Electron Structure Flashcards

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Questions and Answers

Why is bromine classified as a p-block element?

The outermost electrons are in the p-subshells.

What is the electron configuration of Cr and the Cr3+ ion?

Cr: 1s2, 2s2, 2p6, 3s2, 3p6, 4s1, 3d5; Cr3+: 1s2, 2s2, 2p6, 3s2, 3p6, 3d3.

What is an orbital? Describe it.

An orbital is a region that can hold up to two electrons, with opposite spins.

Describe the shapes of s and p orbitals.

<p>s orbitals are spherical and can hold two electrons; p orbitals are in the shape of a dumb-bell and can hold two electrons in each orbital.</p> Signup and view all the answers

State the number of orbitals making up s-, p-, and d-subshells.

<p>s subshell: 1 orbital; p subshell: 3 orbitals; d subshell: 5 orbitals.</p> Signup and view all the answers

State the number of electrons that occupy s-, p-, and d-subshells.

<p>s subshell: 2 electrons; p subshell: 6 electrons; d subshell: 10 electrons; f subshell: 14 electrons.</p> Signup and view all the answers

State Aufbau's Principle.

<p>Fill the orbitals in order of energy levels.</p> Signup and view all the answers

State Hund's Rule.

<p>For orbitals with the same energy, occupation singly before pairing.</p> Signup and view all the answers

Describe the relative energies of s-, p-, and d-orbitals for shells 1, 2, 3 and the 4s and 4p orbitals.

<p>1s &lt; 2s &lt; 2p &lt; 3s &lt; 3p &lt; 4s &lt; 3d &lt; 4p.</p> Signup and view all the answers

Classify the elements into s, p, and d blocks.

<p>s-block: first two groups, plus hydrogen and helium; p-block: group 3 to group 0 minus helium; d-block: transition metals.</p> Signup and view all the answers

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Study Notes

Electron Structure and Orbital Concepts

  • Bromine is a p-block element because its outermost electrons are located in p-subshells.
  • The electron configuration of Chromium (Cr) is 1s² 2s² 2p⁶ 3s² 3p⁶ 4s¹ 3d⁵, while that of its Cr³⁺ ion is 1s² 2s² 2p⁶ 3s² 3p⁶ 3d³.

Orbitals and Their Shapes

  • An orbital can accommodate a maximum of two electrons that have opposite spins.
  • s orbitals have a spherical shape, holding a total of two electrons; p orbitals have a dumbbell shape, with each orbital capable of holding two electrons.

Subshells and Electron Capacity

  • The s subshell contains one orbital (2 electrons), the p subshell has three orbitals (6 electrons), and the d subshell consists of five orbitals (10 electrons).
  • An f subshell has seven orbitals and can hold up to 14 electrons.

Principles of Electron Configuration

  • Aufbau's Principle states that electrons occupy orbitals in order of increasing energy levels.
  • According to Hund's Rule, electrons will fill orbitals of the same energy singly before pairing in order to minimize repulsion.

Relative Energy of Orbitals

  • The 1s subshell has the lowest energy level, followed by the 2s and 2p subshells.
  • Within the third shell, the 3s subshell is filled first, followed by 3p.
  • The 4s subshell is filled before the 3d subshell, subsequent filling order is 4p, then 4d, and finally 4f.

Classification of Elements

  • The s-block elements include the first two groups of the periodic table, along with hydrogen and helium.
  • The p block comprises groups 3 to 0, excluding helium.
  • The d block consists of transition metals.

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