Elements, Atoms, Molecules, Compounds, and Ions

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Questions and Answers

What distinguishes an element from other substances?

  • It always has equal numbers of protons and neutrons.
  • It consists of atoms with the same number of protons. (correct)
  • It is composed of molecules bonded ionically.
  • It contains only protons.

What is the fundamental particle of an element that retains the properties of that element?

  • Atom (correct)
  • Ion
  • Molecule
  • Compound

Which of the following best describes a molecule?

  • An atom that has gained or lost electrons.
  • Two or more atoms chemically bonded together. (correct)
  • A substance with atoms of different elements.
  • A single atom of an element.

What distinguishes a compound from a molecule?

<p>A compound consists of atoms of different elements, while a molecule can consist of the same or different elements. (B)</p> Signup and view all the answers

How does an ion differ from an atom?

<p>An ion has a charge due to gaining or losing electrons. (A)</p> Signup and view all the answers

Which type of substance is composed of a single atom?

<p>Monatomic (D)</p> Signup and view all the answers

Which of the following represents a diatomic molecule?

<p>O₂ (C)</p> Signup and view all the answers

What is a key requirement for writing chemical equations at A-level?

<p>Using correct state symbols and balancing the equation. (D)</p> Signup and view all the answers

What is the purpose of including state symbols in chemical equations?

<p>To identify the physical state of each substance involved. (B)</p> Signup and view all the answers

In ionic equations, what are spectator ions?

<p>Ions that do not change oxidation state during the reaction. (C)</p> Signup and view all the answers

Which of the following acids is NOT typically used in laboratory experiments at A-level?

<p>Acetic acid (C)</p> Signup and view all the answers

What gas is produced when an acid reacts with a metal, and how is it tested?

<p>Hydrogen, tested by a 'squeaky pop' sound. (A)</p> Signup and view all the answers

What products are formed when an acid reacts with a metal oxide or hydroxide?

<p>Salt and water (B)</p> Signup and view all the answers

What happens when an acid reacts with a metal carbonate?

<p>Salt, Water, and Carbon Dioxide (D)</p> Signup and view all the answers

What evidence suggests carbon dioxide is evolved from a reaction?

<p>It turns lime water cloudy. (C)</p> Signup and view all the answers

What type of reaction involves one element replacing another in a compound?

<p>Displacement (A)</p> Signup and view all the answers

What is required to initiate displacement reactions in solid state, like the thermite reaction?

<p>Significant energy input (C)</p> Signup and view all the answers

In the thermite reaction, what element displaces iron in iron oxide?

<p>Aluminum (A)</p> Signup and view all the answers

Which of the following statements accurately describes the reactivity of halogens in displacement reactions?

<p>Chlorine is more reactive than bromine. (B)</p> Signup and view all the answers

What is the key characteristic of a precipitation reaction?

<p>Formation of a solid (C)</p> Signup and view all the answers

Which precipitate is formed when testing for sulfate ions?

<p>Barium sulfate (C)</p> Signup and view all the answers

What type of precipitate is formed when testing for halide ions?

<p>Silver halides (B)</p> Signup and view all the answers

What type of reaction occurs when dilute sulfuric acid is added to barium chloride?

<p>Precipitation (B)</p> Signup and view all the answers

What is the ionic equation for the reaction between hydrochloric acid and sodium hydroxide?

<p>H⁺(aq) + OH⁻(aq) → H₂O(l) (A)</p> Signup and view all the answers

What color precipitate is typically formed from a lead iodide salt?

<p>Yellow (C)</p> Signup and view all the answers

Which is the correct balanced equation for the reaction between zinc (Zn) and hydrochloric acid (HCl)?

<p>$Zn + 2HCl \rightarrow ZnCl_2 + H_2$ (C)</p> Signup and view all the answers

What is the oxidation state of sulfur in sulfuric acid (H₂SO₄)?

<p>+6 (D)</p> Signup and view all the answers

Which of the following reactions does not produce a salt?

<p>Acid + Non-Metal (B)</p> Signup and view all the answers

A student mixes two clear solutions, and a yellow solid immediately forms. Which of the following is the most likely type of reaction that has occurred?

