Emergency Preparedness and Fire Safety

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Questions and Answers

What is the flash point of a flammable liquid?

  • The temperature at which it spontaneously ignites
  • The lowest temperature at which it gives off vapor to ignite (correct)
  • The temperature at which it can no longer burn
  • The maximum temperature before it forms an explosive mixture

At what concentration of flammable vapors should a work permit for confined space entry be issued?

  • 100% of LEL (correct)
  • 1% of LEL
  • 10% of LEL
  • 0.5% of LEL

What is a correct statement regarding the auto-ignition temperature?

  • It requires an external ignition source
  • It is always lower than the flash point
  • It is the highest temperature for ignition
  • It is always higher than both flash point and fire point (correct)

Which gas law relates volume and temperature of a gas at constant pressure?

<p>Charles' Law (B)</p> Signup and view all the answers

What does the Lower Explosive Limit (LEL) signify?

<p>The minimum concentration for flame propagation (B)</p> Signup and view all the answers

How can 1 PPM of benzene be converted to mass per volume concentration?

<p>Apply the formula Mg/m3 x 24.45 (D)</p> Signup and view all the answers

What should be true about the Upper Explosive Limit (UEL)?

<p>It is the maximum concentration where flame propagation does not occur (A)</p> Signup and view all the answers

For a mixture containing 50% methane (LEL 5%) and 50% propane (LEL 2%), how can the LEL be calculated?

<p>Using LEL of each gas in a weighted average (B)</p> Signup and view all the answers

What is Boyle's Law primarily concerned with?

<p>The relationship between gas volume and pressure at constant temperature (C)</p> Signup and view all the answers

Which law states that the volume of a fixed mass of gas is inversely proportional to its pressure at constant temperature?

<p>Boyle's law (A)</p> Signup and view all the answers

What does Avogadro's law relate to in terms of gas properties?

<p>Volume and number of molecules at constant temperature and pressure (D)</p> Signup and view all the answers

Which equation represents the relationship between pressure, volume, and temperature for a fixed mass of gas?

<p>PV = nRT (A)</p> Signup and view all the answers

How does heat transfer by conduction occur?

<p>From hotter to colder parts without movement of molecules (B)</p> Signup and view all the answers

In the context of convection, what does the heat transfer coefficient (H) account for?

<p>Rate of heat transfer in fluids (D)</p> Signup and view all the answers

Which mode of heat transfer does not require any medium for the transfer of energy?

<p>Radiation (D)</p> Signup and view all the answers

What is the primary relationship defined by Gay-Lussac's law?

<p>Pressure is directly proportional to absolute temperature at constant volume (C)</p> Signup and view all the answers

Which equation is correctly associated with radiation heat transfer?

<p>Q = εσA(T^4) (A)</p> Signup and view all the answers

What is a key characteristic of the combined gas law?

<p>It interrelates pressure, volume, and temperature for a fixed mass of gas. (B)</p> Signup and view all the answers

Given a cylinder of hydrogen at 5 ft³ under 1,000 psig pressure, what would be the approximate volume of hydrogen released into the atmosphere if the valve breaks?

<p>5,000 ft³ (B)</p> Signup and view all the answers

Which class of hazardous location is characterized by the presence of flammable vapours and gases?

<p>Class 1 (D)</p> Signup and view all the answers

What is identified as the most critical factor to address in emergency response plans?

<p>How to protect people, property, and the environment (D)</p> Signup and view all the answers

What are the standards developed by the National Fire Protection Association (NFPA) for fire prevention known as?

<p>National Fire Code (A)</p> Signup and view all the answers

What defines the autoignition temperature of a material?

<p>It is the minimum temperature for combustion without an ignition source. (B)</p> Signup and view all the answers

What simultaneous elements are required for combustion reactions to occur?

<p>Fuel, heat, source of ignition, and air (A)</p> Signup and view all the answers

What is the primary consideration to prevent fire loss in a storage area for flammable liquids?

