Energy Storage Technologies Overview

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Questions and Answers

What is the most common means of storing energy for later use?

  • Hydrogen fuel cells
  • Pumped hydro plants
  • Batteries (correct)
  • Capacitors

Which component of a battery is responsible for separating the anode and cathode?

  • Oxidizer
  • Conductor
  • Electrolyte (correct)
  • Electrode

During battery discharge, what occurs at the anode?

  • Oxidation occurs (correct)
  • Ions move to the cathode
  • Reduction occurs
  • Electrons are created

What is the typical efficiency range of batteries?

<p>80-85% (D)</p> Signup and view all the answers

What type of energy storage involves the use of heat?

<p>Thermodynamic energy storage (A)</p> Signup and view all the answers

Which statement is true about the movement of ions during battery charging?

<p>Ions move back to their respective electrodes (D)</p> Signup and view all the answers

What happens to battery charge over time due to self-discharge?

<p>Charge decreases (A)</p> Signup and view all the answers

What are hydrogen fuel cells classified as in terms of energy storage technology?

<p>Electrochemical energy storage (D)</p> Signup and view all the answers

What happens to the available charge from a battery as the current discharge increases?

<p>It declines due to internal resistance. (B)</p> Signup and view all the answers

Which metric represents the total energy a battery can deliver before needing a charge?

<p>Charge capacity (D)</p> Signup and view all the answers

What occurs when batteries are connected in parallel?

<p>The total voltage equals the voltage of a single battery. (B)</p> Signup and view all the answers

Why is it important to charge batteries at a higher voltage than their rated voltage?

<p>It ensures the reaction is driven to completion. (D)</p> Signup and view all the answers

How is specific energy of a battery defined?

<p>Wh/kg (A)</p> Signup and view all the answers

What effect does a decrease in temperature have on a battery's performance?

<p>It reduces the available charge from the battery. (A)</p> Signup and view all the answers

What is the primary difference between batteries and hydrogen fuel cells?

<p>Batteries utilize stored energy, while fuel cells use a fuel source. (D)</p> Signup and view all the answers

Which of the following represents power loss in a battery?

<p>current output2 x internal resistance (D)</p> Signup and view all the answers

What does the standard reduction potential (SRP) indicate?

<p>The ease with which an electrode will be reduced. (A)</p> Signup and view all the answers

In a lead acid battery, what is the SRP at the cathode?

<p>+1.7 V (A)</p> Signup and view all the answers

What happens to the SRP at the anode during battery operation?

<p>It becomes negative. (A)</p> Signup and view all the answers

How is the total voltage of a redox reaction in a lead acid battery calculated?

<p>It is the positive SRP at the cathode plus the voltage at the anode. (C)</p> Signup and view all the answers

What describes a series arrangement of batteries?

<p>Anodes in one battery connect directly to cathodes in another battery. (C)</p> Signup and view all the answers

Which statement accurately describes the voltage addition in series battery arrangements?

<p>The total voltage is the sum of the individual battery voltages. (C)</p> Signup and view all the answers

What is the voltage of the redox reaction at the anode in a lead acid battery?

<p>+0.35 V (A)</p> Signup and view all the answers

What is the correct relationship between SRP and spontaneity of a reaction?

<p>More positive SRP indicates a more spontaneous reaction. (C)</p> Signup and view all the answers

Which component of a battery acts as a separator between the electrodes?

<p>Electrolyte (C)</p> Signup and view all the answers

During battery discharge, which process occurs at the anode?

<p>Oxidation and loss of electrons (B)</p> Signup and view all the answers

What is the primary reason for a battery's efficiency being in the range of 80-85%?

<p>Internal resistance of ion movement (D)</p> Signup and view all the answers

In which energy storage category does a pumped hydroelectric dam fall?

<p>Mechanical (C)</p> Signup and view all the answers

What movement occurs in a battery when it is charging?

<p>Electrons flow from cathode to anode (D)</p> Signup and view all the answers

What type of reaction encompasses both the oxidation and reduction processes in a battery?

<p>Redox reaction (A)</p> Signup and view all the answers

Which type of energy storage system draws energy from non-electric sources?

<p>Pumped hydro plants (B)</p> Signup and view all the answers

What mechanism allows for self-discharge in batteries over time?

<p>Internal resistance (B)</p> Signup and view all the answers

When batteries are connected in parallel, how is the current output affected?

