General Chemistry I: Quantum Numbers & Electron Config
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Questions and Answers

What does the Aufbau principle state regarding electron configuration?

  • Electrons fill only the outermost shell before any inner shells.
  • Electrons can occupy the same orbital with identical spins.
  • Electrons occupy orbitals in order of increasing energy. (correct)
  • Electrons fill all orbitals before moving to the next energy level.

According to Hund's rule, how should electrons be placed in orbitals of equal energy?

  • Electrons should occupy orbitals in a random manner.
  • Electrons are paired in the same orbital first.
  • Electrons must occupy the lowest energy orbital available.
  • Electrons are evenly distributed among orbitals before pairing. (correct)

What is indicated by the superscript in the electron configuration notation?

  • The total number of orbitals occupied by electrons.
  • The energy level of the orbital being filled.
  • The number of electrons in a specific set of orbitals. (correct)
  • The stability of the electron configuration.

Which statement is true regarding the valence shell electron configuration?

<p>It only mentions electrons in the outermost shell. (D)</p> Signup and view all the answers

How is the abbreviated electron configuration represented?

<p>By enclosing the last filled shell's element in brackets. (D)</p> Signup and view all the answers

What do quantum numbers primarily describe about electrons in an atom?

<p>The energy, size, shape, and orientation of the electrons (A)</p> Signup and view all the answers

Which quantum number specifies the shape of the orbital?

<p>Angular quantum number (l) (B)</p> Signup and view all the answers

According to the Pauli exclusion principle, what must be true about electrons in an atom?

<p>No two electrons can have identical values for all four quantum numbers. (B)</p> Signup and view all the answers

How many orbitals are present in an s subshell?

<p>1 (C)</p> Signup and view all the answers

Which quantum number indicates the orientation of an orbital in space?

<p>Magnetic quantum number (ml) (D)</p> Signup and view all the answers

Flashcards

Quantum Numbers

Four numbers used to describe each electron in an atom.

Principal Quantum Number (n)

Positive integer specifying electron energy & orbital size.

Angular Quantum Number (l)

Describes the shape of an orbital.

Pauli Exclusion Principle

No two electrons have the same four quantum numbers.

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Magnetic Quantum Number (ml)

Specifies orbital orientation in space.

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Electron Configuration

The arrangement of electrons in the orbitals of an atom.

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Aufbau Principle

A set of rules that dictates the filling order of electron orbitals, primarily from lowest to highest energy.

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Orbital Diagram

A visual representation of electron placement, using boxes to signify orbitals and arrows to show electron spin.

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Abbreviated electron configuration

A shorthand way to write electron configurations, using the symbol of a noble gas to represent filled inner shells.

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Valence Shell Electron Configuration

Focuses on the outermost electron shell of an atom, representing only the valence electrons.

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Study Notes

General Chemistry I - Lecture Notes

  • Course title: General Chemistry I
  • Instructor: Dr. Mahmoud A. A. Ibrahim
  • Department: Chemistry, Faculty of Science, Minia University
  • Email: [email protected]
  • Course code: CH101

Lecture 2: Quantum Numbers & Electron Configuration

  • Topic: Quantum Numbers

    • Each electron in an atom is described by four quantum numbers.
    • Principle quantum number (n): Specifies the energy level and size of the electron's orbital (positive integer, excluding zero).
    • Angular quantum number (l): Specifies the shape of the electron's orbital. It also affects the subshell energy (integers from 0 to n-1). Subshells are labelled s, p, d, f (s=0, p=1, d=2, f=3).
    • Magnetic quantum number (ml): Specifies the orientation of the orbital in space(-l to +l). Determines the number of orbitals in each subshell (2l + 1 orbitals) The s subshell has 1 orbital, the p subshell has 3, the d subshell has 5, and the f subshell has 7.
    • Spin quantum number (ms): Specifies electron spin (equal to +1/2 or -1/2). Electrons in the same orbital must have opposite spins.
  • Topic: Pauli Exclusion Principle

    • No two electrons in an atom can have the same set of four quantum numbers.
    • No more than two electrons can occupy the same atomic orbital.
    • Electrons within the same orbital must have opposite spins.
  • Topic: Electron Configuration

    • Aufbau principle: Electrons fill orbitals in increasing order of energy levels (1s, 2s, 2p, 3s, 3p...).
    • The distribution of electrons among the orbitals of an atom is called the electron configuration.
    • Orbital diagrams: Diagrams that show the electron placement in each orbital within a subshell
    • Hund's rule: Electrons occupy orbitals of equal energy singly before they pair up.
  • Topic: Abbreviated Electron Configurations

    • Abbreviated electron configurations use the noble gas preceding that element, followed by the electron configuration of the remaining electrons.
  • Topic: Valence Shell Electron Configuration

    • Configuration focusing on the outer shell electrons (valence shell)
  • Topic: Unexpected Electron Configurations

    • Some elements have unexpected electron configurations (e.g., Cr and Cu). This is due to special stability that arises when specific subshells are half-filled or completely filled.

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Explore the fundamental concepts of quantum numbers and electron configuration in this General Chemistry I lecture. Understand the significance of each quantum number, including principal, angular, magnetic, and spin quantum numbers, and their roles in defining electron behavior in atoms.

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