Environmental Chemistry Chapter 14: The Atmosphere
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Environmental Chemistry Chapter 14: The Atmosphere

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Questions and Answers

What do you mean by atmosphere?

The atmosphere is the envelope of gases that surrounds the Earth.

What is the difference between atmosphere and environment?

The atmosphere specifically refers to the layer of gases surrounding the Earth, while the environment encompasses all living and non-living things in a given area including air, water, and land.

Name the major constituents of the troposphere.

Nitrogen and oxygen constitute about 99% by volume of the Earth's atmosphere.

How is the temperature of the atmosphere maintained?

<p>The temperature is maintained through the absorption of infrared radiation by various gases, including carbon dioxide and water vapor.</p> Signup and view all the answers

Where does the ozone layer exist?

<p>The ozone layer exists in the stratosphere, approximately 25 to 30 km above the Earth's surface.</p> Signup and view all the answers

Why is the temperature of the upper stratosphere higher?

<p>The temperature in the upper stratosphere is higher due to the presence of ozone, which absorbs ultraviolet radiation from the Sun.</p> Signup and view all the answers

What do you mean by an air pollutant?

<p>An air pollutant is a substance in the air that can cause harm to humans, animals, or the environment.</p> Signup and view all the answers

Name three primary air pollutants.

<p>Sulfur dioxide (SO2), carbon monoxide (CO), and nitrogen oxides (NOx).</p> Signup and view all the answers

Identify as primary or secondary air pollutant: SO2, CH4, HNO3, NH3, H2SO4, O3.

<p>CH4 - Primary</p> Signup and view all the answers

Why is CO2 called a greenhouse gas?

<p>CO2 is called a greenhouse gas because it traps heat in the atmosphere, preventing it from escaping into space.</p> Signup and view all the answers

Why are flood risks increasing?

<p>Flood risks are increasing due to climate change, which is causing more extreme weather events and rising sea levels.</p> Signup and view all the answers

Comment: burning in open air is preferred.

<p>Burning in open air is often preferred to avoid toxic build-up in confined spaces; however, it can still contribute to air pollution.</p> Signup and view all the answers

How are sulfur-containing compounds emitted naturally?

<p>Sulfur-containing compounds are emitted naturally through volcanic eruptions, bacterial decay of organic matter, and forest fires.</p> Signup and view all the answers

How does combustion of fossil fuels in internal combustion engines produce oxides of nitrogen?

<p>NO is formed by the direct combination of nitrogen and oxygen during the high temperatures of fuel combustion.</p> Signup and view all the answers

How is acid rain produced?

<p>Acid rain is produced when rainwater combines with sulfur dioxide and nitrogen oxides in the atmosphere to form sulfuric and nitric acids.</p> Signup and view all the answers

Why does acid rain damage buildings?

<p>Acid rain damages buildings by reacting with materials such as limestone and marble, leading to erosion.</p> Signup and view all the answers

How is aquatic life affected by acid rain?

<p>Acid rain lowers the pH of water bodies, which can harm aquatic organisms and disrupt ecosystems.</p> Signup and view all the answers

Why are plants dying day by day?

<p>Plants can die due to conditions caused by acid rain, such as soil acidification and direct leaf damage.</p> Signup and view all the answers

Justify why ozone is beneficial for humankind.

<p>Ozone is beneficial as it protects the Earth from harmful ultraviolet radiation, reducing the risk of skin cancer and other health issues.</p> Signup and view all the answers

Why is ozone depleting in the atmosphere?

<p>Ozone is depleting due to the release of chlorofluorocarbons (CFCs) and other chemicals that break down ozone molecules.</p> Signup and view all the answers

What do you mean by ozone hole?

<p>The ozone hole refers to regions of significant depletion of the ozone layer, particularly over Antarctica.</p> Signup and view all the answers

Where is the ozone layer found?

<p>The ozone layer is found in the stratosphere, approximately 25 to 30 kilometers above the Earth's surface.</p> Signup and view all the answers

Explain the phenomenon of decreasing temperature in the troposphere.

<p>Temperature decreases with altitude in the troposphere due to the decreasing density of air and the fact that the Earth's surface, which absorbs heat from the sun, is the primary source of warmth.</p> Signup and view all the answers

Differentiate between primary and secondary air pollutants.

<p>Primary air pollutants are emitted directly from a source, such as carbon monoxide (CO), while secondary air pollutants are not emitted directly but form in the atmosphere through chemical reactions, such as ozone (O3).</p> Signup and view all the answers

State the major sources of CO and CO2 emission.

<p>Major sources of CO emissions include vehicle exhaust, industrial processes, and residential heating, while CO2 emissions predominantly come from fossil fuel combustion, deforestation, and industrial activities.</p> Signup and view all the answers

How is CO2 responsible for heating up the atmosphere?

