Electrochemistry Fundamentals Quiz
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Questions and Answers

What happens to the oxidation number of iron during the reaction?

  • It remains the same at (2+).
  • It fluctuates between (2+) and (3+).
  • It increases from (2+) to (3+). (correct)
  • It decreases from (3+) to (2+).
  • How many electrons are added to balance the charges in the reduction half-reaction?

  • Four electrons.
  • Six electrons. (correct)
  • One electron.
  • Two electrons.
  • What is the first step when balancing the half-reactions?

  • Adding electrons to balance the charges.
  • Balancing charges last.
  • Balancing oxygen atoms with water. (correct)
  • Balancing hydrogen atoms.
  • What must occur after balancing the half-reactions before combining them?

    <p>Ensure the number of electrons is equal in both reactions.</p> Signup and view all the answers

    In what medium does the described reaction occur initially?

    <p>Acidic medium.</p> Signup and view all the answers

    What is the primary process involved in redox reactions?

    <p>Electron transfer between species</p> Signup and view all the answers

    What occurs to the oxidation state of an atom during oxidation?

    <p>It increases</p> Signup and view all the answers

    In the reaction of zinc and copper, what role does zinc play?

    <p>It is oxidized</p> Signup and view all the answers

    What are the two general types of electrochemical cells?

    <p>Electrolytic cells and voltaic cells</p> Signup and view all the answers

    To balance a redox reaction in a half-reaction method, which step should be taken first?

    <p>Split the equation into two half-reactions</p> Signup and view all the answers

    What is the purpose of balancing charges in a redox reaction?

    <p>To make sure both sides have equal total charge</p> Signup and view all the answers

    In an electrochemical process, what happens to the energy during a spontaneous redox reaction?

    <p>It is converted to electricity</p> Signup and view all the answers

    Which of the following accurately describes the reduction reaction in a redox process?

    <p>It causes an atom to gain electrons</p> Signup and view all the answers

    Study Notes

    Electrochemistry Fundamentals

    • Electrochemistry studies the interconversion of chemical and electrical energy.
    • Redox reactions involve electron transfer. Oxidation is loss of electrons, reduction is gain of electrons.
    • Oxidation states change during redox reactions. Oxidation increases the oxidation state (more positive), reduction decreases it (more negative).
    • Balancing redox reactions involves identifying oxidation and reduction half-reactions and balancing atoms and charges.
    • Balancing half-reactions: First balance atoms other than H and O. Balance O atoms by adding H2O. Balance H atoms by adding H+. Balance charges by adding electrons.

    Voltaic Cells

    • Voltaic cells are electrochemical cells that produce electricity from a spontaneous chemical reaction.
    • Anode: electrode where oxidation occurs (electrons released)
    • Cathode: electrode where reduction occurs (electrons received)
    • Salt bridge: completes the circuit, maintains charge neutrality by allowing ion movement between half-cells.
    • Cell notation: Anode | anode solution || cathode solution | cathode
      • Example: Zn(s) | Zn2+(aq) || Cu2+ (aq) | Cu(s)

    Cell Notation Details

    • The anode is always written on the left, followed by the anode species, then a double vertical bar ( || ), followed by the cathode species, then the cathode.
    • Phases must be specified in the cell notation (i.e., solid, aqueous, gas).
    • Concentrations or pressures (for gases) of species are given in parentheses (e.g. 1.0M, 1.0 atm).
    • Inert electrodes (like Pt or graphite) are included in the notation.

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    Description

    Test your knowledge on the basics of electrochemistry, focusing on redox reactions and the functioning of voltaic cells. This quiz will evaluate your understanding of oxidation, reduction, and the components involved in electrochemical processes.

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