General Chemistry 1 - Unit 4: The Gas Phase
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Questions and Answers

What state of matter expands freely to fill the whole container?

gas

What are common units used to express volume?

  • Gallons
  • Liters (correct)
  • Pints
  • Miles
  • Pressure is defined as a force exerted by the substance per unit area.

    True

    What is the absolute zero temperature in Celsius?

    <p>-273.15</p> Signup and view all the answers

    To convert Celsius to Kelvin, you must add __________.

    <p>273.15</p> Signup and view all the answers

    What happens to the pressure of gas when the volume increases?

    <p>Pressure decreases</p> Signup and view all the answers

    What is Boyle's Law equation?

    <p>P1V1 = P2V2</p> Signup and view all the answers

    Volume is __________ proportional to applied pressure when temperature is constant.

    <p>inversely</p> Signup and view all the answers

    If the pressure of helium gas is 210 kPa at a volume of 4.0 L, what will the pressure be at a volume of 2.5 L?

    <p>336 kPa</p> Signup and view all the answers

    Who arranged the known elements in order of their atomic masses?

    <p>Dmitri Mendeleev and Lothar Meyer</p> Signup and view all the answers

    What is electronegativity a measure of?

    <p>An atom's ability to attract a pair of electrons when bonded to another atom</p> Signup and view all the answers

    Which element has the highest electronegativity?

    <p>Fluorine (F)</p> Signup and view all the answers

    What is electron affinity?

    <p>The measure of the energy change that occurs when an atom gains a single electron and forms a negative ion</p> Signup and view all the answers

    Chlorine has the greatest tendency to gain an electron.

    <p>True</p> Signup and view all the answers

    What is ionization energy?

    <p>The energy needed to remove an atom's most loosely held electron</p> Signup and view all the answers

    As you go from left to right of the periodic table, the elements' ionization energy, electron affinity, and electronegativity _______________.

    <p>increases</p> Signup and view all the answers

    As you go from top to bottom of the periodic table, the elements' ionization energy, electron affinity, and electronegativity _______________.

    <p>decreases</p> Signup and view all the answers

    How many periods are there in the periodic table?

    <p>7</p> Signup and view all the answers

    Which groups are classified as s-block elements?

    <p>Group 1A and 2A</p> Signup and view all the answers

    Match the following blocks with their classifications:

    <p>s-block = Group A (1A) 2 (IIA) p-block = Group 13 (IIIA) and 18 (VIIIA) d block = Group 3-12 f block = Lanthanoids and actinoids</p> Signup and view all the answers

    Study Notes

    General Chemistry 1 - Unit 4: The Gas Phase

    • Unit covers the gas phase, gas laws, and kinetic molecular theory
    • Includes chapters 9 (Gas Law) and 10 (Kinetic Molecular Theory)

    Describing Gases

    • Gases expand to fill their containers
    • Gases have no fixed shape or volume

    Learning Outcomes

    • Students should be able to describe gases and explain postulates of kinetic theory as applied to gases
    • Relate postulates to the properties of gases

    Fundamentals of Gases

    • Key properties include volume, pressure, temperature, and mole
    • Volume is the 3-dimensional space occupied by matter
    • Common volume units: Liters (L), cubic meters (m³), milliliters (mL)
    • Pressure is exerted force per unit area on another substance
    • Common pressure units: atm, torr, Pa, kPa
    • Other pressure units: lbs per square foot, lbs per square inch, kg per square centimeter
    • Temperature measures kinetic energy of gas molecules
    • Common temperature units: Celsius (°C), Fahrenheit (°F), Kelvin (K)
    • For gas calculations, all temperatures must be in Kelvin

    Mole

    • Mole is the amount of substance containing the same number of particles (Avogadro's number)
    • Molecular weight is used to convert measured mass to moles

    Pressure and Volume: Boyle's Law

    • At constant temperature, volume is inversely proportional to pressure
    • Boyle's Law: P1V1 = P2V2

    Temperature and Volume: Charles's Law

    • At constant pressure, volume is directly proportional to temperature (Kelvin)
    • Charles's Law: V1/T1 = V2/T2

    Temperature and Pressure: Gay-Lussac's Law

    • At constant volume, pressure is directly proportional to temperature (Kelvin)
    • Gay-Lussac's Law: P1/T1 = P2/T2

    Ideal Gas Laws

    • Ideal Gas Law: PV = nRT
    • P = pressure
    • V = volume
    • n = number of moles
    • R = ideal gas constant (depends on pressure units)
    • T = temperature (Kelvin)
    • Standard pressure units: 1 atm = 760 torr = 760 mmHg = 101.3 kPa = 14.7 psi
    • Ideal gas constant values: 8.314 J/(mol·K) or 0.0821 L·atm/(mol·K)

    Dalton's Law of Partial Pressures

    • Total pressure of a gas mixture equals the sum of partial pressures of individual gases
    • Ptotal = P1 + P2 + P3 + ...

    Kinetic Molecular Theory

    • Defines pressure as force exerted per unit area on container walls
    • At constant temperature, changing volume changes the force per unit area and thus the pressure
    • Explains the relationship between Pressure, Volume, and Temperature of ideal gases

    Examples of Temperature & Kinetic Energy

    • Higher temperature generally means higher average kinetic energy of gas particles.

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