Elements, Compounds & Mixtures Quiz

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Questions and Answers

What is the first substance to evaporate during fractional distillation of a mixture of water and ethanol?

  • Water
  • Ethanol (correct)
  • Both Evaporate Simultaneously
  • None of the Above

Fractional distillation can be used to separate liquids that are not miscible.

False (B)

At what temperature should heating be stopped during the fractional distillation of ethanol and water?

100 ºC

The boiling point of ethanol is _____ ºC.

<p>78</p> Signup and view all the answers

Match the following components with their properties:

<p>Ethanol = Boiling point of 78 ºC Water = Boiling point of 100 ºC Condenser = Cools vapors into liquid Fractional Distillation = Separates miscible liquids</p> Signup and view all the answers

Which of the following is NOT a characteristic of an element?

<p>It can be chemically combined with other elements. (C)</p> Signup and view all the answers

A compound can be separated into its elements by physical means.

<p>False (B)</p> Signup and view all the answers

What defines a compound?

<p>A pure substance made up of two or more elements chemically combined.</p> Signup and view all the answers

An example of a _____ is sand and water.

<p>mixture</p> Signup and view all the answers

Match the substance to its classification:

<p>Copper = Element Carbon Dioxide = Compound Salt Water = Mixture Iron = Element</p> Signup and view all the answers

What type of substance can be separated by filtration?

<p>Mixture (C)</p> Signup and view all the answers

There are 118 elements listed in the Periodic Table.

<p>True (A)</p> Signup and view all the answers

What is the main difference between a compound and a mixture?

<p>A compound is chemically combined while a mixture is not.</p> Signup and view all the answers

What is the primary purpose of filtration?

<p>To separate an undissolved solid from a liquid (C)</p> Signup and view all the answers

Crystallisation can be used to separate a solid that is less soluble in hot solvent than in cold.

<p>False (B)</p> Signup and view all the answers

What indicates that a solution has reached saturation during the crystallisation process?

<p>Crystals form on a glass rod dipped into the solution.</p> Signup and view all the answers

In filtration, the solid particles remain as a ______ while the liquid that passes through is called ______.

<p>residue; filtrate</p> Signup and view all the answers

Match the following processes with their correct descriptions:

<p>Filtration = Separation of undissolved solids from liquids Centrifugation = Separation of mixtures using high speed Crystallisation = Separation of dissolved solids from solutions Evaporation = Conversion of liquid to vapor to leave solids behind</p> Signup and view all the answers

What is the first step in the process of crystallisation?

<p>Heating the solution to evaporate the solvent (B)</p> Signup and view all the answers

During crystallisation, crystals grow as the solubility of the solid increases.

<p>False (B)</p> Signup and view all the answers

What is done to the crystals after they are collected from the saturated solution?

<p>They are washed with cold distilled water and allowed to dry.</p> Signup and view all the answers

What is the primary purpose of paper chromatography?

<p>To separate substances based on their solubilities (A)</p> Signup and view all the answers

In paper chromatography, the pencil line must be submerged in the solvent.

<p>False (B)</p> Signup and view all the answers

What causes the different substances to separate during paper chromatography?

<p>Different solubilities in the solvent.</p> Signup and view all the answers

In paper chromatography, substances with higher solubility will travel ______ than those with lower solubility.

<p>further</p> Signup and view all the answers

Which technique is used to separate a soluble solid like sodium chloride from a solution?

<p>Crystallisation (D)</p> Signup and view all the answers

Match the term with its correct definition:

<p>Chromatography = Technique for separating substances based on solubility Capillary action = Movement of solvent up the paper Soluble solid = Solid that dissolves in a solvent Evaporation = Process of turning liquid into vapor</p> Signup and view all the answers

Different inks will travel the same distance when subjected to paper chromatography.

<p>False (B)</p> Signup and view all the answers

Why is a pencil line preferred over an ink line in chromatography?

<p>Ink would run into the chromatogram and mix with the samples.</p> Signup and view all the answers

What does an Rf value indicate?

<p>The retention factor of a substance (D)</p> Signup and view all the answers

The Rf value of a compound remains the same regardless of the solvent used.

<p>False (B)</p> Signup and view all the answers

What is the formula to calculate the Rf value?

<p>Rf = distance moved by substance / distance moved by solvent</p> Signup and view all the answers

The maximum possible Rf value is ______.

<p>1</p> Signup and view all the answers

Which statement about Rf values is false?

