Fundamentals of Chemistry: Atoms and Elements
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Questions and Answers

What defines an element in terms of atomic structure?

  • Atoms with equal numbers of neutrons and protons
  • Atoms with equal numbers of electrons and neutrons
  • Atoms with different numbers of protons (correct)
  • Atoms with different electron configurations
  • Which particle of the atom has a neutral charge?

  • Neutron (correct)
  • Proton
  • Electron
  • Alpha particle
  • Why are atoms considered neutrally charged?

  • Neutrons negate the positive charges of protons
  • They contain only protons and neutrons
  • Electrons are more massive than protons
  • The charges of protons and electrons cancel each other (correct)
  • What determines the position of an element in the Periodic Table?

    <p>Electron organization (C)</p> Signup and view all the answers

    What is true about isotopes?

    <p>They are atoms of the same element with different neutron counts (A)</p> Signup and view all the answers

    Which particle of the atom has the least mass?

    <p>Electron (D)</p> Signup and view all the answers

    What charge does a proton carry?

    <p>Positive (C)</p> Signup and view all the answers

    How are hydrogen isotopes categorized?

    <p>Based on their atomic mass (A)</p> Signup and view all the answers

    What does the unit 'molar' specifically represent?

    <p>The concentration of a substance in moles per liter (D)</p> Signup and view all the answers

    Which statement correctly distinguishes between moles and molarity?

    <p>Moles quantify amount of substance, while molarity measures concentration. (D)</p> Signup and view all the answers

    In the equation C6H12O6 + 6O2 → 6CO2 + 6H2O, if there is 1 mol of glucose involved, how many moles of oxygen are required?

    <p>6 mol (A)</p> Signup and view all the answers

    If a solution has a molarity of 5M, what is its concentration in terms of moles per liter?

    <p>5 mol/L (A)</p> Signup and view all the answers

    What is a key aspect of distinguishing 'moles' and 'molarity'?

    <p>Moles measure total amount, while molarity relates to the ratio of moles per volume. (C)</p> Signup and view all the answers

    What does the atomic number of an element indicate?

    <p>The number of protons in the element (A)</p> Signup and view all the answers

    What is the molecular mass of water (H2O)?

    <p>18.02 (C)</p> Signup and view all the answers

    Which of the following best describes the relationship between atomic mass and atomic number?

    <p>Atomic mass is always greater than atomic number (D)</p> Signup and view all the answers

    What does Avogadro's Number represent?

    <p>The number of particles in one mole of any substance (A)</p> Signup and view all the answers

    Which of the following is true about groups in the periodic table?

    <p>They represent elements with similar properties (D)</p> Signup and view all the answers

    How do you calculate the amount in moles from mass?

    <p>Amount (in grams) / relative molecular mass (D)</p> Signup and view all the answers

    What distinguishes elements like Hydrogen and Helium?

    <p>They contain different numbers of protons (D)</p> Signup and view all the answers

    What is the molecular mass of carbon dioxide (CO2)?

    <p>44.01 (C)</p> Signup and view all the answers

    What is the definition of a one molar (1M) solution?

    <p>1 mole of solute per 1 liter of solvent (C)</p> Signup and view all the answers

    Which of the following statements regarding electron orbitals is true?

    <p>Each orbital can hold a maximum of 2 electrons. (C)</p> Signup and view all the answers

    How do elements in the same group of the periodic table compare?

    <p>They have similar chemical properties. (A)</p> Signup and view all the answers

    What is the primary goal of electron interactions within molecules?

    <p>To increase the molecules' stability. (C)</p> Signup and view all the answers

    Which statement best describes the position of electrons in an atom?

    <p>Electrons exist in specific regions called orbitals within shells. (C)</p> Signup and view all the answers

    What defines a subshell in an atom?

    <p>A group of equivalent orbitals (D)</p> Signup and view all the answers

    Which shell has the highest number of orbitals?

    <p>3rd shell (D)</p> Signup and view all the answers

    In the context of electron configuration, what do core electrons refer to?

    <p>Electrons in filled shells closest to the nucleus (B)</p> Signup and view all the answers

    What does the group number in the Periodic Table indicate?

    <p>The number of valence electrons for the element (C)</p> Signup and view all the answers

    According to the octet rule, how can atoms achieve stability?

