General Chemistry 1 Practice Exam 1

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Questions and Answers

How many tungsten atoms are contained in a jewelry piece with a diameter of 12.3mm?

  • 2.08 x 1027 atoms
  • 4.92 x 1023 atoms (correct)
  • 6.14 x 1022 atoms
  • 1.66 x 1028 atoms

What is the density of acetone in g/cm3?

  • 7.91 x 10-4 g/cm3
  • 7.91 x 10-1 g/cm3 (correct)
  • 7.91 x 107 g/cm3
  • 7.91 x 103 g/cm3

Which species does NOT have the same number of neutrons as 31P3-?

  • 35K+ (correct)
  • 31P
  • 34Ar
  • 29Si

What is the correct number of significant figures for the result of 114.mL – 7.× 101 mL?

<p>44.mL (D)</p> Signup and view all the answers

How is the ordering of energy levels for GS, ES-A, and ES-B arranged from lowest energy to highest energy?

<p>GS &lt; ES-A &lt; ES-B (A)</p> Signup and view all the answers

Which statement about a pure nickel sphere and a pure silver sphere with identical volumes is true?

<p>They have the same total number of protons (C)</p> Signup and view all the answers

What is the volume of a sphere with a diameter of 12.3 mm?

<p>5.66 cm³ (C)</p> Signup and view all the answers

Which molecule transitions first from ground state to excited electronic state before emitting light at 510 nm?

<p>GS (A)</p> Signup and view all the answers

What changes when 12C is replaced by 13C in a molecule?

<p>The total number of neutrons in the molecule (A)</p> Signup and view all the answers

Which electronic transition in a hydrogen atom emits a photon with sufficient frequency to activate a specific molecular switch?

<p>n = 4 to n = 2 (A), n = 2 to n = 1 (C), n = 6 to n = 3 (D)</p> Signup and view all the answers

What is the mass of a mole of electrons in g/mol?

<p>5.49 × 10-4 g/mol (A)</p> Signup and view all the answers

Which quantity is NOT dependent on the wavelength of a photon of light?

<p>The intensity (C)</p> Signup and view all the answers

Which element could have an atom mass of 5.148 x 10-23 g?

<p>He (C)</p> Signup and view all the answers

Which sample consists of the greatest number of atoms?

<p>1.5 g graphite (B)</p> Signup and view all the answers

How should the average atomic mass of magnesium be estimated from its isotopes' abundances?

<p>(79  24 amu + 10  25 amu + 11  26 amu) / 100 (A)</p> Signup and view all the answers

What is the mass of water lost from the sample after drying, reported with the correct number of significant figures?

<p>4.61 g (C)</p> Signup and view all the answers

In what way does the stability of an electron in the n = 1 state of a hydrogen atom differ from when it is in the n = 2 state?

<p>The n = 1 electron is more stable because it has a lower energy than in n = 2. (C)</p> Signup and view all the answers

What does the value 10.81 on the periodic table for Boron represent?

<p>An average Boron atom weighs 10.81 amu; a mole of average Boron atoms weighs 10.81 g. (A)</p> Signup and view all the answers

When converting the first ionization energy of Scandium from J/atom to kJ/mol, what is the correct conversion result?

<p>6.32 x 102 kJ/mol (A)</p> Signup and view all the answers

What scientific principle is demonstrated by diffraction patterns emerging from a beam of electrons passing through two slits?

<p>The wave-like behavior of matter (C)</p> Signup and view all the answers

Which statement about the addition of Zinc as a micronutrient in commercially produced foods is accurate?

<p>Zinc is required for proper immune function and growth. (C)</p> Signup and view all the answers

How does the energy of an electron in a hydrogen atom change with an increase in principal quantum number (n)?

<p>The energy increases as n increases. (D)</p> Signup and view all the answers

What is the significance of the value 10.81 listed for Boron in the periodic table?

<p>It is the atomic mass of Boron, averaged over all its isotopes. (A)</p> Signup and view all the answers

What is the recommended daily value of zinc, in mg?

<p>44 mg (D)</p> Signup and view all the answers

If the volume of a cell is approximately $1.0 imes 10^3 , ext{μm}^3$, what is the typical volume of the cell nucleus assuming it is about 10% of the total cell volume?

<p>10 μm³ (A)</p> Signup and view all the answers

What is the density of DNA in g/cm³?

<p>1.7 g/cm³ (C)</p> Signup and view all the answers

Why does the number density of Titanium (Ti) remain lower than that of Beryllium (Be) despite Ti having a higher density?

<p>Ti has a larger atomic volume. (B)</p> Signup and view all the answers

What is the mass of DNA inside a typical cell nucleus in grams?

<p>6.5 × 10^-9 g (B)</p> Signup and view all the answers

What is the wavelength of the photon emitted during the electronic transition in the hydrogen atom?

<p>1.282 μm (D)</p> Signup and view all the answers

If the number density of Silicon (Si) is to be calculated as atoms per cm³, which of the following must be known?

<p>Density, atomic mass, and volume. (C)</p> Signup and view all the answers

If an electronic transition in hydrogen moves from n = 5 to a lower state, what factor could determine the new quantum state?

<p>The wavelength of the emitted photon. (D)</p> Signup and view all the answers

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Study Notes

Practice Exam 1 Overview

  • The exam tests various fundamental concepts in General Chemistry.
  • Key topics include density conversions, atomic structure, molecular transitions, and isotopes.

Density and Conversions

  • Acetone density: 791 kg/m³ converts to 0.791 g/cm³.
  • Tungsten density: 19.25 g/cm³; volume formula V = (4/3)πr³ helps find the number of atoms in a jewelry piece.
  • Loss of water mass during drying reviewed: Initial and final masses reported affect significant figure calculations.

Atomic Structure and Isotopes

  • Isotopes display different neutron counts compared to standard elements: 31P³⁻ compared with other elements like K⁺ and Si.
  • Isotopic labeling used in molecular studies; substitution of 13C for 12C changes neutron count but retains proton and electron totals.

Electronic Transitions and Energy States

  • Green Fluorescent Protein (GFP) absorbs light at 395 nm, transitioning from ground state (GS) to excited states (ES-A, ES-B). Energy hierarchy: GS < ES-A < ES-B.
  • Hydrogen atom transitions include various energy states; transitions n = 2 to n = 1 are significant for high-frequency photon emissions.

Calculations and Formula Applications

  • Conversion of electron mass (9.11 x 10^-31 kg) to molar mass yields 5.49 x 10^-4 g/mol.
  • Average atomic mass calculations for elements consider percent natural abundances, applied to Magnesium's isotopes.

Significant Figures and Empirical Measurements

  • Performing calculations with significant figures is crucial, especially in volume and mass differences.
  • Specific density and mass allow comparison of atomic number densities among elements like Be, Si, and Ti.

Micronutrient Content

  • Zinc daily value calculated from cereal content illustrates the importance of nutrient labeling.

Work-Out Problems

  • Density and volume calculations for nucleic DNA provide practical applications of density formulas and significant figures.
  • Electronic transitions in hydrogen can be used to infer higher frequency transitions through wavelength calculations.

General Observations

  • Understanding fundamental principles of chemistry is essential for solving practical problems.
  • Mastery of significant figures, density, isotopes, and atomic structure is critical for exam preparation.

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