General Chemistry 2 - Nonelectrolyte & Electrolyte Solutions
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Questions and Answers

Which substance will cause the greatest boiling point elevation in a solution at a 1m concentration?

  • 1m CaCl2
  • 1m C6H12O6
  • 1m AlCl3 (correct)
  • 1m NaCl
  • What is the primary factor affecting colligative properties of solutions?

  • Concentration of solute particles (correct)
  • Molar mass of the solute
  • Identity of the solute
  • Type of solvent used
  • Which of the following correctly classifies NaCl and C6H12O6 in terms of their impact on colligative properties?

  • NaCl is a strong electrolyte; C6H12O6 is a strong electrolyte
  • Both are non-electrolytes
  • NaCl is a strong electrolyte; C6H12O6 is a non-electrolyte (correct)
  • NaCl is a non-electrolyte; C6H12O6 is a strong electrolyte
  • How do ionic compounds like CaCl2 affect the number of solute particles in a solution compared to molecular compounds?

    <p>They increase the number of solute particles</p> Signup and view all the answers

    If 1m solutions of NaCl and C6H12O6 are compared, which property will be more affected by NaCl's dissociation?

    <p>All of the above</p> Signup and view all the answers

    Which of the following statements about colligative properties is true?

    <p>They depend on the total number of solute particles in solution</p> Signup and view all the answers

    Which pair of substances, when dissolved in water, will exhibit the least freezing point depression at the same molality?

    <p>1m C6H12O6 and 1m NaCl</p> Signup and view all the answers

    In assessing the effects of solutes on colligative properties, how are electrolytes different from non-electrolytes?

    <p>Electrolytes dissociate into ions, increasing particle count</p> Signup and view all the answers

    What mainly determines the colligative properties of a solution?

    <p>The total concentration of solute particles</p> Signup and view all the answers

    What is the formula for calculating molality?

    <p>m = mole solute / kg solvent</p> Signup and view all the answers

    Which statement correctly describes why adding salt to boiling water increases its temperature?

    <p>Salt increases the number of particles, requiring more energy to reach the boiling point.</p> Signup and view all the answers

    How much does the boiling point of water increase when 5 g of C12H22O11 is added?

    <p>0.041 °C</p> Signup and view all the answers

    What happens to the melting point of water when salts are added?

    <p>The melting point decreases, allowing water to freeze at lower temperatures.</p> Signup and view all the answers

    What is the boiling point of the solution when 85.0 g of Sodium acetate is dissolved in 356 mL of water?

    <p>102.2124 °C</p> Signup and view all the answers

    What type of solution does NOT dissociate into ions when dissolved in a solvent?

    <p>Nonelectrolyte solutions</p> Signup and view all the answers

    What is the effect of colligative properties on boiling point elevation?

    <p>It increases the boiling point based solely on the number of solute particles.</p> Signup and view all the answers

    What is the change in temperature (ΔTb) when 85.0 g of Sodium acetate is added to the solution?

    <p>2.124 °C</p> Signup and view all the answers

    What condition is required for freezing point depression to occur?

    <p>The solvent must be pure.</p> Signup and view all the answers

    In the context of nonelectrolyte and electrolyte solutions, the presence of more solute particles generally leads to which result?

    <p>Increased boiling point and decreased freezing point</p> Signup and view all the answers

    What relationship exists between molality and the freezing point depression?

    <p>They are directly proportional.</p> Signup and view all the answers

    Why do ice vendors add salt to the ice used in ice cream containers?

    <p>To lower the freezing point of the ice, keeping the temperature low.</p> Signup and view all the answers

    If 100 g of NaCl were added to 1 kg of water, what effect would it have on the boiling point of water?

    <p>It would slightly increase the boiling point.</p> Signup and view all the answers

    The calculation of molar mass from colligative properties is primarily affected by which factor?

    <p>The boiling point elevation and freezing point depression values</p> Signup and view all the answers

    What is the boiling point constant (Kb) for water used in these calculations?

    <p>0.512 °C/m</p> Signup and view all the answers

    What is the change in boiling point (ΔTb) when 15.0 g of an organic compound is dissolved in carbon tetrachloride resulting in a boiling point of 84.36°C?

    <p>7.64°C</p> Signup and view all the answers

    Using the boiling point elevation equation, if Kb for carbon tetrachloride is 5.02°C/m and the observed boiling point elevation is 7.64°C, what is the molality of the solution?

    <p>1.52 m</p> Signup and view all the answers

    How many moles of solute are present when 220 g of carbon tetrachloride is dissolved with a molality of 1.522 mol/kg?