<p>Current output is the summed output from all the batteries. (C)</p> Signup and view all the answers

Which parameter is used to express battery capacity?

<p>Amp-hours (Ah) (C)</p> Signup and view all the answers

What is the reason for charging batteries at a voltage higher than their rated voltage?

<p>To ensure the electrochemical reaction is driven to completion. (A)</p> Signup and view all the answers

What effect does decreasing temperature have on battery charge availability?

<p>Charge availability declines due to slower electrochemical reactions. (B)</p> Signup and view all the answers

Which of the following denotes energy capacity in batteries?

<p>Volts multiplied by Amp-hours (V x Ah) (C)</p> Signup and view all the answers

Which equation correctly represents the relationship of power loss in a battery?

<p>Power loss = current output^2 x battery's internal resistance. (A)</p> Signup and view all the answers

What does a more positive standard reduction potential (SRP) indicate about a chemical reaction?

<p>The reaction occurs more spontaneously. (D)</p> Signup and view all the answers

In a battery, where is the standard reduction potential (SRP) positive?

<p>At the cathode during reduction. (A)</p> Signup and view all the answers

When batteries are connected in series, what happens to the total voltage?

<p>The total voltage adds together. (C)</p> Signup and view all the answers

How is the voltage at the anode expressed when considering the oxidation reaction?

<p>As the inverse of SRP, thus positive. (B)</p> Signup and view all the answers

For a lead acid battery, if the SRP at the cathode is +1.7 V and at the anode is -0.35 V, what is the total redox reaction voltage?

<p>About 2.00 V. (A)</p> Signup and view all the answers

What is the characteristic of battery connections when arranged in parallel?

<p>The anodes are connected to each other. (C), The cathodes are connected to each other. (D)</p> Signup and view all the answers

What does the term standard reduction potential (SRP) specifically measure?

<p>The tendency for a substance to gain electrons. (D)</p> Signup and view all the answers

What is the relationship between the SRP at the cathode and the total voltage calculation in a redox reaction?

<p>Total voltage is the sum of the cathode SRP and anode SRP. (A), Total voltage includes the inverse of the anode's SRP. (C)</p> Signup and view all the answers

What percentage of the nation's primary energy consumption is accounted for by buildings?

<p>40% (A)</p> Signup and view all the answers

What is the main factor that affects conductive heat loss in buildings?

<p>Building material thermal conductance (D)</p> Signup and view all the answers

Which metric is primarily used to estimate a building's heating and cooling needs?

<p>Degree day (B)</p> Signup and view all the answers

What is the term for the inverse of thermal conductance in buildings?

<p>Thermal resistance (A)</p> Signup and view all the answers

Why is space conditioning considered the biggest energy draw for buildings?

<p>It encompasses heating and cooling needs. (C)</p> Signup and view all the answers

What potential consequence of energy efficiency improvements is noted as a limitation?

<p>Greater overall energy use for certain technologies (B)</p> Signup and view all the answers

What is one of the primary energy services that could benefit from increased efficiency in buildings?

<p>Heating and cooling services (B)</p> Signup and view all the answers

How much of the nation's electricity use is attributed to buildings?

<p>70% (B)</p> Signup and view all the answers

What happens to heat transfer when the outside temperature is similar to the inside temperature?

<p>Minimal heat transfer occurs due to low temperature difference. (D)</p> Signup and view all the answers

How does an increase in the U rating of building materials affect energy efficiency?

<p>It causes the building to lose heat more easily. (B)</p> Signup and view all the answers

Which factor is significantly important for conduction in buildings?

<p>Interior volume. (B)</p> Signup and view all the answers

What is the primary energy consumption source in commercial buildings related to air quality?

<p>Ventilation systems. (C)</p> Signup and view all the answers

What role does refrigerant play in an air conditioning system?

<p>It absorbs heat from the warm area and releases it outside. (B)</p> Signup and view all the answers

During the cooling process in an air conditioner, which phase change occurs to the refrigerant?

<p>It evaporates to absorb heat. (B)</p> Signup and view all the answers

What is the correct sequence of the refrigerant cycle in air conditioning?

<p>Liquid absorbs heat, evaporates, compresses, and cools. (B)</p> Signup and view all the answers

What is the main energy draw of an air conditioning system?

<p>Electricity to pump and compress the refrigerant. (D)</p> Signup and view all the answers

What percentage of the U.S. primary energy consumption is attributed to buildings?

