Food Additives and Redox Reactions
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Questions and Answers

Chelating agents can form stable complexes with metal ions.

True (A)

Prooxidants only promote the formation of lipid hydroperoxides.

False (B)

The presence of chelating agents in food can lead to precipitation and discoloration.

False (B)

Ionizing radiation is considered a prooxidant in food systems.

<p>True (A)</p> Signup and view all the answers

Chelating agents contribute negatively to the stability of food color, aroma, and texture.

<p>False (B)</p> Signup and view all the answers

Singlet oxygen is a type of prooxidant that enhances food preservation.

<p>False (B)</p> Signup and view all the answers

Lipid hydroperoxides are formed exclusively by prooxidants.

<p>False (B)</p> Signup and view all the answers

The action of polyphenol oxidase in foods can lead to undesirable oxidation reactions.

<p>True (A)</p> Signup and view all the answers

Phytoalexins are primarily effective against bacteria rather than fungi.

<p>False (B)</p> Signup and view all the answers

Isoflavonoids have a C6-C3-C6 basic skeleton structure.

<p>True (A)</p> Signup and view all the answers

Gram-negative bacteria are more sensitive to essential oils than Gram-positive bacteria.

<p>False (B)</p> Signup and view all the answers

Capsidiol is an antimicrobial compound found in pepper.

<p>True (A)</p> Signup and view all the answers

Terpenes/terpenoids in essential oils can disrupt the bacterial cell membrane.

<p>True (A)</p> Signup and view all the answers

Ascorbic acid can reduce reactive oxygen species such as hydrogen peroxide.

<p>True (A)</p> Signup and view all the answers

SO2 is less effective against Gram-negative bacteria than Gram-positive bacteria.

<p>False (B)</p> Signup and view all the answers

Sulfites are primarily used for inhibiting enzymatic browning in fruits and vegetables.

<p>True (A)</p> Signup and view all the answers

Sulfurous acid is the least effective form of sulfites in food preservation.

<p>False (B)</p> Signup and view all the answers

SO2 acts as an antioxidant by directly eliminating oxygen from foods.

<p>False (B)</p> Signup and view all the answers

Sulfite filters are commonly used in the winemaking process.

<p>True (A)</p> Signup and view all the answers

The main goal of using SO2 during the prefermentation process is to promote oxidation.

<p>False (B)</p> Signup and view all the answers

High pH levels enhance the effectiveness of sulfites against yeast.

<p>False (B)</p> Signup and view all the answers

Excessive usage of EDTA in foods could lead to depletion of calcium and other cationic minerals in the body.

<p>True (A)</p> Signup and view all the answers

Pink discoloration in canned pears is caused by a purple-pink insoluble tin-anthocyanin complex.

<p>True (A)</p> Signup and view all the answers

Blue discoloration in crab meat does not involve the presence of biuret.

<p>False (B)</p> Signup and view all the answers

Chill Haze in beer occurs when the beer is chilled below approximately 1.6°C.

<p>True (A)</p> Signup and view all the answers

Polyphosphates and EDTA are utilized in canned seafood to enhance the formation of glassy crystals.

<p>False (B)</p> Signup and view all the answers

Chelating agents can stabilize fermented malt beverages by complexing copper.

<p>True (A)</p> Signup and view all the answers

Tartaric acid and its salts are added to cheese to enhance color and increase rancidity.

<p>False (B)</p> Signup and view all the answers

Seafood contains substantial amounts of magnesium that can react with ammonium phosphate to produce crystals.

<p>True (A)</p> Signup and view all the answers

Chelating agents are effective antioxidants.

<p>False (B)</p> Signup and view all the answers

Raising the pH enhances the efficiency of chelating agents.

<p>True (A)</p> Signup and view all the answers

Citric acid can solubilize fats and oils.

<p>True (A)</p> Signup and view all the answers

EDTA salts are ineffective in emulsion systems.

<p>False (B)</p> Signup and view all the answers

Trace elements can catalyze oxidation in fats and oils.

<p>True (A)</p> Signup and view all the answers

Ascorbic acid is unaffected by copper and iron.

<p>False (B)</p> Signup and view all the answers

The term 'chelate' comes from the Latin word for crab claw.

<p>False (B)</p> Signup and view all the answers

Pink discoloration in canned pears is caused by trace minerals.

<p>True (A)</p> Signup and view all the answers

High doses of SO2 can cause organoleptic changes of the final product and some allergies.

<p>True (A)</p> Signup and view all the answers

Propyl gallate (PG) is a natural antioxidant derived from gallate acid.

<p>False (B)</p> Signup and view all the answers

Gallates exhibit higher antioxidant activity in fats with maximum moisture.

<p>False (B)</p> Signup and view all the answers

Propyl gallate is considered unstable and not suitable for frying fats.