    <p>By having filled s and p orbitals for their valence electrons (A)</p> Signup and view all the answers

    What is the electron configuration of Fluorine?

    <p>1s22s22p5 (A)</p> Signup and view all the answers

    What does a Lewis Dot structure illustrate?

    <p>The valence electrons of an element (A)</p> Signup and view all the answers

    Which shell fills with electrons before the others according to the energy level?

    <p>Shells closest to the nucleus fill first (C)</p> Signup and view all the answers

    What do noble gases have that contributes to their stability?

    <p>Filled outer p orbitals (C)</p> Signup and view all the answers

    Which factor causes electronegativity to increase across a period?

    <p>Greater number of protons (D)</p> Signup and view all the answers

    What is the relationship between electronegativity and the type of bond formed?

    <p>Electronegativity differences indicate bond polarity (D)</p> Signup and view all the answers

    What primarily determines the reactive properties of an element?

    <p>The number of valence electrons it contains (A)</p> Signup and view all the answers

    How does atomic radius affect electronegativity down a group in the periodic table?

    <p>Increases due to increased electron shielding (C)</p> Signup and view all the answers

    What is the function of Avogadro's number in chemistry?

    <p>It relates molecular mass to the number of moles (B)</p> Signup and view all the answers

    What does a filled outer p orbital in an atom signify?

    <p>The atom is chemically inert (B)</p> Signup and view all the answers

    Which of the following statements is true regarding chemical properties of elements?

    <p>They are related to the arrangement of electrons (A)</p> Signup and view all the answers

    Flashcards

    Atomic Structure

    Atoms consist of a central nucleus containing protons and neutrons, surrounded by orbiting electrons.

    Proton

    Positively charged particle found in the atom's nucleus.

    Neutron

    Neutral particle found in the atom's nucleus.

    Electron

    Negatively charged particle orbiting the atom's nucleus.

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    Element

    Atoms with a specific number of protons.

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    Isotope

    Atoms of the same element with different numbers of neutrons.

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    Atomic Mass Unit (amu)

    A unit of measurement for atomic mass, where both protons and neutrons are 1 amu.

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    Neutral Atom

    An atom with an equal number of protons and electrons, resulting in a net charge of zero.

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    Mole (mol)

    A unit of the amount of a substance.

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    Molarity (M)

    A unit of concentration, equal to moles of solute per liter of solution.

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    Mole vs. Molarity

    Mole measures the amount of substance, while Molarity measures the concentration of the substance. This is a critical distinction.

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    Units of Molarity

    Molarity is expressed as moles per liter (mol/L), conventionally written as 'M'.

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    Chemical Equation

    Shows the reactants and products in a chemical reaction, including their mole ratios.

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    Atomic Mass

    The mass of an atom, equal to the sum of the protons and neutrons in the atom's nucleus.

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    Atomic Number

    The number of protons in the nucleus of an atom.

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    Molecular Mass

    The sum of the atomic masses of all atoms in a molecule.

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    Mole

    A unit of measure representing 6.02 x 10^23 particles of a substance.

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    Avogadro's Number

    6.02 x 10^23, the number of particles in a mole.

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    Relative Molecular Mass (RMM)

    The ratio of the mass of a molecule to the mass of 1/12th of a carbon-12 atom.

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    Periodic Table

    A table that organizes elements by atomic number and properties.

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    Subshell

    A group of equivalent orbitals within a shell, such as the 2s and 2p subshells in the second shell.

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    What is an electron configuration?

    The arrangement of electrons in the shells and subshells of an atom, like 1s22s22p6 for Helium.

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    What do shells closest to the nucleus fill first?

    Electrons fill shells closest to the nucleus first as these shells have lower energy levels.

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    Core electrons

    Electrons in the filled inner shells closest to the nucleus, not involved in chemical reactions.

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    Valence electrons

    Electrons in the outermost shell of an atom, involved in chemical reactions.

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    Lewis dot structures

    A simple representation showing only the valence electrons of an atom as dots around the element's symbol.

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    What does the group number tell you?

    The group number in the periodic table corresponds to the number of valence electrons for an element.

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    Octet rule

    Atoms tend to gain or lose electrons to achieve a stable configuration with eight valence electrons (a filled s and p subshells).

