Giant Covalent Structures and Graphite

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Questions and Answers

What property makes diamonds particularly useful in cutting tools?

  • High conductivity
  • Solubility in water
  • High hardness (correct)
  • Low melting point

Which aspect of diamond explains its inability to conduct electricity?

  • No free electrons or ions (correct)
  • Presence of free electrons
  • High solubility in solvents
  • Lack of covalent bonds

What characteristic of graphite allows it to be used in pencil leads?

  • Transparency
  • High melting point
  • Ability to dissolve in water
  • Lubricating properties (correct)

Which property of graphite contributes to its use as a material for electrodes in electrolysis?

<p>Good electrical conductivity (C)</p> Signup and view all the answers

How do carbon nanotubes compare to graphite in terms of structure?

<p>They are arranged in tubes rather than layers. (D)</p> Signup and view all the answers

What is a key feature of the covalent bonds in diamond?

<p>Each carbon atom is bonded to four other carbon atoms. (C)</p> Signup and view all the answers

What distinguishes the electronic structure of graphite from that of diamond?

<p>Graphite allows electron flow while diamond does not. (D)</p> Signup and view all the answers

Which of the following best describes the visual properties of diamond?

<p>Colourless and lustrous (C)</p> Signup and view all the answers

What characteristic of giant covalent structures leads to their very high melting points?

<p>Strong covalent bonds (D)</p> Signup and view all the answers

Which of the following best describes the conductivity of graphite?

<p>It conducts electricity due to free electrons (C)</p> Signup and view all the answers

What distinguishes diamond from graphite in terms of atomic bonding?

<p>Diamond atoms are bonded to four other carbon atoms (C)</p> Signup and view all the answers

Which property is NOT characteristic of diamond?

<p>Softness (C)</p> Signup and view all the answers

Why is graphite used as a lubricant?

<p>The layers can slide over each other (C)</p> Signup and view all the answers

What is a key feature of silica in relation to diamond?

<p>It has a similar structure to diamond (C)</p> Signup and view all the answers

Which allotropes of carbon exhibit a similar structural property to diamond?

<p>Silica and fullerenes (B)</p> Signup and view all the answers

What is the primary reason silicon is classified as a semiconductor?

<p>It has a variable electrical conductivity (D)</p> Signup and view all the answers

Flashcards

Giant covalent structures

Structures with many atoms bonded by strong covalent bonds, forming a regular lattice.

High melting points

Giant covalent structures require a lot of energy to break bonds, resulting in very high melting points.

Graphite

A form of carbon where each atom bonds with three others, allowing layers to slide and conduct electricity.

Diamond

A hard form of carbon where each atom bonds with four others, forming a very hard structure with no conductivity.

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Electrical conductivity in graphite

Graphite conducts electricity due to free 'spare' delocalised electrons between layers.

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Delocalised electrons

Electrons that are not bound to a single atom and can move freely, as in graphite's layered structure.

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Silica

Silicon dioxide, similar to diamond in structure and properties, but made of silicon and oxygen.

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Allotropes of carbon

Different structural forms of pure carbon, including diamond, graphite, and fullerenes.

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Covalent bonds

Strong connections formed between carbon atoms in allotropes.

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Insoluble

A property meaning it does not dissolve in water.

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Carbon nanotubes

Molecular-scale tubes of carbon that can conduct electricity and have a very high melting point.

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Electrodes

Conductive materials that facilitate the flow of electricity in processes like electrolysis; graphite is often used.

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Study Notes

Giant Covalent Structures

  • Giant covalent structures consist of many atoms held together by strong covalent bonds, forming a giant regular lattice structure.

  • High melting points are a defining characteristic due to the extensive covalent bonds that need to be broken.

  • Electrical conductivity varies, with some materials like diamond being non-conductive and others like graphite being conductive due to delocalized electrons. Silicon is a semiconductor.

Graphite

  • Graphite is an allotrope of carbon with carbon atoms forming covalent bonds with three other carbon atoms.

  • Each carbon atom has one delocalized electron, creating a layered structure enabling layer slippage and making graphite soft/easy to use as a lubricant.

  • Delocalized electrons contribute to graphite's conductivity, making it suitable as electrodes.

  • Despite softness, the strong covalent bonds within each layer give graphite high melting and boiling points.

  • Graphite is black, shiny, opaque, and slippery.

  • It is used in pencils and lubricants due to its layered structure.

Diamond

  • Diamond is an allotrope of carbon where each carbon atom is bonded to four other carbon atoms.

  • Diamond's rigid tetrahedral structure makes it very hard and has a very high melting point.

  • It is insoluble in water and does not conduct electricity because there are no delocalized electrons.

  • High hardness and high melting point make diamond suitable for cutting tools.

  • Diamond is colourless, transparent, lustrous (sparkling).

Silica

  • Silica (silicon dioxide) shares structural similarities with diamond and has similar properties like hardness and high melting points.

  • Silica contains silicon and oxygen atoms instead of carbon.

Allotropes of Carbon

  • Diamond, graphite, and fullerenes (including nanotubes and buckyballs) are different allotropes of pure carbon.

  • Covalent bonds within their structures, however, the arrangements of atoms result in distinct properties.

Nanotubes

  • Nanotubes are fullerene structures resembling graphite's layered structure.

  • High melting point due to strong covalent bonds, similar to graphite and diamond.

  • Conductivity due to delocalized electrons within the carbon structure.

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