<p>Precipitation (C)</p> Signup and view all the answers

A metal X is placed in an aqueous solution of metal nitrate YNO₃. Metal X replaces metal Y, forming XNO₃(aq) and solid Y. What can be concluded from this experiment?

<p>Metal X is more reactive than metal Y. (C)</p> Signup and view all the answers

When chlorine gas is bubbled through a solution of potassium iodide (KI), the solution turns brown. What is the brown substance formed in this reaction?

<p>Iodine (I₂) (A)</p> Signup and view all the answers

What volume of carbon dioxide, measured at room temperature and pressure (RTP), is produced when 0.05 moles of hydrochloric acid react completely with an excess of calcium carbonate? (Assume the molar volume of a gas at RTP is 24 dm³mol⁻¹)

<p>0.6 dm³ (A)</p> Signup and view all the answers

Consider the precipitation reaction between silver nitrate ($AgNO_3$) and sodium chloride ($NaCl$). If $50.0 mL$ of $0.10 M$ $AgNO_3$ is mixed with $50.0 mL$ of $0.10 M$ $NaCl$, what mass of silver chloride ($AgCl$) will precipitate out of the solution? (Molar mass of $AgCl = 143.32 g/mol$)

<p>0.717 g (A)</p> Signup and view all the answers

A student performs a displacement reaction by adding 2.0 g of zinc powder to 100.0 mL of a 0.50 M copper(II) sulfate solution. Assuming the reaction goes to completion, what mass of copper will be produced? (Molar mass of Zn = 65.38 g/mol, Cu = 63.55 g/mol)

<p>1.95 g (C)</p> Signup and view all the answers

When excess dilute hydrochloric acid is reacted with 4.0 g of a metal carbonate, $MCO_3$, 960 cm³ of carbon dioxide is produced at room temperature and pressure (RTP). Assuming the molar volume of a gas is 24.0 dm³mol⁻¹ at RTP, identify the metal, M. (RAM : Mg = 24.3, Ca = 40.1, Sr = 87.6, Ba = 137.3)

<p>Calcium (Ca) (A)</p> Signup and view all the answers

A student is tasked with identifying an unknown metal halide salt. They dissolve the salt in water and add silver nitrate solution, resulting in a pale yellow precipitate. The precipitate is then exposed to concentrated ammonia solution, where it partially dissolves. Which halide anion is most likely present in the unknown salt?

<p>Bromide (B)</p> Signup and view all the answers

A solution contains a mixture of chloride ($Cl^−$), bromide ($Br^−$), and iodide ($I^−$) ions. You want to selectively precipitate the silver halide salts one at a time using silver nitrate ($AgNO_3$). Given the solubility products ($K_{sp}$) of $AgCl = 1.8 × 10^{−10}$, $AgBr = 5.0 × 10^{−13}$, and $AgI = 8.3 × 10^{−17}$, which silver halide will precipitate first as $AgNO_3$ is added?

<p>AgI (D)</p> Signup and view all the answers

Aqueous lead(II) nitrate reacts with aqueous sodium chloride to form a precipitate. Considering a solution containing 0.1 M $Pb^{2+}$ and 0.2 M $Cl^-$, calculate the concentration of $Pb^{2+}$ ions remaining in solution at equilibrium. (The $K_{sp}$ for $PbCl_2$ is $1.6 × 10^{−5}$)

<p>$4.0 × 10^{−4} M$ (C)</p> Signup and view all the answers

Flashcards

Element

A substance with atoms containing the same number of protons.

Atom

Smallest particle of an element, composed of protons, neutrons, and electrons.

Molecule

Two or more bonded atoms, typically joined by covalent bonds.

Compound

A substance with atoms of different elements chemically combined.

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Ion

A substance that has gained or lost an electron, resulting in an electrical charge.

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Monatomic

A substance made up of one atom.

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Diatomic

A substance made up of two atoms.

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Polyatomic

A substance made up of multiple atoms.

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Displacement Reaction

A reaction where one element replaces another in a compound, involving redox.

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Precipitation Reaction

A reaction forming an insoluble solid.

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Hydrochloric Acid

HCl

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Sulfuric Acid

H₂SO₄

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Nitric Acid

HNO₃

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Phosphoric Acid

H₃PO₄

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Hydrogen Gas

A metal reacting with an acid produces a salt and this gas.