<p>40% (A)</p> Signup and view all the answers

Which of the following factors does NOT affect conductive heat loss in buildings?

<p>External air pressure (B)</p> Signup and view all the answers

Which metric is used to estimate a building's heating and cooling needs?

<p>Degree Day (B)</p> Signup and view all the answers

What does the inverse of thermal conductance represent in building energy efficiency?

<p>Thermal Resistance (D)</p> Signup and view all the answers

Which of the following statements about energy savings in buildings is true?

<p>The implementation of energy-efficient technologies can sometimes increase energy use. (A)</p> Signup and view all the answers

Which of the following contributes most significantly to energy consumption in buildings?

<p>Space conditioning (B)</p> Signup and view all the answers

What is the primary purpose of reducing energy use in buildings?

<p>To reduce greenhouse gas emissions (D)</p> Signup and view all the answers

What are the two main ways buildings lose or gain heat from their surroundings?

<p>Conduction and convection (D)</p> Signup and view all the answers

What is the significance of a higher R rating in building materials?

<p>Represents a material that is more effective at insulating. (C)</p> Signup and view all the answers

Which factor does NOT significantly influence conduction heat transfer in buildings?

<p>Quality of building materials used. (B)</p> Signup and view all the answers

What is the primary energy draw for an A/C system?

<p>Electricity needed to compress and pump refrigerant. (B)</p> Signup and view all the answers

What happens during the cooling process in an A/C system?

<p>Heat is absorbed from the inside and released outdoors. (D)</p> Signup and view all the answers

Which statement best describes the outside-inside temperature difference for minimal heat transfer?

<p>Requires a significant temperature difference. (C)</p> Signup and view all the answers

What is a major consequence of inadequate ventilation in buildings?

<p>Higher risk of airborne diseases. (B)</p> Signup and view all the answers

In commercial buildings, which aspect of ventilation represents the greatest source of energy consumption?

<p>Energy used to drive the ventilation system. (C)</p> Signup and view all the answers

What primary role does the refrigerant play in an A/C system?

<p>It absorbs heat and facilitates the cooling cycle. (D)</p> Signup and view all the answers

Flashcards

Standard Reduction Potential (SRP)

A measure of how easily an electrode gains electrons (reduction). It determines the spontaneity of a redox reaction, and is measured in volts.

Battery Components

Batteries have three key parts: a negative anode, a positive cathode, and an electrolyte separating them.

Battery Discharge Electron Flow

During discharge, electrons move from the negative anode to the positive cathode through a connected wire.

SRP and Spontaneity

More positive SRP values indicate more spontaneous reduction reactions.

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Battery Discharge Ion Flow

Ions move between the electrodes through the electrolyte during battery discharge.

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SRP at Cathode

The SRP value of the substance being reduced (at the cathode).

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Battery Charging Process

During charging, electrons flow from the cathode to the anode, and ions move to their original electrodes.

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SRP at Anode

The SRP value of the substance being oxidized (at the anode).

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Oxidation at Anode

The opposite of reduction (loss of electrons) at the anode. Its SRP is opposite in sign.

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Battery Efficiency

Battery efficiency is around 80-85% because of internal resistance and some heat loss.

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Voltage in Series Arrangement

A series battery arrangement adds voltages of individual batteries.

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Battery Self-Discharge

Batteries slowly lose their charge over time due to ongoing chemical reactions.

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Battery Series Connection

Batteries connected end-to-end, with the positive terminal of one connected to the negative terminal of the next.

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Redox Reaction

A chemical reaction consisting of oxidation and reduction reaction (both happening at the same time).

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Battery Voltage Source

The voltage of a battery comes from chemical reactions that produce electrons at one electrode and consume them at the other (oxidation and reduction).

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Battery Parallel Connection

Batteries connected side-by-side, with the positive terminals connected and the negative terminals connected.

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Battery voltage in parallel

The voltage of a single battery when connected in parallel circuits

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Battery current in parallel

The combined current output of all batteries when connected in parallel

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Battery capacity (Ah)

Total charge a battery can hold (current x time)

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Battery power loss

Power loss due to internal resistance (current squared x resistance)

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Battery energy capacity (Wh)

Energy a battery can store (voltage x capacity (Ah))

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Battery charge voltage

Voltage needed to charge a battery to completion.

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Battery discharge voltage decline

Battery voltage decreases during discharge due to internal resistance.