<p>CO2 traps heat in the atmosphere through the greenhouse effect, where it absorbs and re-emits infrared radiation, contributing to global warming.</p> Signup and view all the answers

CO is a hidden enemy, explain its action.

<p>Carbon monoxide (CO) binds with hemoglobin in the blood more effectively than oxygen, reducing the amount of oxygen transported in the body, which can lead to serious health issues.</p> Signup and view all the answers

What threats are there to human health due to SO2 gas as an air pollutant?

<p>SO2 can cause respiratory problems, aggravate existing heart diseases, and contribute to the formation of acid rain, which can harm the environment.</p> Signup and view all the answers

Which air pollutant is produced on anaerobic decomposition of organic matter?

<p>Methane (CH4) is produced during anaerobic decomposition of organic matter.</p> Signup and view all the answers

How does acid rain increase the acidity of soil?

<p>Acid rain lowers the pH of soil by introducing sulfuric and nitric acids, which leach base cations from the soil, leading to increased acidity.</p> Signup and view all the answers

Point out two serious effects of ozone depletion.

<p>Ozone depletion can lead to increased UV radiation reaching the Earth's surface, resulting in higher rates of skin cancer and cataracts, and negatively affecting ecosystems.</p> Signup and view all the answers

How is the ozone layer formed in the stratosphere?

<p>The ozone layer is formed when oxygen molecules (O2) are split by ultraviolet (UV) radiation, and the free oxygen atoms react with other oxygen molecules to create ozone (O3).</p> Signup and view all the answers

Why does 75% of the atmospheric mass lie within the troposphere?

<p>The troposphere contains most of the atmospheric mass because it is the closest layer to the Earth's surface, where gravitational forces are strongest, and it holds the majority of air molecules.</p> Signup and view all the answers

How is the ozone layer being depleted by chlorofluorocarbons?

<p>Chlorofluorocarbons (CFCs) release chlorine atoms in the stratosphere, which catalyze the breakdown of ozone molecules, leading to ozone layer depletion.</p> Signup and view all the answers

Write down the significance of atmospheric gases.

<p>Atmospheric gases are essential for maintaining life, regulating temperature, supporting weather patterns, and facilitating processes such as photosynthesis.</p> Signup and view all the answers

Give the characteristics of troposphere. Why does temperature decrease upwards in this sphere?

<p>The troposphere is characterized by weather phenomena, a decrease in temperature with height, and a higher concentration of water vapor and pollutants near the surface.</p> Signup and view all the answers

What are the characteristics of the stratosphere? Why does temperature increase upwards in this sphere?

<p>The stratosphere contains the ozone layer, has a stable temperature profile, and experiences temperature increases due to ozone absorption of UV radiation.</p> Signup and view all the answers

CO2 is necessary for plants but why is its increasing concentration alarming for us?

<p>Increasing CO2 concentration enhances the greenhouse effect, leading to climate change, which can disrupt ecosystems and human activities.</p> Signup and view all the answers

Why is CO considered a health hazard?

<p>CO is considered a health hazard because it can prevent oxygen from binding to hemoglobin in the blood, leading to asphyxiation and other serious health issues.</p> Signup and view all the answers

Define acid rain. How is it formed and what are its effects?

<p>Acid rain is precipitation that has a lower pH due to the presence of sulfuric and nitric acids, formed from SO2 and NOx emissions reacting in the atmosphere. It can damage ecosystems, infrastructure, and human health.</p> Signup and view all the answers

Compounds of sulphur are air pollutants. Describe the sources of these compounds along with their effects.

<p>Sources of sulfur compounds include fossil fuel combustion, volcanic eruptions, and industrial processes. Their effects can include respiratory problems and contributions to acid rain.</p> Signup and view all the answers

Where does the ozone layer lie in the atmosphere? How is it depleting and how can we prevent its depletion?

<p>The ozone layer lies within the stratosphere. It is depleting mainly due to human-made chemicals like CFCs. Prevention can involve phasing out these substances and enhancing regulations.</p> Signup and view all the answers

Oxides of nitrogen cause air pollution. Describe the sources of these compounds.

<p>Sources of nitrogen oxides include vehicle emissions, industrial processes, and combustion of fossil fuels, which contribute to smog and respiratory issues.</p> Signup and view all the answers

Study Notes

Environmental Chemistry I: The Atmosphere

Composition of Atmosphere

  • The atmosphere is an envelope of different gases around the Earth
  • About 99% of atmospheric mass lies within 30 kilometers of the surface
  • The atmosphere is divided into four regions: troposphere, stratosphere, mesosphere, and thermosphere
  • Percentage composition of atmosphere by volume:
    • Nitrogen: 78.09%
    • Oxygen: 20.94%
    • Argon: 0.93%
    • Carbon dioxide: 0.03%

