Formation of Hydronium Ions and Hydroxyl Ions
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Questions and Answers

What is the Arrhenius theory's definition of an acid?

An acid is a substance that dissociates in aqueous solution to produce $H^+$ ions.

Explain the formation of the hydronium ion from water and a proton.

A proton ($H^+$$) adds to the lone pair of electrons on the oxygen atom of water, forming the hydronium ion $[H_3O^+]$ through a coordinate covalent bond.

According to the Lowry-Bronsted theory, what defines a base?

A base is defined as a proton acceptor.

Describe the role of the lone pairs in the formation of $H_3O^+$.

<p>The lone pairs on the oxygen atom of water are used to coordinate with the $H^+$ ion, facilitating bond formation.</p> Signup and view all the answers

How do hydroxyl ions ($[OH^-]$) form in aqueous solutions?

<p>Hydroxyl ions form when a proton ($H^+$) from water is accepted by ammonia ($NH_3$), which results in the creation of $OH^-$.</p> Signup and view all the answers

What is the significance of the coordinate covalent bond in the formation of the hydronium ion?

<p>The coordinate covalent bond is significant as it represents the sharing of electron pairs between the water's oxygen atom and the proton.</p> Signup and view all the answers

Discuss the dissociation of strong vs. weak acids according to the Arrhenius theory.

<p>Strong acids dissociate almost completely in solution, while weak acids dissociate only partially.</p> Signup and view all the answers

What molecules are involved in the formation of hydroxyl ions from ammonia?

<p>The formation of hydroxyl ions involves ammonia ($NH_3$) and water ($H_2O$).</p> Signup and view all the answers

What is the charge on the nitrogen atom in the ammonia molecule, and why is it significant?

<p>The nitrogen atom in ammonia carries a slight negative charge, which enables it to attract protons.</p> Signup and view all the answers

Explain the charge separation in water and its influence on acid-base reactions.

<p>Water exhibits a charge separation where the hydrogen atom is slightly positive and the oxygen slightly negative, influencing its ability to form hydronium and hydroxyl ions.</p> Signup and view all the answers

Study Notes

Formation of Hydronium Ions ([H3O]+[H_3O]^+[H3​O]+)

  • Arrhenius Theory: Defines acids as substances that produce H+H^+H+ ions in water. Strong acids dissociate completely, while weak acids dissociate only partially.
  • Lowry-Bronsted Theory: Acids donate protons, and bases accept protons. For example, HCl⟶H++Cl−HCl \longrightarrow H^+ + Cl^-HCl⟶H++Cl− signifies that HClHClHCl donates a proton, acting as an acid. NH3+H+⟶NH4+NH_3 + H^+ \longrightarrow NH_4^+NH3​+H+⟶NH4+​ shows NH3NH_3NH3​ accepting a proton, acting as a base.
  • Water Molecule: Water has a polar covalent structure with a slight charge separation—hydrogen atoms are slightly positive, and the oxygen atom is slightly negative. Oxygen has two lone pairs of electrons available.
  • Formation of H3O+H_3O^+H3​O+ Ions: A proton (H+H^+H+) from the acid bonds to the lone pair on the oxygen in water, forming the hydronium ion (H3O+H_3O^+H3​O+) through a coordinate covalent bond.

Formation of Hydroxyl Ions ([OH−][OH^-][OH−])

  • Formation from Alkalis: Alkalis, such as ammonia (NH3NH_3NH3​), form hydroxyl ions when dissolved in water.
  • Reaction with Water: The reaction between ammonia and water results in the formation of NH4+NH_4^+NH4+​ and OH−OH^-OH−. Ammonia accepts a proton from water, leading to the production of hydroxyl ions.
  • Ammonia Molecule: The nitrogen atom in ammonia, having a slight negative charge, donates a lone pair to bond with the proton from water. This interaction creates a coordinate covalent bond between nitrogen and the added hydrogen, resulting in NH4+NH_4^+NH4+​ and OH−OH^-OH− ions.

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Description

Explore the concepts behind the formation of hydronium and hydroxyl ions. This quiz covers Arrhenius and Lowry-Bronsted theories, along with examples of acid-base reactions. Test your understanding of how acids and bases interact in aqueous solutions.

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