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Types of Energy Storage

Energy storage technologies can be categorized based on the way energy is stored. Common types include electrochemical (batteries, fuel cells), electromagnetic (capacitors), thermodynamic (compressed air, ice, molten salt), and mechanical (pumped hydro, flywheels).

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Electrochemical Energy Storage

This type of energy storage uses chemical reactions to store and release energy. Examples include batteries and hydrogen fuel cells.

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How Batteries Work

During discharge, electrons move from the anode to the cathode through a conductor, while ions move through the electrolyte. This is like a chemical reaction releasing energy. During charging, the process is reversed, electrons flow from cathode to anode, ions move back, and energy is stored.

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What Causes Battery Voltage?

Voltage in a battery arises from chemical reactions at the electrodes. Oxidation occurs at the anode (loss of electrons), and reduction occurs at the cathode (gain of electrons). These reactions create a potential difference, resulting in voltage.

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Hydrogen Fuel Cells

These devices convert stored chemical energy in hydrogen into electricity through a chemical process. They offer a potential solution for energy storage and clean energy production.

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What is SRP?

The Standard Reduction Potential (SRP) measures how easily a substance gains electrons (reduction) in a redox reaction. It is measured in volts and indicates the spontaneity of the reaction.

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How does SRP relate to spontaneity?

A more positive SRP value indicates a more spontaneous reduction reaction. This means the substance is more likely to gain electrons.

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What is the difference between SRP at the anode and cathode?

The SRP at the cathode is positive because reduction is occurring, meaning the substance is gaining electrons. At the anode, the SRP is negative because oxidation is occurring, meaning the substance is losing electrons.

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Battery Voltage

The total voltage of a battery is the sum of the SRP at the cathode (positive) and the inverse of the SRP at the anode (also positive).

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Series Battery Arrangement

In a series arrangement, the anode of one battery connects to the cathode of the next, and so on. This adds up the individual voltages of each battery.

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Parallel Battery Arrangement

In a parallel arrangement, all anodes are connected together and all cathodes are connected together. This increases the current capacity but keeps the voltage the same as a single battery.

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Oxidation at the Anode

At the anode, oxidation occurs, meaning the substance loses electrons. The SRP for oxidation is the inverse of the SRP for reduction (a negative value).

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Why is anode SRP negative?

The SRP measures the spontaneity of reduction, but at the anode, oxidation (loss of electrons) is occurring. So, the SRP for the anode is expressed as a negative value.

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Battery Voltage in Series

When batteries are connected in series, the total voltage is the sum of the individual battery voltages.

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Battery Charge Capacity

The amount of electrical charge a battery can store, measured in Amp-hours (Ah).

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Battery Energy Capacity

The total amount of energy a battery can store, measured in Watt-hours (Wh).

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Battery Voltage Decline

As a battery discharges, its voltage decreases due to internal resistance and power loss.

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Battery Performance and Temperature

Lower temperatures reduce the rate of chemical reactions within a battery, leading to decreased charge availability.

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Building Energy Use

Buildings consume a large portion of energy, especially for heating and cooling.

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Space Conditioning

The process of heating or cooling a building to maintain a comfortable temperature.

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Conduction

The transfer of heat through direct contact between materials.

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Convection

Heat transfer through the movement of fluids (liquids or gases).

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Thermal Conductance (U)

A measure of how easily heat flows through a material.

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Thermal Resistance (R)

The opposite of thermal conductance, indicating how well a material resists heat flow.

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Degree Day

A measure of how much heating or cooling a building needs based on the difference between the average daily temperature and a comfort setpoint.

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Energy Efficiency Potential

The potential to reduce energy consumption through upgrades and technologies in buildings.

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R-rating of building material

Indicates how well a building material insulates against heat loss or gain. A higher R-rating means better insulation.

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U-value of a building

Represents how easily heat can pass through a building component, like a wall or window. A lower U-value signifies better insulation.

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Temperature difference impact on heat transfer

The greater the temperature difference between the inside and outside of a building, the more significant the heat transfer will be.

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Conduction heat loss/gain

Heat transfer due to the physical movement of air in and out of a building. It's influenced by building volume, temperature difference, and ventilation rates.

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Ventilation's role in energy consumption

Ventilation is crucial for healthy indoor environments but also a major source of energy consumption in commercial buildings.

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Basic heating technologies

Common methods of heating a building include furnaces and electric heaters.

