Equilibrium Constant and Reaction Quotient
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Questions and Answers

What is the expression for the rate of the forward reaction in a reversible reaction?

  • r1 = k1 [C]c [D]d
  • r1 = k1 [A]a [B]b (correct)
  • r1 = k2 [A]a [B]b
  • r1 = k2 [C]c [D]d
  • What is the condition for a system to be in equilibrium?

  • The concentrations of the reactants are equal to the concentrations of the products
  • The rate of the forward reaction is less than the rate of the reverse reaction
  • The rate of the forward reaction is equal to the rate of the reverse reaction (correct)
  • The rate of the forward reaction is greater than the rate of the reverse reaction
  • What is the equilibrium constant expression for a reaction?

  • 𝐊𝐜 = [𝐂]𝐜 [𝐃]𝐝/[𝐀]𝐚 [𝐁]𝐛 (correct)
  • 𝐊𝐜 = [𝐂]𝐜 [𝐃]𝐝-[𝐀]𝐚 [𝐁]𝐛
  • 𝐊𝐜 = [𝐂]𝐜 [𝐃]𝐝+[𝐀]𝐚 [𝐁]𝐛
  • 𝐊𝐜 = [𝐀]𝐚 [𝐁]𝐛/[𝐂]𝐜 [𝐃]𝐝
  • What do the exponents a, b, c, and d represent in the equilibrium constant expression?

    <p>The coefficients of the balanced equation</p> Signup and view all the answers

    What is the significance of a larger K value in a reaction?

    <p>The concentrations of the products of the forward reaction are greater than those of the reactants.</p> Signup and view all the answers

    What is the equilibrium constant expression for the reaction N2 (g) + 3 H2 (g) 2 NH3 (g)?

    <p>Kp = (pNH3)^2/(pN2)(pH2)^3</p> Signup and view all the answers

    What is the unit of the equilibrium constant Kc?

    <p>Unitless</p> Signup and view all the answers

    In a heterogeneous equilibrium, what happens to the concentration of a pure solid or liquid?

    <p>It is constant under constant conditions.</p> Signup and view all the answers

    What is the significance of a smaller K value in a reaction?

    <p>The concentrations of the products of the forward reaction are less than those of the reactants.</p> Signup and view all the answers

    What is the physical interpretation of the equilibrium constant Kc?

    <p>It is the ratio of the concentrations of products to reactants</p> Signup and view all the answers

    What is the relationship between the rates of forward and reverse reactions at equilibrium?

    <p>The rate of the forward reaction is equal to the rate of the reverse reaction</p> Signup and view all the answers

    What is the mathematical expression for the rate of the reverse reaction?

    <p>r2 = k2 [C]c [D]d</p> Signup and view all the answers

    What is the condition for which the equilibrium constant Kc is a constant?

    <p>k1 and k2 are both constants</p> Signup and view all the answers

    What is the significance of the equilibrium constant expression?

    <p>It describes the ratio of the concentrations of products to reactants</p> Signup and view all the answers

    A reaction has an equilibrium constant expression of Kc = [HI]2/[H2][I2]. Which of the following statements is true?

    <p>The reaction involves only gases</p> Signup and view all the answers

    For the reaction CaCO3 (s) → CaO (s) + CO2 (g), what is the reason why the concentrations of solid CaCO3 and CaO do not appear in the equilibrium constant expression?

    <p>Because their concentrations are constant under constant conditions</p> Signup and view all the answers

    For a reaction with an equilibrium constant Kp, which of the following statements is true?

    <p>Kp is equivalent to Kc for reactions involving only gases</p> Signup and view all the answers

    In the reaction 2 SO2 + O2 → 2 SO3, if Kc is greater than 1, what can be inferred about the reaction?

    <p>The equilibrium position lies more to the right</p> Signup and view all the answers

    For the reaction H2 (g) + CO2 (g) → H2O (g) + CO (g), if Kc is 0.771 at 750°C, what can be inferred about the reaction?

    <p>The reaction favors the reactants</p> Signup and view all the answers

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