Gravimetric Methods of Analysis

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Questions and Answers

Gravimetric methods of analysis are qualitative methods.

False (B)

In the determination of lead (Pb+2) in water, PbCl2 is used to calculate the amount of Pb+2 in the original solution.

True (A)

Volatilization method involves separating the analyte by converting it into a liquid form.

False (B)

Electro-analytical method separates the analyte by deposition on an electrode using a magnetic field.

<p>False (B)</p> Signup and view all the answers

Gravimetric analysis requires calibration for all apparatus used.

<p>False (B)</p> Signup and view all the answers

Precipitation gravimetry involves converting the analyte to a highly soluble precipitate.

<p>False (B)</p> Signup and view all the answers

Crystalline suspension particles are easily filtered.

<p>True (A)</p> Signup and view all the answers

Particle size of a precipitate is directly proportional to the relative supersaturation of the solution during the precipitation process.

<p>False (B)</p> Signup and view all the answers

In order to promote particle growth, it is advisable to increase the relative supersaturation ratio.

<p>False (B)</p> Signup and view all the answers

It is recommended to precipitate from a dilute solution for experimental control of particle size.

<p>True (A)</p> Signup and view all the answers

Adding precipitating reagents slowly, without stirring, is an effective way to control particle size.

<p>False (B)</p> Signup and view all the answers

To maintain quantitative precipitation, it is recommended to precipitate at a high pH.

<p>False (B)</p> Signup and view all the answers

In the precipitation method for determining calcium in water, oxalic acid is added to the sample to precipitate calcium carbonate.

<p>False (B)</p> Signup and view all the answers

After the precipitate in gravimetric analysis is filtered, it is washed free of impurities.

<p>True (A)</p> Signup and view all the answers

Particle growth occurs when molecules come together to form a stable solid.

<p>True (A)</p> Signup and view all the answers

If nucleation is faster than particle growth, pure crystals with large particles form.

<p>False (B)</p> Signup and view all the answers

Gravimetric precipitating agents react specifically with the analyte in all cases.

<p>False (B)</p> Signup and view all the answers

Particles of large precipitates are difficult to filter and wash.

<p>False (B)</p> Signup and view all the answers

Colloidal suspensions consist of large particles that are visible to the naked eye.

<p>False (B)</p> Signup and view all the answers

Precipitates made up of fine particles are usually purer than those made up of large particles.

<p>False (B)</p> Signup and view all the answers

The physical nature of precipitates is determined by the rate of particle growth only.

<p>False (B)</p> Signup and view all the answers

Large particles in precipitates are generally harder to filter and wash compared to small particles.

<p>False (B)</p> Signup and view all the answers

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