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Questions and Answers
What is the valence-shell configuration for gallium (Z = 31)?
What is the valence-shell configuration for gallium (Z = 31)?
- [Ar]3d104s24p6
- [Ar]4s24p1 (correct)
- [Kr]5s24d105p3
- [Ne]3s23p1
What are the configurations for the outer electrons of tellurium (Z = 52)?
What are the configurations for the outer electrons of tellurium (Z = 52)?
- [Kr]5s24d105p4 (correct)
- [Ne]3s23p6
- [Xe]4f145d106s26p2
- [Ar]4s23d8
According to the Hund's Rule, what is the lowest energy arrangement of electrons in a subshell?
According to the Hund's Rule, what is the lowest energy arrangement of electrons in a subshell?
- Putting electrons into separate orbitals of the subshell with the same spin before pairing electrons (correct)
- Pairing electrons with opposite spins before putting them into separate orbitals
- Pairing electrons with the same spin before putting them into separate orbitals
- Putting electrons into separate orbitals of the subshell with opposite spins before pairing electrons
Based on the information provided, arrange the following elements in order of increasing atomic radius: Al, C, Si.
Based on the information provided, arrange the following elements in order of increasing atomic radius: Al, C, Si.
What is the first ionization energy for Li in eV?
What is the first ionization energy for Li in eV?
"High values of first ionization energy are associated with which group of elements?"
"High values of first ionization energy are associated with which group of elements?"
"Ionization energies tend to decrease going down any column." According to this statement, what can be expected for ionization energies going down a group?
"Ionization energies tend to decrease going down any column." According to this statement, what can be expected for ionization energies going down a group?
"The atomic radius tends to decrease with increasing atomic number within each period." According to this statement, what can be expected for atomic radius within a period?
"The atomic radius tends to decrease with increasing atomic number within each period." According to this statement, what can be expected for atomic radius within a period?
"From its position in the periodic table, would you classify X as a main-group element, a transition element, or an inner transition element?" Based on the given electron configuration [Xe]4f14 5d106s26p2, how would you classify X?
"From its position in the periodic table, would you classify X as a main-group element, a transition element, or an inner transition element?" Based on the given electron configuration [Xe]4f14 5d106s26p2, how would you classify X?
According to the Pauli exclusion principle, which of the following statements is true?
According to the Pauli exclusion principle, which of the following statements is true?
What does the electron configuration 1s22s22p1 represent?
What does the electron configuration 1s22s22p1 represent?
In an orbital diagram, what does an upward-pointing arrow indicate?
In an orbital diagram, what does an upward-pointing arrow indicate?
What is the significance of the Stern–Gerlach experiment in relation to electron spin?
What is the significance of the Stern–Gerlach experiment in relation to electron spin?
Which subshell consists of a group of orbitals having the same n and l quantum numbers but different ml values?
Which subshell consists of a group of orbitals having the same n and l quantum numbers but different ml values?
What is the sequence for filling subshells according to the building-up principle (Aufbau Principle)?
What is the sequence for filling subshells according to the building-up principle (Aufbau Principle)?
Study Notes
Valence-Shell Configurations
- Gallium (Z = 31) has the valence-shell configuration of 4s² 4p¹.
- Tellurium (Z = 52) has outer electron configurations of 5s² 5p⁴.
Hund's Rule
- According to Hund's Rule, the lowest energy arrangement of electrons in a subshell is characterized by maximizing the number of unpaired electrons in degenerate orbitals.
Atomic Radius Trends
- The order of increasing atomic radius is C < Si < Al.
- Carbon is the smallest, followed by silicon, then aluminum which is the largest among them.
First Ionization Energy for Lithium
- The first ionization energy for lithium (Li) is approximately 5.39 eV.
High First Ionization Energy Elements
- High values of first ionization energy are typically associated with noble gases and nonmetals.
Ionization Energies and Group Trends
- Ionization energies generally decrease as one moves down a group in the periodic table due to increasing atomic size and shielding effect.
Atomic Radius and Period Trends
- The atomic radius tends to decrease with increasing atomic number within each period as effective nuclear charge increases, pulling electrons closer to the nucleus.
Classification of Element X
- Based on the electron configuration [Xe]4f¹⁴ 5d¹⁰ 6s² 6p², element X is classified as a main-group element.
Pauli Exclusion Principle
- The Pauli exclusion principle states that no two electrons in an atom can have identical sets of quantum numbers.
Electron Configuration Representation
- The electron configuration 1s² 2s² 2p¹ represents the element Boron (B).
Orbital Diagrams
- An upward-pointing arrow in an orbital diagram indicates an unpaired electron.
Stern-Gerlach Experiment Significance
- The Stern–Gerlach experiment demonstrated the existence of electron spin and the quantization of angular momentum in quantum mechanics.
Subshell Characteristics
- A subshell consists of a group of orbitals sharing the same n and l quantum numbers but differing in their ml values.
Aufbau Principle (Building-Up Principle)
- The sequence for filling subshells follows the order of increasing energy levels: generally fills according to [n + l] rule, with lower n + l values filled first.
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Description
Test your knowledge about electron spin, the Pauli exclusion principle, and electron configurations with this quiz. The quiz covers concepts such as the Stern–Gerlach experiment and orbital diagrams.