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Basic cooling technologies

Air conditioning units work by using a refrigerant to absorb heat from a warm area and release it outside, cooling the enclosed space.

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Refrigerant's role in cooling

Refrigerant, like ammonia, changes state from liquid to gas, absorbing heat, and then back to liquid, releasing heat, to achieve cooling.

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Buildings and Energy Consumption

Buildings are responsible for 40% of the US primary energy use and 70% of its electricity consumption, mainly due to heating and cooling needs.

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Conduction Heat Transfer

Heat moves through a material by direct contact, like touching a hot stove. The hotter the material, the more heat it transfers.

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What is Convection?

Heat transfer through the movement of fluids (liquids or gases). Think of hot air rising and cold air sinking.

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Understanding Thermal Conductance (U)

Measures how easily heat flows through a material. A high U-value means heat passes easily, like a thin window.

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Thermal Resistance (R) Explained

Measures a material's ability to resist heat flow. Think of thick insulation on a wall.

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Degree Day: Heating and Cooling Needs

A measure of how much heating or cooling a building needs based on daily temperature differences.

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Impact of Efficiency on Energy Use

While efficiency can reduce energy use, sometimes it can lead to increased energy use for certain technologies, like lighting.

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U-value of a building component

Represents how easily heat can pass through a building component, like a wall or window. A lower U-value signifies better insulation. For example, a window with a U-value of 0.3 will allow less heat to pass through than a window with a U-value of 1.

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Study Notes

Energy Storage Technologies

  • Various technologies store electrical energy for later use, from seconds to many hours.
  • Some technologies take energy from non-electrical sources (e.g., pumped hydro).
  • Others store electrical energy and release it as another form (e.g., ice storage).
  • Batteries are the most common energy storage method.

Lecture Outline: Major Forms of Energy Storage

  • Electrochemical:
    • Batteries
    • Hydrogen fuel cells
  • Electromagnetic:
    • Capacitors
  • Thermodynamic:
    • Compressed air
    • Ice
    • Molten salt
  • Mechanical:
    • Pumped hydroelectric dams
    • Flywheels

Battery Basics

  • Components:
    • Negative anode
    • Positive cathode
    • Electrolyte (separates electrodes)
  • Charging:
    • Electrons flow from anode to cathode through conductor.
    • Ions move between electrodes via electrolyte.
  • Efficiency:
    • 80-85% due to internal resistance and heat loss.
  • Self-Discharge:
    • Batteries lose charge over time.

Battery Voltage Source

  • Chemical reactions at both electrodes during discharge:
    • Oxidation (loss of electrons) at the anode.
    • Reduction (gain of electrons) at the cathode.
  • These are half-reactions of a redox reaction.

Standard Reduction Potential (SRP)

  • Measures the ease of reduction of an electrode.
  • Higher SRP values indicate more spontaneous reduction reactions.
  • Positive SRP at the cathode (reduction).
  • Negative SRP at the anode (oxidation).
  • Total voltage is the sum of anode and cathode SRP values.

Battery Arrangement

  • Series: Connecting anodes to cathodes of multiple batteries.
    • Adds battery voltages.
    • Current output from a single battery.
  • Parallel: Connecting anodes to anodes and cathodes to cathodes of multiple batteries.
    • Adds battery capacities.
    • Summed current output from all batteries.

Battery Metrics

  • Voltage: Electrical potential difference
  • Current output: Flow rate of charge.
  • Power output: Rate of energy transfer.
  • Power loss: Voltage loss due to internal resistance.
  • Charge capacity: Amount of charge a battery stores (measured in Ah).
  • Energy capacity: Total energy stored (measured in Wh).
  • Energy density: Energy stored per unit volume.
  • Power density: Power output per unit volume.
  • Specific energy: Energy stored per unit mass (Wh/kg).
  • Specific power: Power output per unit mass (W/kg).

Battery Performance

  • Charging at higher voltage than rated ensures reaction completion.
  • Battery voltage decreases during discharge due to internal resistance.
  • Charge capacity reduced as current discharge increases due to internal resistance.
  • Rate of electrochemical reactions reduces with decreasing temperature.

Hydrogen Fuel Cells

  • Produce energy via fuel (hydrogen), not by storing it.
  • Hydrogen can come from electrolysis or methane reformation.
  • Electrolysis of water produces hydrogen and oxygen.

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