<p>True (A)</p> Signup and view all the answers

BHA is effective in protecting lipids containing fatty acids with shorter chains, such as in coconut oil.

<p>True (A)</p> Signup and view all the answers

Butylated hydroxyanisole (BHA) is less effective than propyl gallate in stabilizing free radicals.

<p>False (B)</p> Signup and view all the answers

BHT can stop autooxidation by converting hydroperoxides into stable radicals.

<p>False (B)</p> Signup and view all the answers

BHA and BHT are often blended with other synthetic antioxidants to improve their antioxidative properties.

<p>True (A)</p> Signup and view all the answers

Flashcards

Chelating Agents (Sequestrants)

Substances that bind free metal ions in food systems, forming non-ionized, non-toxic complexes. These complexes prevent reactions that lead to food degradation, such as discoloration, rancidity, and loss of nutritional quality.

Free Metal Ions in Food Systems

Metal ions in food systems can cause various problems like discoloration, rancidity, and loss of nutritional quality.

Chelation

The formation of a stable compound between a metal ion and a chelating agent, resulting in a complex that is non-ionized and non-toxic.

Benefits of Chelating Agents

Chelating agents remove free metal ions from food, preventing them from catalyzing unwanted reactions. This helps to preserve food quality, color, and texture.

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Reaction that Forms a Chelating Complex

The reaction between a metal ion and a chelating agent that forms a stable, non-ionized, non-toxic complex.

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Elimination of Chelating Complexes

Chelating complexes are easily eliminated from the body, making them safe for use in food.

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Role of Chelating Agents in Food Preservation

Chelating agents play a crucial role in food preservation by controlling metal ions that can damage food quality.

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Metal Ion Binding Ability

The ability of a chelating agent to bind to a single metal ion.

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What are chelating agents?

Chelating agents are molecules that bind to metal ions, forming a stable complex. They are not antioxidants, but they can act as antioxidants by removing metal ions that catalyze oxidative reactions.

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How do chelating agents improve food stability?

Chelating agents can help stabilize food products by preventing oxidative reactions that can lead to spoilage. They can also prevent discoloration by removing trace metals that contribute to color changes.

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What are some popular chelating agents used in food?

Citric acid and its derivatives, phosphates, and EDTA are commonly used in food applications to bind to metal ions.

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Why is the solubility of chelating agents important?

The solubility of chelating agents is crucial for their effectiveness. For example, citric acid and its esters are soluble in fats and oils, while EDTA salts are effective in emulsions like mayonnaise and salad dressings.

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How does pH influence the effectiveness of chelating agents?

The pH of the environment affects the efficiency of chelating agents. A higher pH generally enhances chelating efficiency because the carboxylate ion, which is formed at higher pH, is a more efficient donor group.

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How do trace elements impact food quality?

Trace elements like iron, copper, and cobalt can act as catalysts for oxidation, leading to deterioration of food products. For example, copper and iron can destroy vitamins A, E, and thiamine.

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How do chelating agents help prevent discoloration in food?

Chelating agents are helpful in preventing discoloration in food products. For example, they can prevent pink discoloration in canned pears, blue-green discoloration in shellfish, and clouding in soft drinks.

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Do chelating agents act as antioxidants?

Chelating agents do not directly scavenge free radicals or delay oxidation. They prevent oxidative reactions by removing metal ions that act as catalysts for oxidation.

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Chelating Agents

Chemicals that bind to metal ions, preventing them from reacting and causing unwanted changes in food.

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Chill Haze

A condition in beer where particles form and cause cloudiness when chilled.

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Pink Discoloration in Canned Pears

A reddish pigment that forms in some canned fruits during processing, caused by the breakdown of tannins.

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Blue Discoloration in Crab Meat

A blue discoloration in crab meat caused by a reaction between copper and a substance called biuret.

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EDTA and Mineral Depletion

The use of EDTA to prevent the depletion of calcium and other essential minerals in the body.

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Glassy Crystals in Canned Seafood

Polyphosphates and EDTA can be used to prevent the formation of glassy crystals in canned seafood by reacting with magnesium in the seafood.

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Chelating Agents in Cheese

Chelating agents like tartaric acid and its salts can be added to cheese to prevent color loss and rancidity.

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Copper and Haze Formation in Beer

Free copper can cause the formation of haze in beer by promoting the oxidation of polyphenolic compounds.

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What are Phytoalexins?

Phytoalexins are antimicrobial compounds produced by plants in response to pathogen attacks. They help defend against fungi and bacteria.

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Are all phytoalexins the same?

Phytoalexins are often specific to plant families. For instance, legumes primarily produce isoflavonoids as phytoalexins, while Solanaceae plants produce terpenoids.

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What are essential oils?