Layers of Atmosphere

  • Troposphere: extends up to 12 km, temperature decreases regularly from 17°C to -58°C
  • Stratosphere: extends up to 50 km, temperature rises gradually up to 2°C
  • Mesosphere: covers up to 85 km, temperature decreases down to -93°C
  • Thermosphere: temperature increases upwards

Characteristics of Troposphere and Stratosphere

  • Troposphere:
    • Major constituents: nitrogen and oxygen gases
    • Carbon dioxide and water vapors play a significant role in maintaining temperature
    • Temperature decreases at a rate of 6°C per kilometer
  • Stratosphere:
    • Presence of ozone (due to absorption of radiation) is responsible for the rise of temperature
    • Ozone layer exists in mid-stratosphere

Air Pollutants

  • Three factors determine the severity of a pollutant: chemical nature, concentration, and persistence
  • Types of pollutants:
    • Primary pollutants: waste products driven out due to combustion of fossil fuels and organic matter (e.g. oxides of sulfur, carbon, and nitrogen, hydrocarbon, ammonia, and compounds of fluorine)
    • Secondary pollutants: produced by various reactions of primary pollutants (e.g. sulfuric acid, carbonic acid, nitric acid, hydrofluoric acid, ozone, and peroxyacetyl nitrate)
  • Sources of air pollutants:
    • Oxides of carbon (CO2 and CO): combustion of fossil fuels, decomposition of organic matter, and volcanic eruptions
    • Oxides of sulfur (SO2 and SO3): combustion of fossil fuels, decomposition of organic matter, and volcanic eruptions
    • Oxides of nitrogen (NOx): combustion of fossil fuels, decomposition of organic matter, and electrical lightening in air

Effects of Air Pollutants

  • CO: highly poisonous, binds with haemoglobin, hindering oxygen supply to the body
  • CO2: contributes to greenhouse effect and global warming
  • SO2: forms sulfuric acid, damages buildings and vegetation, and causes respiratory problems
  • NOx: forms nitric acid, contributes to acid rain, and irritates breathing passage

Control of Air Pollution

  • Role of government: improve fuel quality, make combustion engines efficient, and preserve the natural environment### Air Pollution and Its Effects
  • Burning of fossil fuels produces air pollutants, such as oxides of sulphur and nitrogen, which contribute to acid rain formation.
  • Government should promote the use of alternative fuels, such as methanol, ethanol, and bio-diesel, which are less polluting than hydrocarbons.
  • Battery-powered electric vehicles can reduce carbon dioxide production, a greenhouse gas.

Acid Rain and Its Effects

  • Acid rain is formed when rain water dissolves acidic air pollutants, such as sulphur dioxide and nitrogen dioxide, reducing the pH of rain water to 4.
  • Effects of acid rain include:
    • Leaching heavy metals into soil and water, affecting human health and aquatic life.
    • Damaging buildings and monuments by reacting with calcium carbonate.
    • Increasing soil acidity, affecting plant growth and tree health.
    • Directly damaging leaves and limiting plant growth.

Ozone Depletion and Its Effects

  • Ozone (O3) is an allotropic form of oxygen, formed in the atmosphere by the association of an oxygen atom with an oxygen molecule.
  • Ozone layer, present in the stratosphere, protects the Earth from harmful ultraviolet radiations of sunlight.
  • Chlorofluorocarbons (CFCs) are the major cause of ozone layer depletion, reacting with ozone to form oxygen and chlorine free radicals.
  • Effects of ozone depletion include:
    • Increased risk of skin cancer and infectious diseases.
    • Disruption of the food chain and climate changes.

Incineration of Waste Material

  • Incineration reduces the volume of solid waste by 80-85%, but produces poisonous gases and toxic ash, including dioxins, furans, and particulate matter.
  • Key air pollutants from incineration include sulphur dioxide, carbon dioxide, carbon monoxide, and hydrochloric acid.

Filtration of Suspended Impurities

  • Filtration separates insoluble solid particles from a liquid using a filter paper, with the mixture being poured into the filter paper and the filtrate being collected in a conical flask.
  • The solid particles deposit on the filter paper and are dried, leaving a residue.

Atmosphere and Air Pollutants

  • Atmosphere is divided into four regions: troposphere, stratosphere, mesosphere, and thermosphere.
  • Natural sources of air pollutants include volcanic eruptions and decomposition of organic matter.
  • Human activities, such as burning fossil fuels, open air fires, and forest fires, contribute to air pollution.
  • CO2 forms a layer around the Earth, absorbing infrared radiations and causing the greenhouse effect.
  • CO is highly poisonous and a health hazard, while SO2 is also a health hazard and forms sulphuric acid by combining with water vapours in air, contributing to acid rain.

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Learn about the atmosphere, its composition, and the difference between stratosphere and troposphere. This quiz covers the basics of environmental chemistry.

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