<p>Rf values have units. (B)</p> Signup and view all the answers

Match the following terms with their definitions:

<p>Rf value = A ratio used to identify substances Solvent = The medium that moves the analytes Chromatography = A technique to separate mixtures Retention factor = Another term for Rf value</p> Signup and view all the answers

If a substance moves 4 cm and the solvent moves 8 cm, what is the Rf value?

<p>0.5</p> Signup and view all the answers

Calculating the Rf value does not require precise measurements.

<p>False (B)</p> Signup and view all the answers

What is the first step in the paper chromatography method?

<p>Use a ruler to draw a horizontal pencil line 2 cm from the end of the chromatography paper (B)</p> Signup and view all the answers

The unknown mixture of food colorings is labeled as T.

<p>False (B)</p> Signup and view all the answers

What should be the maximum diameter of each spot applied to the chromatography paper?

<p>2-3 mm</p> Signup and view all the answers

The paper chromatography method is used to separate and identify a mixture of _____ colorings.

<p>food</p> Signup and view all the answers

How far from the end of the chromatography paper should the pencil line be drawn?

<p>2 cm (D)</p> Signup and view all the answers

The spots for the known food colorings should be applied using the same capillary tube.

<p>False (B)</p> Signup and view all the answers

After allowing the solvent to travel, what should you draw on the dry part of the paper?

<p>solvent front line</p> Signup and view all the answers

Flashcards

Fractional Distillation

A method used to separate liquids with different boiling points from a mixture.

Miscible Liquids

Liquids that can mix together in any proportion.

Boiling Point

The temperature at which a liquid turns into a gas.

Fractional Distillation Apparatus

Equipment used to separate liquids by fractional distillation, including a heating source, a flask, a fractionating column, and a condenser.

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Separation of Ethanol and Water

Fractional distillation used to separate ethanol and water because they have different boiling points (ethanol 78°C, water 100°C).

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Element

A substance made of atoms that all contain the same number of protons, and cannot be split into anything simpler.

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Compound

A pure substance made up of two or more elements chemically combined.

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Mixture

A combination of two or more substances (elements and/or compounds) that are not chemically combined.

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Pure Substance

A substance with a fixed composition. Examples: elements and compounds.

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Classification of Substances

All substances can be categorized as either elements, compounds, or mixtures.

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Separating Mixtures

Techniques like filtration and evaporation can be used to separate components of a mixture.

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Periodic Table

A table listing all known elements.

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Protons

Subatomic particles found in the atom's nucleus.

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Filtration

A method used to separate an undissolved solid from a mixture of the solid and a liquid, like separating sand from water.

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Filtrate

The liquid that passes through the filter paper during filtration.

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Residue

The solid that remains on the filter paper after filtration.

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Crystallisation

A method used to separate a dissolved solid from a solution by taking advantage of its solubility difference in hot and cold solvents, like separating copper sulphate from water.

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Saturated Solution

A solution containing the maximum amount of solute that can dissolve at a given temperature.

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Solubility

The amount of solute that can dissolve in a given amount of solvent at a specific temperature.

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Impurities

Substances that are present in a mixture but not desired after the separation process.

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Why wash crystals with cold distilled water?

Washing crystals with cold distilled water helps to remove any impurities that might be clinging to them after filtration. Cold water minimizes further dissolving of the crystals.

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Paper Chromatography

A technique used to separate substances based on their different solubilities in a solvent.

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Pencil Line in Chromatography

A line drawn on chromatography paper with a pencil to mark the starting point for the samples. Pencil is used because ink would also run with the samples.

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Capillary Action

The movement of a liquid up a narrow tube or porous material, like chromatography paper, due to cohesive forces between the liquid molecules and adhesive forces with the surface.

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Solubility in Chromatography

The degree to which a substance dissolves in a solvent. Substances with higher solubility travel further in paper chromatography.

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Separation of Substances

In paper chromatography, different substances travel at different rates due to varying solubilities, leading to their separation.

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Analyzing Ink Composition

Paper chromatography can reveal the different components of a mixture, such as the colors in a black ink.

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Separating Soluble Solids

Crystallisation is the technique used to separate a soluble solid from a solution.

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Rf Value

A ratio that represents the distance traveled by a substance in chromatography relative to the distance traveled by the solvent. It's used to identify the components of a mixture.

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How does Rf relate to solvent?

The Rf value of a substance is always the same for a specific solvent. However, changing the solvent also changes the Rf value.

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Calculating Rf

The Rf value is calculated by dividing the distance traveled by the substance by the distance traveled by the solvent. This gives a ratio with no units, always less than 1.

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What does Rf help identify?

Rf values help to identify unknown substances by comparing them to known substances run under identical chromatography conditions.