Essential oils are a type of natural antimicrobial extracted from plants. They're often considered safe for use.

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How do essential oils work?

Essential oils work by interfering with the cell membrane of bacteria and fungi. Their lipophilic nature helps them penetrate cell walls.

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Why are Gram-negative bacteria more resistant?

Essential oils are more effective against Gram-positive bacteria than Gram-negative bacteria. This is because Gram-negative bacteria have an outer membrane that makes them more resistant.

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Gallates

Synthetic antioxidants used to prevent oxidation in food, especially fats. They are more polar than other antioxidants like BHA and BHT.

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Propyl Gallate (PG)

A specific type of gallate, it is a synthetic antioxidant that is derived from gallic acid. It effectively protects against oxidation in animal fats like lard and tallow.

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Butylated Hydroxyanisole (BHA) and Butylated Hydroxytoluene (BHT)

Two powerful synthetic antioxidants similar in structure and activity. They contain di-tert-butyl groups, making them effective at neutralizing free radicals and slowing down oxidation.

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Butylated Hydroxyanisole (BHA)

A specific antioxidant used in food to prevent spoilage by delaying oxidation. More effective in short-chain fatty acids like those found in coconut or palm kernel oils.

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Butylated Hydroxytoluene (BHT)

A common antioxidant often found in food packaging materials and used in conjunction with other antioxidants. BHT is especially good with BHA for a better antioxidative effect.

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Carry-Through Property

The ability of an antioxidant to effectively stop oxidation even after the food product has been cooked or heated. This is a desirable trait for synthetic antioxidants.

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Oxidation

A type of chemical reaction that involves the loss of electrons. In the context of food, oxidation is the process that causes food spoilage, like rancidity in fats and oils.

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Antioxidants

These are molecules that can react with free radicals, preventing them from causing damage to the food. Antioxidants donate a hydrogen atom to stabilize free radicals, effectively ending their damaging chain reaction.

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What is a reducing agent?

A chemical compound that can donate electrons to protect other molecules from damage caused by free radicals. It can also reduce the concentration of reactive oxygen species (ROS) like hydrogen peroxide.

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What are sulfites and their role in food preservation?

Sulfur dioxide (SO2) and its related compounds, such as sulfites (Na2SO3, NaHSO3, KHSO3), are widely used in food preservation, particularly for fruits and vegetables. They effectively inhibit microbial growth, prevent discoloration caused by enzymatic and non-enzymatic browning, and act as antioxidants.

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How does SO2 act as an antioxidant?

Sulfur dioxide (SO2) can react with hydrogen peroxide, a reactive oxygen species (ROS), effectively neutralizing it and acting as an antioxidant. It can also reduce quinones (compounds involved in browning reactions) to their phenol form, which are less reactive, and prevent the formation of these quinones by inhibiting polyphenol oxidase enzymes, further protecting from browning.

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What are the antimicrobial properties of sulfites?

Sulfite forms, such as bisulfite, exhibit antimicrobial properties. Their effectiveness is influenced by pH conditions, with higher pH favoring activity against bacteria but not yeast. Gram-negative bacteria are more susceptible to sulfite action compared to Gram-positive, making these compounds valuable in food preservation.

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What is the role of SO2 in winemaking?

Sulfur dioxide (SO2) is a key component in winemaking, acting as a solvent to extract flavors and compounds from grape solids like stems, seeds, and skins. It is also used throughout the winemaking process.

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Why are sulfite filters used in winemaking?

Sulfite filters are commonly used in winemaking to remove excess sulfites. This is done to prevent unwanted sulfite levels in the final product, which can cause adverse reactions in some individuals.

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How is SO2 used throughout winemaking?

Sulfur dioxide (SO2) is utilized at three stages of winemaking. First, it prevents oxidation during the prefermentation process, ensuring the must (grape juice) remains fresh. Second, it controls microbial growth after fermentation, preventing spoilage. Third, it stabilizes the wine before bottling, preventing any changes or accidents in the bottle.

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Are there any limitations to using SO2 in food?

While its use in food preservation is widespread, SO2 is not advised for foods containing thiamine (Vitamin B1) as it can degrade this essential nutrient.

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Study Notes

Additives

  • Acids
  • Bases
  • Buffer systems and salts
  • Chelating agents
  • Antioxidants
  • Emulsifiers
  • Gums
  • Flavor Substances
  • Flavor enhancers
  • Stabilizers & Thickeners
  • Anticaking agents
  • Gases
  • Firming Texturizers
  • Clarifying Agents
  • Flour Bleaching Agents
  • Colorants
  • Fat replacers
  • Antimicrobial agents
  • Sweeteners

Redox Reactions in Food

  • Redox Reactions involve the gain or loss of electrons.
  • Oxidation is the loss of electrons, increasing the oxidation number.
  • Reduction is the gain of electrons, decreasing the oxidation number.
  • Redox reactions are important in food because they can lead to undesirable changes like enzymatic browning.