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    Noble Gas Stability

    Noble gases are extremely stable due to having a full outer shell of electrons, specifically filled p orbitals.

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    Reactivity of Alkali Metals

    Alkali metals are highly reactive because they have only one electron in their outer shell, readily losing it to achieve a stable configuration.

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    Reactivity of Halogens

    Halogens readily gain one electron to complete their outer shell, making them highly reactive.

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    Electronegativity

    The measure of an atom's ability to attract electrons towards itself in a chemical bond.

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    Electronegativity Trends

    Electronegativity increases across a period and decreases down a group in the periodic table.

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    Bond Types and Electronegativity

    Electronegativity difference between atoms determines bond type: non-polar covalent (similar), polar covalent (different), or ionic (large difference).

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    Atomic Number Importance

    The atomic number indicates the number of protons in an atom's nucleus, which determines the element.

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    Valence Electrons Role

    Valence electrons are the outermost electrons, involved in chemical bonding and determining an element's reactivity.

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    Molar Concentration

    The amount of solute dissolved in a liter of solution, expressed in moles per liter (mol/L).

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    What are the 3 main subatomic particles?

    The three main subatomic particles are protons, neutrons, and electrons. Protons reside in the nucleus and carry a positive charge. Neutrons are also in the nucleus and are neutral in charge. Electrons orbit the nucleus and carry a negative charge.

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    What are electron shells and orbitals?

    Electron shells are energy levels surrounding the nucleus. Each shell can hold a specific number of electrons. Within a shell, there are sub-shells called orbitals, which are regions of space where electrons are most likely to be found. The number of orbitals in each shell increases as you move further from the nucleus.

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    What is the Pauli Exclusion Principle?

    Each orbital can hold a maximum of 2 electrons, but these 2 electrons must have opposite spins.

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    What determines an element's reactivity?

    An element's reactivity is determined by the number and arrangement of its electrons, specifically its valence electrons (the electrons in the outermost shell). Elements tend to gain, lose, or share electrons to achieve a stable configuration, often following the octet rule (8 valence electrons).

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    Study Notes

    Fundamentals of Chemistry: Part 1 - Atoms and Elements

    • Learning Goals:
      • Understanding basic atomic structure
      • Understanding electron organization in simple elements
      • Representing electron configuration
      • Relating electron organization to Periodic Table position

    The Human Body - Elemental Composition by Mass

    • Elements: Hydrogen, Carbon, Nitrogen, Oxygen, Fluorine, Sodium, Magnesium, Phosphorus, Sulfur, Chlorine, Potassium, Calcium, Iron, Cobalt, Copper, Zinc, Selenium, Iodine.
    • Percentage by Mass: (Values are approximate; specific percentages vary by individual and context)
      • Hydrogen (10%)
      • Carbon (18%)
      • Nitrogen (3%)
      • Oxygen (65%)
      • Fluorine (<0.01%)
      • Sodium (0.1%)
      • Magnesium (0.05%)
      • Phosphorus (1.2%)
      • Sulfur (0.2%)
      • Chlorine (0.2%)
      • Potassium (0.2%)
      • Calcium (1.5%)
      • Iron (<0.05%)
      • Others (in very small proportions)

    Structure of the Atom

    • Definition: Smallest unit of an element.
    • Structure: Central nucleus surrounded by one or more electrons.
    • Nucleus: Contains protons and neutrons.
    • Electrons: Orbit the nucleus in specific regions (orbitals).
    • Protons: Positively charged particles.
    • Neutrons: Neutral particles.
    • Hydrogen Atom Image: An image of a hydrogen atom with orbiting electrons, produced using a quantum microscope.

    The Atomic Nucleus

    • Composition: Protons and usually neutrons
    • Mass: Protons and neutrons have approximately the same mass (one atomic mass unit).
    • Charge: Proton is positive; neutron is neutral.
    • Force: Held together by the nuclear force

    Components of the Atom

    • Particle: Proton, Neutron, Electron
    • Mass: Proton(1), Neutron(1), Electron (very small: 5.5 x 10-4amu or about 1/1800 of a proton or neutron).
    • Charge: Proton(+1.6 x 10-19 C), neutron(0), Electron(-1.6 x 10-19 C)

    Elements and Isotopes

    • Elements: Atoms with different numbers of protons and thus, electrons.
    • Isotopes: Atoms of the same element with the same number of protons (and thus electrons), but a different number of neutrons.
    • Carbon Isotope Example: Carbon-12, Carbon-13, Carbon-14 are isotopes of carbon with varying numbers of neutrons and have slightly differing percentages for each isotope.