    <p>0.3348 mol</p> Signup and view all the answers

    What is the molar mass of a solute if 15.00 g of it corresponds to 0.3348 moles?

    <p>44.80 g/mol</p> Signup and view all the answers

    How many grams of Pyrazine (C4H4N2) are needed to lower the freezing point of carbon tetrachloride by 5.6°C?

    <p>29.633 g</p> Signup and view all the answers

    Given a molar mass of 80.0896 g/mol for Pyrazine, what is the total mass if 0.37 mol is to be dissolved?

    <p>29.633 g</p> Signup and view all the answers

    If the freezing point depression constant (Kf) for carbon tetrachloride is 30.0°C/m, what is the relationship between freezing point depression and molality?

    <p>Δt = Kf x m</p> Signup and view all the answers

    What substance is being dissolved in carbon tetrachloride in Sample Problem 2 to achieve freezing point depression?

    <p>Pyrazine</p> Signup and view all the answers

    What is the boiling point of the solution when 0.20 grams of eugenol is dissolved in 12.0 grams of benzene?

    <p>80.70 °C</p> Signup and view all the answers

    How does the freezing point of a solution containing benzoic acid compare to that of pure benzene?

    <p>It will be lower than 5.50 °C</p> Signup and view all the answers

    What formula is used to calculate the boiling point elevation of a solution?

    <p>ΔT = i * Kb * m</p> Signup and view all the answers

    What is the molal freezing point depression constant (Kf) of water used for calculations?

    <p>1.86 °C/m</p> Signup and view all the answers

    In the freezing point depression calculations, which component is affected by the addition of the solute?

    <p>The freezing point of the solvent</p> Signup and view all the answers

    When calculating the molecular weight of a solute using freezing point depression, what information is required?

    <p>Mass of solute and Kf of solvent</p> Signup and view all the answers

    What would be the effect on the boiling point of a solution when more solute is dissolved?

    <p>The boiling point increases</p> Signup and view all the answers

    If 12g of glucose is dissolved in 200g of water, how much does the boiling point increase?

    <p>0.5120 °C</p> Signup and view all the answers

    Study Notes

    Solutions Overview

    • Solutions consist of solute (substance dissolved) and solvent (substance doing the dissolving).
    • Properties of solutions, including colligative properties, depend on the amount of solute present.
    • Colligative properties are influenced by the number of solute particles, not their identity.

    Colligative Properties

    • Colligative properties include boiling point elevation and freezing point depression.
    • These properties demonstrate how adding a solute (like salt) changes boiling and freezing points of solvents.
    • Example: Salt added to water raises its boiling point and lowers its freezing point.

    Electrolyte vs. Nonelectrolyte

    • Electrolytes (e.g., NaCl) dissociate into ions, increasing the number of particles in solution.
    • Nonelectrolytes (e.g., sucrose) do not dissociate, resulting in fewer particles in the solution.
    • The effect on boiling and freezing points is greater with electrolytes due to increased particle count.

    Calculating Colligative Properties

    • Molality (m) is calculated as the number of moles of solute per kilogram of solvent.
      • Formula: Molality = moles of solute / kg of solvent
    • Boiling point elevation (ΔTb) can be calculated using ΔTb = Kb x m.
    • Freezing point depression and its relationship to the colligative properties are similar to boiling point calculations.

    Example Calculations

    • Boiling Point Elevation Example:

      • For a solution with 5 g of sucrose in 180 g of water:
        • Molality = 0.081 m, Kb for water = 0.512 °C/m
        • ΔTb = Kb x m = 0.041 °C, resulting in a new boiling point of 100.041 °C.
    • Freezing Point Depression Example:

      • Adding a non-volatile solute lowers the vapor pressure and the freezing point.
      • For a 15 g compound in 220 g carbon tetrachloride:
        • ΔTb = 7.64 °C, leading to a molar mass of 44.80 g/mol after calculations.

    Exercise Problems

    • Practice involves solving for boiling points and freezing points with given constants and solute quantities.
    • Activities include calculating specific scenarios such as the effects of different solutes on boiling and freezing points.

    Assessments

    • Students are tasked with determining molecular weights, boiling point elevations, and freezing point depressions through problem-solving scenarios.
    • These problems reinforce understanding of colligative properties and their dependence on solute concentrations.

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    Quiz Team

    Description

    This quiz focuses on the concepts of nonelectrolyte and electrolyte solutions covered in General Chemistry 2 for grades 11 and 12. It is based on Module 5 from Quarter 3, helping students to understand the distinctions and applications of these types of solutions. Test your knowledge and prepare for your examinations!

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