Enzymatic Browning

  • Hydroxylation and oxidation reactions catalysed by polyphenol oxidase.
  • Reactions lead to a change in color.
  • Oxidation reactions are caused by polyphenol oxidase.

Prooxidants

  • Promote the formation of lipid hydroperoxides.
  • Promote the formation of free radicals (singlet oxygen, ionizing radiation, lipoxygenase).
  • Promote decomposition of hydroperoxides (transition metals, light, elevated temperatures).

Lipid Oxidation

  • Initiation, propagation, and termination are the three stages.
  • Primary oxidation products are lipid hydroperoxides.
  • Secondary oxidation products include volatile aldehydes, ketones, alcohols, acids, hydrocarbons, and non-volatile aldehydes.

Chelating Agents (Sequestrants)

  • Prevent the formation of colored or insoluble compounds of free metal ions.
  • Prevent the degradation of food components.
  • Improve the stabilization of food color, aroma, and texture.
  • Useful for stabilizing food colors, aromas and textures.

Phytic Acid

  • Known as inositol hexakisphosphate (IP6).
  • Principal storage form of phosphorus in many plant tissues.
  • Found in cereals, grains, bran, and seeds
  • Can bind to important minerals (calcium, iron, and zinc).
  • Can inhibit metal-induced discolorations, and remove calcium from pectic substances in cell walls.

Antioxidants

  • Prevent or delay oxidative deterioration in foods.
  • Prevent undesirable changes (bad odor, loss of taste, rancidity).
  • ROS (reactive oxygen species) are stabilized or removed

Action Mechanisms of Antioxidants

  • Quenching: Scavenge singlet oxygen (O2)
  • Charge transfer: Donate electrons to reactive species
  • Bond breaking: React with lipid radicals to terminate oxidation chain reactions.

Natural Antioxidants: Tocopherol (Vitamin E)

  • Collective name for eight related tocopherols and tocotrienols
  • Fat-soluble vitamins with antioxidant properties.
  • Primarily a-tocopherol.
  • Found in vegetable oils.
  • Effective as a membrane protector against oxidation caused by lipid radicals.

Natural Antioxidants: Ascorbic Acid (Vitamin C)

  • A monosaccharide.
  • Antioxidant found in animal and plant tissues.
  • Necessary for humans as it cannot be synthesized.
  • Acts as a reducing agent (scavenging oxygen) in foods.

Natural Antioxidants: Sulfites and Sulfur Dioxide

  • Used as microbial growth and enzymatic/non-enzymatic browning inhibitors, as well as antioxidants and reducing agents in food preservation.
  • High effectiveness and efficiency in acid medium
  • More effective against Gram-negative bacteria

Synthetic Antioxidants

  • BHA (Butylated Hydroxyanisole):

  • Contains di-tert-butyl groups, effective as primary antioxidants.

  • Effective in fats, oils, and oil-in-water emulsions.

  • Synergistic when combined with other antioxidants.

  • BHT (Butylated Hydroxytoluene):

  • Effective against lipid radicals.

  • White crystalline solid.

Synthetic Antioxidants: Sodium Erythorbate

  • Sodium salt of erythorbic acid.
  • Primarily used in meats, poultry, and soft drinks.
  • Structurally related to vitamin C, improves flavor stability.

Antimicrobial Agents

  • Substances which control microbial growth.

Antimicrobials: Mechanism of Action

  • Affect genetic systems (replication and transcription, DNA/RNA, protein synthesis inhibition).
  • Impact on the cell wall/membrane (affecting cell wall synthesis, permeability).
  • Inhibit enzymes.
  • Bind to essential nutrients.

Antimicrobials: Epoxides

  • Useful for sterilizing low-moisture foods and packaging materials.
  • Include ethylene oxides and propylene oxides.

Antimicrobials: Nitrate and Nitrites

  • Used in curing meats for color development and inhibition of Clostridium botulinum.
  • Form nitric oxide that react to myoglobin, which forms pigments.

Antimicrobials: Bacteriocins

  • Produced by certain lactic acid bacteria.
  • Effective against Gram-positive bacteria.
  • Used in foods.

Antimicrobials: Phytoalexins

  • Produced by healthy plant cells in response to infection.
  • Antimicrobial activity primarily against fungi.

Antimicrobials: Essential Oils

  • Have antimicrobial activity, often disrupting cells, leading to their death.
  • Used to preserve a variety of food products.

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Description

This quiz explores key concepts related to food additives, redox reactions, and enzymatic browning. Understand the role of different agents and the chemical processes that affect food quality. Test your knowledge on how these concepts influence food preservation and flavor enhancement.

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