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How to measure distances for Rf

Measure the distance from the baseline to the center of the spot for both the substance and the solvent front.

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Why is Rf always less than 1?

Because the substance will always travel a shorter distance than the solvent front, leading to a fraction less than 1.

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Examiner Tip

Be careful when measuring distances for Rf calculations in exams. Use a ruler carefully and measure from the baseline to the center of the spot. Marks can be deducted for inaccurate measurements.

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Chromatography

A technique that separates substances based on their different affinities for a stationary phase and a mobile phase.

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Chromatography Paper

The stationary phase in paper chromatography, a special type of paper that absorbs the solvent and allows the components of the mixture to travel at different rates.

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Mobile Phase

The solvent used in paper chromatography, which travels up the chromatography paper, carrying the components of the mixture with it.

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Solvent Front

The leading edge of the mobile phase (solvent) on the chromatography paper.

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What are the spots on the chromatography paper?

The spots represent the separated components of the mixture. Each spot corresponds to a different substance that has travelled a unique distance based on its affinity for the paper and the solvent.

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What is the purpose of drawing a pencil line below the spots?

The line serves as a reference point to measure the distance travelled by the solvent and the separated components.

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How to Calculate Rf Value

The Rf value is calculated by dividing the distance travelled by the component (from the base line to the center of the spot) by the distance travelled by the solvent (from the base line to the solvent front).

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What is the significance of the Rf value?

The Rf value is a characteristic property of a particular substance in a given solvent and on a specific type of chromatography paper, helping to identify the components of the mixture.

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Study Notes

Elements, Compounds & Mixtures

  • Substances can be classified as elements, compounds, or mixtures.
  • An element is a substance made of atoms with the same number of protons. These atoms cannot be broken down into simpler substances. There are 118 elements found on the Periodic Table. Examples include copper, iron, and magnesium.
  • A compound is a pure substance formed when two or more elements chemically combine. There are numerous compounds, and they cannot be separated into their constituent elements through physical methods. Examples include copper(II) sulfate (CuSOâ‚„), calcium carbonate (CaCO₃), and carbon dioxide (COâ‚‚).
  • A mixture is a combination of two or more substances (elements and/or compounds) that are not chemically combined. Mixtures can be separated by physical methods. Examples include sand and water, oil and water, and sulfur powder and iron filings.

Pure Substance vs Mixture

  • A pure substance contains only one type of element or compound.
  • Pure substances have specific and sharp melting and boiling points.
  • Impure substances have a range of melting and boiling points, as they consist of more than one substance. Impure substances typically have lower melting points and higher boiling points than the pure substance.

Separation Techniques: Simple Distillation

  • Used to separate a liquid from a solution containing a soluble solid or to separate two liquids with different boiling points.
  • The solution is heated, causing the liquid to evaporate and become a vapor.
  • The vapor then passes through a condenser, where it cools and condenses back into a liquid.
  • The pure liquid is collected in a beaker, leaving the dissolved solid behind.
  • An example is separating water from a salt-water solution.

Separation Techniques: Fractional Distillation

  • Used to separate two or more miscible liquids with different boiling points.
  • The liquid with the lower boiling point evaporates first and is collected.
  • The column acts as a fractionating column, increasing surface area and allowing for slow condensation to occur.

Separation Techniques: Filtration

  • Used to separate an undissolved solid from a liquid.
  • A filter paper is placed in a filter funnel above a beaker.
  • The mixture is poured into the filter funnel.
  • The liquid passes through the filter paper (filtrates), while the solid is retained on the filter paper (residue).

Separation Techniques: Crystallisation

  • Used to separate a dissolved solid from a solution.
  • The solution is heated to evaporate the solvent.
  • The solution is cooled slowly, causing the dissolved solid to come out of solution as crystals.
  • The crystals are collected, washed, and dried.

Paper Chromatography

  • Separates substances based on their different solubilities in a given solvent.
  • A pencil line is drawn on chromatography paper, and spots of the sample (like different colored inks) are placed on the line.
  • The paper is lowered into a solvent container, and the solvent travels up the paper by capillary action.
  • Substances with higher solubility travel further.
  • This separation allows the identification of the different components of a mixture.

Interpreting Chromatograms

  • Chromatograms show the separation of substances in a mixture.
  • Pure substances produce a single spot on the chromatogram.
  • Mixtures produce multiple spots.
  • Substances can be identified based on their Rf values. Rf values are ratios obtained by dividing the distance traveled by the substance by the distance traveled by the solvent. They are useful because they are constant for a given substance in a given solvent system.

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