaction with Water

Group 2 elements react with water to form hydroxides: M(OH)₂.

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Group 2 Reaction with Oxygen

Group 2 elements burn in oxygen to form oxides: MO.

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Group 2 Reaction with Chlorine

Group 2 elements react with chlorine to form chlorides: MCl₂.

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Magnesium and Steam Reaction

Magnesium reacts with steam to form magnesium oxide (MgO) and hydrogen.

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Reactivity Trend in Group 2

Reactivity increases down group 2 as ionisation energy decreases.

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Insoluble Group 2 Oxide

Beryllium oxide is the insoluble oxide in Group 2.

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Group 2 Hydroxides in Water

Group 2 oxides react with water to form hydroxides: M(OH)₂.

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Reaction with Hydrochloric Acid

Group 2 metals react with dilute HCl to form MCl₂ and H₂.

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Sulfate Formation

Group 2 metals react with dilute sulfuric acid to form MSO₄ and H₂.

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Reaction with Nitric Acid

Group 2 metals react with dilute nitric acid to form M(NO₃)₂ and H₂.

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Hydroxides with Hydrochloric Acid

Hydroxides react with dilute HCl to form MCl₂ and H₂O.

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Solubility Trend of Hydroxides

Solubility of hydroxides increases down group 2.

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Barium Sulfate Insolubility

Barium sulfate is insoluble, used in medical imaging.

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Test for Sulfate Ions

Add acidified barium chloride; a white ppt indicates sulfate ions.

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Thermal Stability Definition

Thermal stability measures a compound's decomposition extent.

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Thermal Stability Trend in Group 2

Thermal stability increases down group 2 due to larger ionic radius.

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Flame Test of Lithium

Lithium produces a red flame when tested in a flame test.

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Flame Color for Sodium

Sodium gives an orange-yellow flame in a flame test.

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Chlorine in Water Color

Chlorine appears virtually colorless in water.

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Reaction Type of Group 2 Hydroxides and Acids

The reaction is a neutralization producing salt and water.

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Reducing Power of Halide Ions Trend

Reducing power increases down group 7 as ionic size increases.

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Displacement Rule for Halogens

More reactive halogens displace less reactive ones from compounds.

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Study Notes

Group 2 Elements

  • Group 2 elements form +2 ions when reacting.
  • Reactivity increases down the group.
  • Ionisation energy decreases down the group due to increased shielding and distance from the nucleus.
  • Atom radius increases down the group due to added electron shells.
  • Group 2 oxides are generally basic oxides. Beryllium oxide is insoluble.
  • Group 2 hydroxides are soluble to different degrees, increasing down the group. Magnesium hydroxide can be used as an antacid.
  • Group 2 sulphates are soluble to different extents, decreasing down the group. Barium sulphate is insoluble. Barium sulphate is used in medical imaging due to insolubility.
  • Thermal stability increases down the group.
  • Group 2 carbonates and nitrates decompose when heated to form metal oxides, carbon dioxide, and nitrogen dioxide. Lithium compounds show exceptions.
  • Flame tests can be used to identify Group 2 metals.

Group 2 Reactions

  • Group 2 metals react with water to produce hydroxides and hydrogen gas.
  • Group 2 metals react with oxygen to produce oxides.
  • Group 2 metals react with chlorine to produce chlorides.
  • Group 2 metals react with steam to form oxides and hydrogen gas.
  • Group 2 oxides react with water to form hydroxides.
  • Group 2 metals react with dilute acids (hydrochloric, sulfuric, nitric) to produce metal salts and hydrogen gas.
  • Group 2 hydroxides react with dilute acids to produce metal salts and water.
  • Reactions with dilute acids are neutralisation reactions.

Group 7 Elements

  • The halogens exist as diatomic molecules in different states at room temperature.
  • Reactivity decreases down the group.
  • Atomic radius increases down the group.
  • Melting and boiling points increase down the group.
  • Electronegativity decreases down the group.
  • Oxidising power decreases down the group, reducing power increases down the group.
  • Displacement reaction between halogens: more reactive halogen displaces a less reactive halogen from its compound.
  • Halogens can be tested by seeing how they affect organic solvents; colour and states during displacement reactions (organic solvent).
  • Chlorine, bromine, and iodine have different colours in water and organic solvents (hexane).
  • Halogens are oxidising agents. Halide ions are reducing agents.
  • Halogens react with group 1 and 2 metals to form halide salts.
  • Halogens can undergo disproportionation reactions (simultaneous oxidation and reduction).
  • Chlorine reacts with water and cold dilute alkali to form chlorate(I) compounds (bleach).
  • Chlorine reacts with hot concentrated alkali to form chlorate(V) compounds.
  • Halide ions can be distinguished with silver nitrate test.
  • Reaction with acids can be a redox reaction

Tests and Observations

  • Flame tests identify metals by colour.
  • Test for ammonium ions involve adding sodium hydroxide solution, warming, and observing the release of ammonia gas.
  • Test for sulfate ions involves acidified barium chloride, looking for a white precipitate of barium sulphate.
  • Halogen displacement tests involve using organic solvents and observing colour changes(e.g. in hexane) and the formations of precipitates.
  • Tests for halide ions involve adding silver nitrate solution to produce silver halide precipitates.
  • The colour, solubility in ammonia, and other aspects of the reaction are important observations.
  • Reaction of hydrogen halides with water produce dilute acids.

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Test your knowledge on the properties and reactions of Group 2 elements. This quiz covers their ion formation, reactivity trends, and the behavior of their compounds. Challenge yourself with questions on their applications and unique characteristics.

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