Esterification and Soap Chemistry Quiz

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Questions and Answers

What is produced when ethanol reacts with ethanoic acid in the presence of an acid catalyst?

  • Ester and sodium hydroxide
  • Water and carbon dioxide
  • Vinegar and alcohol
  • Ester and water (correct)

What is the melting point of glacial acetic acid?

  • 300 K
  • 285 K
  • 290 K (correct)
  • 273 K

What role does concentrated sulfuric acid play in the esterification process?

  • It acts as a reactant
  • It neutralizes the acids
  • It serves as a catalyst (correct)
  • It dilutes the solution

Which of the following is a common use for a 5-8% solution of acetic acid?

<p>Preservative in pickles (B)</p> Signup and view all the answers

What happens when an ester is treated with sodium hydroxide?

<p>It forms alcohol and sodium salt (A)</p> Signup and view all the answers

What is the product formed when ethanoic acid reacts with sodium hydroxide?

<p>Sodium ethanoate and water (D)</p> Signup and view all the answers

What gas is produced when ethanoic acid reacts with carbonates?

<p>Carbon dioxide (C)</p> Signup and view all the answers

In the soap and water experiment, which test tube is expected to show oil and water separation first when soap is added?

<p>Test tube B (B)</p> Signup and view all the answers

What is the main function of the hydrophilic heads in a micelle?

<p>To attract water and stabilize the micelle (D)</p> Signup and view all the answers

Which of the following represents the correct reaction for ethanoic acid with sodium bicarbonate?

<p>CH_3COOH + NaHCO_3 ightarrow CH_3COONa + H_2O + CO_2 (A)</p> Signup and view all the answers

What is the role of the hydrophilic end of a soap molecule?

<p>It interacts with water (D)</p> Signup and view all the answers

What structure do soap molecules form when they clean oily dirt?

<p>Micelles (C)</p> Signup and view all the answers

Why do soap molecules remain in solution as colloids?

<p>They are prevented from precipitating due to ion-ion repulsion (D)</p> Signup and view all the answers

In a micelle, where do the hydrophobic tails of soap molecules reside?

<p>In the center of the micelle (C)</p> Signup and view all the answers

What happens to the appearance of a soap solution when micelles form?

<p>It appears cloudy (A)</p> Signup and view all the answers

What is one of the primary uses of ethanol in medicine?

<p>As a solvent (C)</p> Signup and view all the answers

What gas is produced when ethanol reacts with sodium?

<p>Hydrogen (B)</p> Signup and view all the answers

What is formed when ethanol is dehydrated using concentrated sulfuric acid?

<p>Ethene (B)</p> Signup and view all the answers

Which of the following is true about methanol compared to ethanol?

<p>Methanol can be fatal even in small amounts. (B)</p> Signup and view all the answers

What effect does large consumption of ethanol have on the central nervous system?

<p>Depresses the central nervous system (C)</p> Signup and view all the answers

What mixture is denatured alcohol made from?

<p>Ethanol and methanol (C)</p> Signup and view all the answers

At what temperature is ethanol dehydrated with concentrated sulfuric acid?

<p>443 K (B)</p> Signup and view all the answers

What is the primary product when sodium reacts with ethanol?

<p>Sodium ethoxide (A)</p> Signup and view all the answers

Which solution is likely to form more foam when soap is added?

<p>Distilled water (D)</p> Signup and view all the answers

What type of compound is primarily used to overcome the issues caused by hard water in washing?

<p>Detergent (C)</p> Signup and view all the answers

What is formed in hard water when soap is used?

<p>A white curdy precipitate (D)</p> Signup and view all the answers

Which of the following is NOT a component of detergents mentioned?

<p>Potassium salts (C)</p> Signup and view all the answers

What is necessary to achieve maximum cleaning efficiency with soap?

<p>Agitation (D)</p> Signup and view all the answers

What effect do calcium and magnesium salts have on soap during washing?

<p>Prevent foaming (D)</p> Signup and view all the answers

Which test tube would likely produce a curdy solid when soap is added?

<p>One with hard water and soap (D)</p> Signup and view all the answers

What is a major difference between soap and detergents regarding cleaning in hard water?

<p>Detergents form no precipitate with hard water ions (B)</p> Signup and view all the answers

Flashcards

Ethanol's Reaction with Sodium

Ethanol reacts with sodium metal to produce hydrogen gas and sodium ethoxide.