    The Periodic Table

    • Organization: Elements are organized by increasing atomic number.
    • Groups (Columns): Elements in the same group have similar chemical properties.
    • Periods (Rows): Elements in the same period have similar electron configurations.
    • Formulator: Dmitri Mendeleev (1869)

    Elements and Periodic Table

    • Atomic Mass: Sum of protons and neutrons.
    • Atomic Number: Number of protons or electrons in an atom
    • Relationship to Periodic Table: Atomic Number determines where an element is located in the Periodic Table.
    • Atomic Mass is greater than Atomic Number: Atomic mass includes protons and neutrons and the mass of electrons is comparatively negligible.

    Atomic Mass and Molecular Masses

    • Molecules: Composed of atoms;
    • Molecular Mass: Sum of the atomic masses of atoms in the molecule.
    • Carbon Dioxide Example: A CO2 molecule contains one Carbon atom and two Oxygen atoms; it's molecular mass can be calculated through summing the individual atomic masses.

    Molecular Mass, Moles and Avogadro's Number

    • Avogadro's Number: 6.02 x 1023
    • Mole: A unit used to represent a certain number of particles.
    • One Mole: Contains 6.02 x 1023 particles of that substance.
    • NaCl (Table salt) Example: 1 mole of NaCl = 58.44 g (RMM = 58.44)

    Moles and Molarity

    • Moles: A unit of substance amount - no capital letter is used.
    • Molar: A unit of concentration
    • Molarity: Moles per liter (mol/L) or written as (M); capital M is used.

    Electron Configuration: arrangement of electrons in the shell

    • Helium Example: Helium (He), Atomic Number=2, 2 protons, 2 electrons, electron configuration 1s2.
    • Neon Example: Neon (Ne), Atomic Number=10, 10 protons, 10 electrons, electron configuration 1s22s22p6
    • Fluorine Example: Fluorine (F), Atomic Number = 9, 9 protons, 9 electrons, Electron configuration 1s22s22p5.

    Core and Valence Electrons

    • Core Electrons: Filled electron shells that are closest to the nucleus.
    • Valence Electrons: Outermost shell electrons. Participate in chemical reactions.
    • Lewis's Dot Structure: Visual representation of valence electrons.

    Electron Organisation

    • Orbitals: Regions of space surrounding the nucleus where electrons reside. Each orbital can have a maximum of 2 electrons.
    • Shells: Groups of equivalent orbitals are shells. Shells are further organized into subshells. Numbers increase from the nucleus outward.

    Electronegativity and Polarity

    • Electronegativity: Ability of an atom to attract electrons in a chemical bond.
    • Polar Covalent Bond: Unequal sharing of electrons.
    • Non-polar Covalent Bond: Equal or near-equal sharing of electrons.
    • Ionic Bond: Complete transfer of electron(s).

    Pauling Scale electronegativity

    • Period Trend: Electronegativity generally increases across a period in the periodic table.
    • Group Trend: Electronegativity generally decreases down a group in the periodic table.
    • Bigger radius = lower electronegativity: Valence electrons are further away from the nucleus as the atomic radius increases.

    Summary

    • Periodic Table Location: Predicts element properties' and reactivity.
    • Atomic Mass & Molecules: Necessary for calculations.
    • Electron Organization: Determines chemical properties.
    • Electronegativity: Determines type of bonding (polarity).
    • Moles & Avogadro's Number: Essential calculations related to molar masses.

    MCQ Quizzes

    • Topic: Fundamentals of Chemistry, part 1 (Atoms)
    • Purpose: Assist ongoing studies in Biochemistry.
    • Use in Seminars: Used for discussions with further analysis.

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    Description

    This quiz covers the basic atomic structure and electron organization within simple elements. It aims to relate electron configurations to their positions on the Periodic Table. Test your understanding of atomic concepts and the elemental composition of the human body.

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