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Questions and Answers
What is the percentage of pyranose in the equilibrium mixture?
What is the result of the reaction between a hydroxyl group of C-5 and the carbonyl oxygen on C-1?
What is the significance of the ring closing reaction in terms of carbon C-1?
What is the byproduct of fermentation in yeast?
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What is the arrangement of -CH2OH and -OH on carbon C-1 in the cis arrangement?
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What is the molecule that bends over in solution to form a ring structure?
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Where does the aerobic breakdown of glucose take place?
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What is the general term for the form of glucose shown in the figure?
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What is the purpose of insulin in the body?
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What is the percentage of the open chain form in the equilibrium mixture?
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What happens to excess glucose in the liver and muscles?
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What is the function of glucagon?
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What is the result of the reaction between the hydroxyl group of C-5 and the carbonyl oxygen on C-1 in terms of the structure of glucose?
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What is the energy source for brain cells?
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What is the result of glycosylation on enzymes?
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What is the significance of the low rate of glycosylation in the presence of glucose?
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What type of bond is formed between two monosaccharide sugars in a disaccharide?
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What is the byproduct of the synthesis process in the formation of disaccharides?
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What is the type of reaction that forms a disaccharide?
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What is formed when a hydroxyl group on C-1 of a glucose molecule reacts with a hydroxyl group on C-2 of fructose?
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What is the term for the bond formed between carbon 1 (C1) of one hexose sugar and carbon 4 (C4) of the second sugar unit?
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What is the type of disaccharide formed by joining two α-glucose molecules?
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What is the term for the removal of a water molecule in the formation of a disaccharide?
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What is the bond referred to in the formation of a disaccharide?
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What is the first step in the conversion of glucose to energy?
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What is the main function of cellulose in plants?
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What is the difference between glucose and glycogen as energy sources?
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What is the composition of cellulose?
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What is the approximate range of glucose units in natural cellulose chains?
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What is the main component of wood?
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What is the main component of cotton?
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What is the structure of cellulose?
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What is the main difference between the structure of cellulose and chitin?
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What type of linkage is present in the polymer of chitin?
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What is the functional group attached to carbon C-2 in chitin?
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What is the repeating unit in the polymer of chitin?
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What is the side chain attached to the nitrogen atom in chitin?
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How many -OH groups are present in each repeating unit of chitin?
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What is the molecular structure of chitin similar to?
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What is the main function of chitin in nature?
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Study Notes
Glucose
- Glucose is a hexose sugar that can exist in both open chain and cyclic forms.
- In solution, glucose is in equilibrium with several cyclic isomers, but primarily exists as a pyranose ring (99%).
- The pyranose ring is formed through a reaction between a hydroxyl group on C-5 and the carbonyl oxygen on C-1.
Structural Forms of Glucose
- The open chain form of glucose is in equilibrium with its cyclic isomers.
- The cyclic forms of glucose can exist as either pyranose (more common) or furanose rings.
- The pyranose ring can have a cis or trans arrangement of the -CH2OH and -OH groups on carbon C-1.
Breakdown of Glucose
- Glucose can be broken down through fermentation (in the absence of oxygen) or aerobic respiration (in the presence of oxygen).
- Fermentation produces carbon dioxide and ethyl alcohol, while aerobic respiration produces carbon dioxide and water.
Biological Relevance of Glucose
- Glucose is an important energy source for cells, particularly brain cells.
- The digestive system breaks down carbohydrates into glucose, which is then absorbed into the bloodstream.
- Insulin and glucagon hormones regulate blood sugar levels by facilitating glucose uptake and storage in cells.
Disaccharides
- Disaccharides are formed through condensation reactions between two monosaccharide sugars.
- The synthesis process involves the formation of a glycosidic bond between carbon 1 of one sugar and carbon 4 of the second sugar.
- Common disaccharides include sucrose, lactose, and maltose.
Maltose
- Maltose is a disaccharide formed by joining two α-glucose molecules through a condensation reaction.
- The reaction removes water and forms an α 1-4 glycosidic bond between the two glucose units.
Cellulose
- Cellulose is a polymer of cellobiose molecules, used for structural support in plant cell walls.
- It is an important polysaccharide found in wood, cotton, and paper.
- Cellulose is a linear polymer composed of glucose units, with a molecular weight ranging from 2,000 to 14,000 glucose units.
Chitin
- Chitin is a polymer of modified glucose units, similar in structure to cellulose.
- It is found in the exoskeletons of insects and crustaceans, and is a major component of fungal cell walls.
- Chitin is composed of repeating units of modified glucose molecules linked through β 1-4 glycosidic bonds.
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Description
This quiz is about the structure of D-Glucose and its reaction with a hydroxyl group in a solution. It involves understanding the molecular composition of glucose and its properties.