<p>Compatible storage (C)</p> Signup and view all the answers

Why is carbon monoxide (CO) particularly dangerous in fire situations?

<p>It is the most toxic of all gases produced in fire. (D)</p> Signup and view all the answers

In a fire situation, the gaseous products of combustion exhibit a vapor density of less than 1. This implies that the air is at which location?

<p>Low spot (D)</p> Signup and view all the answers

What is the relationship between fire point and flash point?

<p>Fire point is higher than flash point. (A)</p> Signup and view all the answers

Which of the following is the most effective method to protect against explosions in storage areas?

<p>Flame arrestors and pressure relief devices (C)</p> Signup and view all the answers

Flashcards

Flash Point

The lowest temperature at which a flammable liquid gives off enough vapors to ignite and immediately extinguish when exposed to a flame.

Fire Point

The lowest temperature at which a flammable liquid produces enough vapors to ignite and sustain combustion.

Auto-ignition Temperature

The lowest temperature at which a fuel will ignite spontaneously without a separate ignition source.

Lower Explosive Limit (LEL)

The minimum concentration of flammable vapor in air needed for a flame to propagate.

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Upper Explosive Limit (UEL)

The maximum concentration of flammable vapor in air above which a flame will not propagate.

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Confined Space Work Permit

A work permit should be issued only when the concentration of flammable vapors is lower than 0.5% of the Lower Explosive Limit (LEL).

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Explosive Gas Concentration

A gas is considered explosive when its concentration is within a specific range, generally 5% to 100% of the Lower Explosive Limit (LEL).

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Boyle's Law (Gas Laws)

Boyle's Law describes the inverse relationship between the volume and pressure of an ideal gas at constant temperature. As volume increases, pressure decreases proportionally, and vice versa.

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Charles' Law (Gas Laws)

Charles' Law describes the direct relationship between the volume and absolute temperature of an ideal gas at constant pressure. As temperature increases, volume increases proportionally.

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Gay-Lussac's Law (Gas Laws)

Gay-Lussac's Law describes the direct relationship between the absolute pressure and temperature of an ideal gas at constant volume. As temperature increases, pressure increases proportionally.

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Class 1 Hazardous Location

Flammable vapors and gases pose a fire hazard.

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Class 2 Hazardous Location

Combustible dust, like flour or wood dust, can create explosive mixtures in the air.

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Class 3 Hazardous Location

Ignitable fibers, such as cotton or textiles, can easily catch fire.

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Most Critical Factor in Emergency Response

The most critical factor in emergency response planning is protecting people, property, and the environment.

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NFPA Standards

NFPA standards are a set of guidelines for fire prevention and protection in buildings and industries.

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Elements for Combustion

For combustion to occur, you need fuel, heat, a source of ignition, and air (oxygen).

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Preventing Fire Loss in Flammable Liquid Storage

The most important consideration for preventing fire loss in flammable liquid storage areas is to use a pre-action automatic sprinkler system.

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Carbon Monoxide in Fires

Carbon monoxide is a deadly gas produced in fires because it reacts with blood, preventing oxygen transport and leading to asphyxiation.

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Gases in Fire Situations

The gaseous products of combustion are lighter than air, so they tend to rise.

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Boyle's Law

At constant temperature, the volume of a gas is inversely proportional to its pressure. Imagine a balloon. If you squeeze it (increase pressure), the volume decreases.

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Charles' Law

At constant pressure, the volume of a gas is directly proportional to its absolute temperature. Think of a hot air balloon. As the air inside gets hotter (higher temperature), the balloon expands (increases volume).

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Gay-Lussac's Law

At constant volume, the pressure of a gas is directly proportional to its absolute temperature. Picture a sealed container. As you heat the gas inside (increase temperature), the pressure inside the container increases.

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Avogadro's Law

At constant temperature and pressure, the volume of a gas is directly proportional to the number of molecules present. Think of a room full of people. The more people (molecules) there are, the more space they take up (volume).