Ethanol Dehydration

Heating ethanol with concentrated sulfuric acid converts it to ethene (an unsaturated hydrocarbon) by removing water.

Ethanol Toxicity

Large amounts of ethanol can slow down bodily functions, impair coordination, and judgment.

Methanol Toxicity

Methanol, even in small amounts, is extremely dangerous and can be fatal.

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Denatured Alcohol

Alcohol made unfit for drinking by adding harmful substances like methanol and dyes.

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Ethanol as a Solvent

Ethanol is a good solvent, dissolving various substances like medications and tinctures.

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Solubility of Ethanol in Water

Ethanol is completely soluble in water in any proportion.

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Ethanol Health Effects

Long-term use of ethanol can lead to long-term health problems.

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Esterification

A reaction between an acid and an alcohol to form an ester and water, catalyzed by an acid.

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Ester

A sweet-smelling substance produced from an acid and an alcohol.

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Saponification

The process by which esters are broken down into alcohol and sodium salt of carboxylic acid using sodium hydroxide.

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Ethanoic acid

A carboxylic acid, also known as acetic acid, found in vinegar.

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Alcohol as fuel additive

Alcohol fuels can produce only carbon dioxide and water when burnt with sufficient air.

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What makes soap effective?

Soap molecules have a hydrophilic (water-loving) end and a hydrophobic (oil-loving) end. This allows them to interact with both water and oil, effectively cleaning away oily dirt.

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Micelle Structure

Micelles are spherical structures formed by soap molecules in water. The hydrophobic tails of the soap molecules cluster together in the center of the micelle, while the hydrophilic heads face outward, interacting with water.

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How does a micelle clean?

The hydrophobic tails of soap molecules trap oily dirt within the micelle's core, separating it from the water. The micelle, now carrying the dirt, can be rinsed away.

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Ethanoic Acid Reaction with Base

Ethanoic acid reacts with sodium hydroxide (NaOH) to form sodium ethanoate (CH3COONa) and water (H2O).

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Ethanoic Acid Reaction with Carbonates

Ethanoic acid reacts with carbonates (like Na2CO3) or hydrogencarbonates (like NaHCO3) to produce a salt (CH3COONa), carbon dioxide (CO2), and water (H2O).

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Why does soap solution appear cloudy?

Soap molecules remain in solution as colloids. They don't precipitate because of ion-ion repulsion and the large size of the micelles, resulting in a cloudy appearance.

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Hydrophobic vs. Hydrophilic

Hydrophobic means 'water-fearing' and refers to substances that don't mix with water. Hydrophilic means 'water-loving' and refers to substances that readily mix with water.

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What is a micelle?

A micelle is a spherical cluster of surfactant molecules in a solvent like water. The hydrophobic tails face inwards, while the hydrophilic heads point outwards towards the water environment.

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How do micelles clean?

Micelles trap dirt and grease in their hydrophobic core and then disperse them in water, allowing them to be washed away.

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How to Distinguish Alcohol from Carboxylic Acid

You can distinguish between an alcohol and a carboxylic acid using a litmus paper test. Carboxylic acids turn blue litmus paper red, while alcohols do not affect the litmus paper.

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Hard Water Test

A simple test using soap solution to determine if water is hard. Hard water produces less foam and a white curdy precipitate forms.

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Soap vs. Detergent

Detergents are effective cleansing agents in hard water, unlike soap, because they don't form insoluble precipitates with calcium and magnesium ions.

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What makes water hard?

Water containing dissolved calcium and magnesium salts is considered hard water.

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Why is agitation needed?

Agitation in washing clothes helps remove dirt by increasing the contact of soap/detergent with the fabric and by creating friction.

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Soap's reaction with hard water

Soap reacts with calcium and magnesium ions in hard water, forming an insoluble precipitate called scum, which is difficult to remove.

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Detergent's advantage in hard water

Detergents are designed to overcome the limitations of soap in hard water by staying effective even in the presence of calcium and magnesium ions.

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What's the curdy white precipitate?

The white curdy precipitate formed in hard water tests is a result of soap reacting with calcium and magnesium ions to form insoluble compounds.

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Why are shampoos often detergents?

Shampoos, being designed for hair washing, often use detergents because they work effectively even in hard water.

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