D and L Configuration of Sugars Quiz

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Questions and Answers

What determines whether a sugar is in the D or L form?

  • Optical rotation
  • Position of the carbonyl group
  • Position of the -OH group on the last chiral carbon (correct)
  • Number of carbon atoms

Which form of sugar has the -OH group on the right side?

  • R form
  • D form (correct)
  • M form
  • L form

Which sugar is also known as dextrose?

  • Glucose (correct)
  • Galactose
  • Maltose
  • Fructose

Match the following terms with their corresponding descriptions:

<p>D-sugar = Rotates plane polarized light to the right L-sugar = Has the -OH group on the left side Glyceraldehyde = Determines the D or L configuration of sugars Glucose = Rotates plane polarized light to the right and is also known as dextrose</p> Signup and view all the answers

Match the following configurations with their corresponding characteristics:

<p>D form = -OH group is on the right side L form = -OH group is on the left side Glyceraldehyde = Used to determine the D or L form of sugars Glucose = Rotates plane polarized light to the right and can be in D or L form</p> Signup and view all the answers

Match the following terms with their meanings:

<p>Dextrose = Another name for glucose Chiral carbon = The last carbon in a sugar molecule with four different groups attached to it Plane polarised light = Light that oscillates in a single plane Glyceraldehyde = Used as a reference to determine the D or L configuration of sugars</p> Signup and view all the answers

Flashcards

D or L form of a sugar

Determined by the position of the -OH group on the last chiral carbon in the sugar molecule.

D form of sugar

The form of a sugar in which the -OH group is on the right side of the last chiral carbon.

Glucose

Also known as dextrose, it is a simple sugar with the molecular formula C6H12O6 and is a key energy source for living organisms.

Study Notes

Stereoisomers of Sugars

  • The 'handedness' of a sugar molecule, whether it is a D-sugar or an L-sugar, is determined by the spatial arrangement of atoms around an asymmetric carbon atom.
  • A sugar is classified as D if the -OH group on the asymmetric carbon atom farthest from the aldehyde or ketone group is on the right side, and L if it is on the left side.

Identity of Sugars

  • D-Glucose, also known as dextrose, is a common sugar found naturally in many foods.
  • D-sugars are more common in nature than L-sugars.

Configuration and Characteristics

  • The Fischer projection is a way to represent the three-dimensional structure of a sugar molecule in two dimensions.
  • Sugars can exist as anomers, which are isomers that differ in the configuration of the hydroxyl group on the anomeric carbon atom.

Key Terms and Definitions

  • Anomer: a type of isomer that differs in the configuration of the hydroxyl group on the anomeric carbon atom.
  • Asymmetric carbon atom: a carbon atom that has four different groups attached to it, resulting in a non-superimposable mirror image.

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