Fatty Acid Nomenclature

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What is the most abundant lipid in nature?

Neutral fats and oils (Triglycerides)

Which type of triglyceride has three fatty acids connected to glycerol of the same type?

Simple triglycerides

Which process results in the production of monoglyceride?

Esterification of glycerol with one molecule of fatty acid

What is the main difference between fats and oils?

State at room temperature

What chemical property allows fats to float on water?

Specific gravity less than 1

What is the systematic name for a C18 fatty acid with no double bonds?

Octadecanoic acid

What does the notation 18:2 signify for a fatty acid?

C18 fatty acid with two double bonds

How is the position of a double bond represented by counting from the distal end, with the ω-carbon as number 1?

ω9

How is the position of a double bond represented by the symbol ∆ followed by a superscript number?

Δ9

Which carbon atoms are also known as the α, β, and carbons in a fatty acid?

2, 3, 4

How is the position of a double bond represented when counting from the distal end, with the ω-carbon as number 1?

ω3

What is the systematic name for a C18 fatty acid with two double bonds?

Octadecadienoic acid

What does the notation 18:0 signify for a fatty acid?

C18 fatty acid with no double bonds

Which carbon atoms are known as the α, β, and ω-carbons in a fatty acid?

Carbon Nos. 2, 3, and 4

What is the main difference between fats and waxes?

Chain length of fatty acids

What is the systematic name for a C16 fatty acid with no double bonds?

Stearic acid

Which type of triglyceride has three fatty acids connected to glycerol of different types?

Mixed triglyceride

What chemical property allows fats to be insoluble in water but soluble in organic solvents like ether and benzene?

Esterification

What is the main difference between fats and oils?

Fats are liquid at room temperature

Which process results in the production of diglyceride?

Esterification

Study Notes

Lipids

  • The most abundant lipid in nature is triglycerides.
  • A simple triglyceride is a type of triglyceride that has three fatty acids connected to glycerol of the same type.
  • Hydrolysis is the process that results in the production of monoglyceride.
  • The main difference between fats and oils is that fats are solid at room temperature, while oils are liquid.
  • The chemical property that allows fats to float on water is their non-polar and hydrophobic nature.

Fatty Acids

  • The systematic name for a C18 fatty acid with no double bonds is stearic acid.
  • The notation 18:2 signifies that a fatty acid has 18 carbon atoms and 2 double bonds.
  • When counting from the distal end, with the ω-carbon as number 1, the position of a double bond is represented by the symbol ω (omega) followed by a number.
  • The position of a double bond can also be represented by the symbol ∆ (delta) followed by a superscript number.
  • The α, β, and ω-carbons in a fatty acid are the carbon atoms that are closest to the carboxyl group, next to the α-carbon, and at the end of the fatty acid chain, respectively.

Fatty Acid Structure

  • The systematic name for a C18 fatty acid with two double bonds is linoleic acid.
  • The notation 18:0 signifies that a fatty acid has 18 carbon atoms and no double bonds.
  • The systematic name for a C16 fatty acid with no double bonds is palmitic acid.

Fats and Waxes

  • The main difference between fats and waxes is that fats are esters of glycerol, while waxes are esters of long-chain fatty acids and long-chain alcohols.
  • A mixed triglyceride is a type of triglyceride that has three fatty acids connected to glycerol of different types.
  • The chemical property that allows fats to be insoluble in water but soluble in organic solvents like ether and benzene is their non-polar and hydrophobic nature.
  • Lipolysis is the process that results in the production of diglyceride.

Test your knowledge on the systematic nomenclature of fatty acids, which involves deriving the name from the parent hydrocarbon by substitution. Learn about naming conventions for saturated and unsaturated fatty acids.

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