Fragile Molecules and Molecular Weighing Techniques
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Questions and Answers

What is the problem with EI mass spectrometry for fragile molecules?

  • The energy of the bombarding electron can cause complete fragmentation. (correct)
  • The energy of the bombarding electron is too low.
  • The energy of the bombarding electron is too high.
  • The energy of the bombarding electron does not affect fragile molecules.

What is chemical ionization in mass spectrometry?

  • Forming a charged complex by accelerating a molecular ion.
  • Mixing a gas such as ammonia with the substrate in the spectrometer. (correct)
  • Ionizing an aerosol of the substrate in the presence of sodium ions.
  • Fragmentation of the molecular ion by bombarding electrons.

What is the mass spectrum of heptan-2-one in electrospray mass spectrometry?

  • M - 1
  • M + Na+
  • M + 23 (correct)
  • M + 18

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