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Water

A metal oxide or hydroxide reacting with an acid produces a salt and this.

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Salt and Water

Result of an acid and alkali reacting.

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Carbon Dioxide

A metal carbonate reacting with an acid produces a salt, water, and this gas.

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Test for CO₂

Turns lime water cloudy.

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Metal Displacement

A more reactive metal will replace a less reactive metal in aqueous solutions.

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Thermite Reaction

Aluminum displaces iron in iron oxide at very high temperatures.

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Halogen Displacement

More reactive halogen replaces a less reactive one.

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Test for Sulfate Ions

Forms a white precipitate of barium sulfate.

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Test for Halide Ions

White, cream, or yellow precipitates.

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Solid Precipitate

Dilute sulfuric acid + barium chloride

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Neutralization Ionic Equation

H⁺(aq) + OH⁻(aq) → H₂O(l)

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Study Notes

Key Definitions

  • An element is a substance with atoms containing the same number of protons (same atomic number), though isotopes may differ.
  • An atom is the smallest particle of an element that retains the element's properties, composed of protons, neutrons, and electrons.
  • A molecule is two or more bonded atoms, typically joined by covalent bonds. These can be the same element (diatomic) or different elements (compounds).
  • A compound is a substance with atoms of different elements combined together
  • An ion is a substance that has gained or lost an electron, resulting in an electrical charge (positive = cation, negative = anion).
  • A monatomic substance is made up one atom
  • A diatomic substance is made up of two atoms
  • A polyatomic substance is made up of multiple atoms

Chemical Reactions

  • At A-level, one must write chemical and ionic formulas, balance equations, correctly use state symbols (solid, liquid, gas, aqueous), and use appropriate arrows (reversible or irreversible).
  • Half and full ionic equations are also required, with and without spectator ions.

Reactions of Acids

  • Four lab acids to know: hydrochloric acid (HCl), sulfuric acid (H₂SO₄), nitric acid (HNO₃), and phosphoric acid (H₃PO₄).
  • Acids react with bases (metals, metal oxides, metal hydroxides, alkalis, metal carbonates, and hydrogen carbonates) in specific ways.
  • Acid + Metal → Salt + Hydrogen gas (test for hydrogen: squeaky pop)
  • Acid + Metal Oxide/Hydroxide → Salt + Water (copper + sulfuric = copper sulfate, Zinc hydroxide + sulfuric acid = zinc sulphate)
  • Acid + Alkali → Salt + Water (alkali is a soluble metal hydroxide)
  • Acid + Metal Carbonate → Salt + Water + Carbon Dioxide (test for CO₂: turns lime water cloudy)
  • Acid + Hydrogen Carbonate → Salt + Water + Carbon Dioxide

Displacement Reactions

  • A displacement reaction is when one element replaces another in a compound, involving redox (oxidation and reduction). Can occur with metals or halogens.
  • More reactive metal replaces a less reactive metal in aqueous solutions
  • Solid-state reactions between two solid reactants (e.g., aluminum and iron oxide) require significant energy input (example: thermite reaction).
  • Thermite reaction: aluminum displaces iron in iron oxide at very high temperatures, used to weld railway lines.
  • Copper wire in silver nitrate solution: copper displaces silver
  • Halogens: more reactive halogen displaces a less reactive one (reactivity: fluorine > chlorine > bromine > iodine).
  • Example: chlorine gas displaces bromine from potassium bromide, forming potassium chloride and bromine.

Precipitation Reactions

  • A precipitation reaction forms a solid (precipitate).
  • Chemical tests using precipitation:
    • Test for CO₂: reacts with lime water giving a white precipitate of calcium carbonate.
    • Test for sulfate ions: white precipitate of barium sulfate.
    • Test for halide ions: precipitates of silver halides (white, cream, or yellow).
  • Precipitation reactions examples:
    • Formation of calcium carbonate precipitate
    • Formation of a lead iodide precipitates forming a salt

Examples of Past Paper Questions

  • Dilute sulfuric acid + barium chloride → solid (precipitation reaction)
  • Ionic equation for hydrochloric acid + sodium hydroxide: H⁺(aq) + OH⁻(aq) → H₂O(l)
  • Determining ionic equation from masses of reactants and products, considering mole ratios and ion valencies.

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