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Combined Gas Law

A combination of Boyle's Law, Charles' Law, and Gay-Lussac's Law. It shows the relationship between pressure, volume & temperature for a fixed mass of gas.

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Ideal Gas Law

A combination of Avogadro's Law and the Combined Gas Law. It describes the behavior of ideal gases - theoretical gases that obey specific rules. It shows the relationship between pressure, volume, temperature, and the number of moles of gas.

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Conduction

The transfer of heat through direct contact between substances, without physical movement of the substances themselves. Imagine a metal spoon in hot soup. The heat from the soup transfers to the spoon, making it warm.

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Convection

The transfer of heat through the movement of fluids (liquids or gases). Picture a boiling pot of water. The hot water at the bottom rises, and the cooler water at the top sinks, creating a circular flow of heat.

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Radiation

The transfer of heat through electromagnetic radiation. Think of the sun. The sun's heat reaches Earth through electromagnetic waves, without needing a medium.

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Sprinkler System

A system that uses water to suppress fires. It can be activated manually or automatically. There are several types of sprinkler systems, each designed for specific applications. Examples include Dry Pipe, Wet Pipe, and Deluge systems.

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Study Notes

Domain 5: Emergency Preparedness, Fire Prevention, and Security

  • This domain covers emergency preparedness, fire prevention, and security measures.

Flash Point

  • The flash point is the lowest temperature at which a flammable liquid gives off enough vapor to form an ignitable mixture.
  • When exposed to a flame, the mixture will ignite momentarily and self-extinguish.

Fire Point

  • The fire point is the lowest temperature at which a flammable liquid produces vapors dense enough to sustain continuous burning.

Autoignition Temperature

  • The autoignition temperature is the lowest temperature at which a fuel will spontaneously ignite in a normal atmosphere without an external ignition source.
  • This temperature is always higher than the flash point and the fire point.

Lower Explosive Limit (LEL)

  • The LEL is the minimum concentration of vapor in air below which flame propagation doesn't occur in the presence of an ignition source.
  • A work permit for entry into a confined space is required when the flammable vapor concentration is less than 0.5% of the LEL.

Upper Explosive Limit (UEL)

  • The UEL is the maximum concentration of vapor in air above which flame propagation will not happen in the presence of an ignition source.

Conversions

  • %Vol to PPM: % Volume x 10,000 = PPM
  • LEL to PPM: % LEL x LEL(%Vol) x 100 = PPM
  • PPM to mg/m³: Mg/m³ x 24.45 = PPM (MW)

NFPA Fire Diamond

  • The NFPA Fire Diamond is used for hazard classification based on health, flammability, reactivity, and specific hazard.
  • It uses color codes (blue, red, yellow, white) to indicate the level of risk in each hazard category.

Sprinkler Systems

  • Different types of sprinkler systems are available, including dry pipe, wet pipe, deluge, and pre-action systems.

Hazardous Location Classification

  • Hazardous locations are classified based on the presence of flammable vapors and gases, combustible dust, or ignitable fibers. Different classifications have various specific factors to consider.

Gas Laws

  • Gas laws describe the behavior of gases, focusing on volume, pressure, temperature, and the amount (number of moles) of gas.
  • Key gas laws include Boyle's law, Charles's law, Gay-Lussac's law, Avogadro's law, combined gas law, and the ideal gas law.

Modes of Heat Transfer

  • Heat transfer occurs through these three modes:
    • Conduction: Heat transfer within a body without molecule movement.
    • Convection: Heat transfer in fluids (liquids and gases) due to the movement of molecules or mass transfer.
    • Radiation: Heat transfer between bodies without involving the medium's molecules.

Emergency Response Plans

  • A critical factor in emergency response plans is the protection of people, property, and the environment.

Important Calculations

  • Specific calculation examples are provided for conversions and mixture calculation. Specific application details are given for each calculation as an example.

Additional Notes

  • Several example questions and their respective analysis are included.
  • These notes provide a comprehensive overview of fire prevention and emergency preparedness concepts.

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