Dijkstra's Algorithm: Shortest Path

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Questions and Answers

Why is benzene less reactive than typical alkenes, despite being unsaturated?

  • Benzene has longer carbon chains compared to alkenes.
  • Benzene undergoes addition reactions more readily than alkenes.
  • Benzene reacts faster with $Br_2$ than alkenes.
  • Benzene fails to undergo the usual alkene addition reactions. (correct)

Benzene readily undergoes alkene addition reactions similar to cyclohexene.

False (B)

What type of reaction does benzene undergo with $Br_2$ in the presence of an Fe catalyst?

substitution

The reaction of benzene with $Br_2$ produces bromobenzene, which is a ______ product.

<p>substitution</p> Signup and view all the answers

Match the following compounds with their typical reaction outcomes with $Br_2$:

<p>Cyclohexene = Addition reaction Benzene = Substitution reaction (slow)</p> Signup and view all the answers

What is the role of Fe in the reaction between benzene and $Br_2$?

<p>Catalyst (C)</p> Signup and view all the answers

The reaction between benzene and $Br_2$ proceeds quickly without a catalyst.

<p>False (B)</p> Signup and view all the answers

What is the chemical formula for bromobenzene, the product of benzene's reaction with $Br_2$?

<p>$C_6H_5Br$</p> Signup and view all the answers

In contrast to cyclohexene, benzene yields a ______ product when reacting with $Br_2$.

<p>substitution</p> Signup and view all the answers

Match the following reaction types to the compounds that typically undergo them:

<p>Addition = Alkenes Substitution = Benzene</p> Signup and view all the answers

Which compound reacts rapidly with $Br_2$ and gives the addition product 1,2-dibromo-cyclohexane?

<p>Cyclohexene (D)</p> Signup and view all the answers

Benzene reacts readily with $Br_2$ to form an addition product.

<p>False (B)</p> Signup and view all the answers

What other product is formed, besides bromobenzene, in the reaction of benzene with $Br_2$?

<p>HBr</p> Signup and view all the answers

The reaction of benzene with $Br_2$ in the presence of Fe catalyst produces ______ and HBr.

<p>bromobenzene</p> Signup and view all the answers

Match the organic compounds with their respective reaction characteristics when reacting with $Br_2$:

<p>Benzene with catalyst = Slow substitution reaction. Cyclohexene = Fast addition reaction</p> Signup and view all the answers

Which of the following is NOT a characteristic of benzene's reaction with $Br_2$?

<p>Occurs rapidly. (A)</p> Signup and view all the answers

The 'addition product' is typically a result of reacting benzene with $Br_2$.

<p>False (B)</p> Signup and view all the answers

What catalyst facilitates the reaction between benzene and $Br_2$ to form bromobenzene?

<p>Fe</p> Signup and view all the answers

Due to its stability, benzene requires a ______ to react with $Br_2$

<p>catalyst</p> Signup and view all the answers

Match the provided organic molecules with the correct description of the reaction with $Br_2$:

<p>Benzene = Slow reaction, substitution product formed. Cyclohexene = A rapid reaction, addition of $Br_2$ across a double bond</p> Signup and view all the answers

Flashcards

Benzene Reactivity

Benzene is less reactive than typical alkenes and does not easily undergo addition reactions.

Substitution Reaction

A reaction in which atoms or groups of atoms replace other atoms or groups of atoms.

Benzene + Br2 Reaction

Benzene reacts slowly with Br2 to yield bromobenzene (C6H5Br) as the substitution product.

Role of Fe Catalyst

An iron catalyst is needed for the bromination of benzene. Fe activates Br2 for the reaction to proceed.

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Cyclohexene + Br2 Reaction

Cyclohexene reacts rapidly with Br2 to form 1,2-dibromocyclohexane through an addition reaction.

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Addition Reaction

A reaction where atoms, or groups of atoms, are added to a molecule.

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Study Notes

Dijkstra's Algorithm

  • Designed to find the shortest paths in a graph.
  • Applicable to both directed and undirected graphs.
  • Requires all edges to have non-negative weights.
  • Classified as a greedy algorithm.
    • Maintains a set S of vertices with determined shortest path weights from source s.
    • Selects vertex u from V - S with the minimum shortest path estimate iteratively.
    • Adds u to S.
    • Relaxes all edges leaving u.

Relaxation Process

  • Each vertex v has a shortest path estimate d[v] from source s.

  • Initially, d[v] is set to infinity for all vertices.

  • Relaxing edge (u,v) optimizes the shortest path to v by checking the path through u.

    Relax (u,v,w)
        if d[v] > d[u] + w(u,v)
           then d[v] := d[u] + w(u,v)
    

Algorithm Steps

DIJKSTRA(G,w,s)
    INITIALIZE-SINGLE-SOURCE(G,s)
    S := 0
    Q := V[G]
    while Q != 0
        do u := EXTRACT-MIN(Q)
           S := S U {u}
           for each vertex v ∈ Adj[u]
               do RELAX(u,v,w)

Complexity Analysis

  • Min-priority queue Q implementation influences the algorithm's complexity significantly.
  • When using an array, complexity is O(V^2 + E) = O(V^2) because EXTRACT-MIN takes O(V) time.
  • With a binary heap, the complexity becomes O((V+E)lgV) = O(ElgV) since EXTRACT-MIN takes O(lgV) time.
  • Implementing with a Fibonacci heap yields a complexity of O(VlgV + E) because EXTRACT-MIN has O(lgV) amortized time.

Example Walkthrough

Iteration S Q A B C D E
{} {A,B,C,D,E} 0 ∞ ∞ ∞ ∞
1 {A} {B,C,D,E} 0 10 3 ∞ ∞
2 {A,C} {B,D,E} 0 7 3 11 5
3 {A,C,E} {B,D} 0 7 3 11 5
4 {A,C,E,B} {D} 0 7 3 9 5
5 {A,C,E,B,D} {} 0 7 3 9 5

Correctness Theorem

  • Dijkstra's algorithm leads to an optimal solution, despite its greedy approach.
  • Theorem: The algorithm concludes with d[v] = σ(s,v) for all vertices v in V, where σ(s,v) represents the shortest path weight from s to v.

Comprehensive Proof

  • Initialization: At the start, d[s] = 0 and d[v] = ∞ for all v in V - {s}, satisfying all vertices trivially.
  • Maintenance:
    • Let u be the first vertex where d[u] ≠ σ(s,u), and u ≠ s because d[s] = 0 = σ(s,s).
    • There is a path from s to u; otherwise, d[u] = ∞ = σ(s,u).
    • A vertex x precedes u on the shortest path from s to u, with x in S and y in V - S.
    • Thus, σ(s,u) = σ(s,y) + σ(y,u).
    • Because u is the first vertex with d[u] ≠ σ(s,u), then d[y] = σ(s,y).
    • Since all edge weights are non-negative, σ(s,y) ≤ σ(s,u), hence d[y] ≤ σ(s,u).
    • Since u was selected before y, d[u] ≤ d[y], implying d[u] ≤ σ(s,u).
    • Because d[u] can never be less than σ(s,u), d[u] = σ(s,u), proving the algorithm's correctness.

Final Thoughts

  • Dijkstra's algorithm effectively finds shortest paths in graphs with non-negative edge weights.
  • Its complexity is heavily determined by the min-priority queue implementation:
    • O(V^2) with an array.
    • O(ElgV) with a binary heap.
    • O(VlgV + E) with a Fibonacci heap.

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