Crystal Structure and Bravais Lattices
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Questions and Answers

What notation is used to indicate an individual direction within a crystal lattice?

  • [hkl] (correct)
  • <hkl>
  • {hkl}
  • (hkl)
  • Which of the following describes the direction going from one corner of the unit cell to the opposite corner?

    What defines the shape and properties of a crystal?

  • The size of the atoms
  • The arrangement of atoms, molecules, or ions (correct)
  • The type of bonding present
  • The temperature at which it was formed
  • How many distinct types of Bravais lattices are there?

    <p>14</p> Signup and view all the answers

    What is the role of a unit cell in a crystal structure?

    <p>It allows for the arrangement of identical cells in space</p> Signup and view all the answers

    The angles between the sides of a unit cell in different crystal systems are represented by which symbols?

    <p>α, β, γ</p> Signup and view all the answers

    What is the 'lattice parameter' in a crystal?

    <p>The distance between two points on the corners of a unit cell</p> Signup and view all the answers

    Which of the following best describes a lattice in a crystal?

    <p>A regular and infinite arrangement of points or atoms</p> Signup and view all the answers

    In a tetragonal lattice, how are the lattice parameters designated?

    <p>a and c only, with b omitted</p> Signup and view all the answers

    What characteristic is common to all points in a Bravais lattice?

    <p>Identical sets of surrounding points</p> Signup and view all the answers

    What is a characteristic of the tetragonal crystal system?

    <p>Three mutually perpendicular axes, two equal in length.</p> Signup and view all the answers

    Which crystal system is defined by three equal axes intersecting at equal angles?

    <p>Trigonal</p> Signup and view all the answers

    What is the main benefit of using fractional coordinates in crystal structure representation?

    <p>Better representation of the repeating nature of the crystal.</p> Signup and view all the answers

    Which crystal system has three axes that are all of different lengths and are mutually perpendicular?

    <p>Orthorhombic</p> Signup and view all the answers

    In which crystal system would you find two axes intersecting at an oblique angle and the third axis perpendicular?

    <p>Monoclinic</p> Signup and view all the answers

    Which of the following statements about the cubic crystal system is true?

    <p>All three axes are of equal length and intersect at right angles.</p> Signup and view all the answers

    The coordination system that uses numbers corresponding to distances along coordinate axes is called what?

    <p>Cartesian coordinates</p> Signup and view all the answers

    In the triclinic crystal system, how are the axes positioned in relation to one another?

    <p>All three axes are unequal and intersect at oblique angles.</p> Signup and view all the answers

    Which notation is used to indicate a family of directions in crystal structures?

    <hkl> Signup and view all the answers

    What does the vector notation [100] indicate in a crystal lattice?

    <p>A direction along the a-axis only</p> Signup and view all the answers

    In crystal lattices, which of the following is true about the directions [100], [010], and [001]?

    <p>They are equivalent and belong to the &lt;100&gt; family of directions.</p> Signup and view all the answers

    What is a critical aspect of understanding a crystal's three-dimensional structure beyond unit cell description?

    <p>The arrangement and distances to neighboring atoms</p> Signup and view all the answers

    Which common arrangement does close packing seek to achieve in crystal structures?

    <p>Maximum density of atoms</p> Signup and view all the answers

    Which of the following structures can be best described using the principle of close packing?

    <p>Hexagonal close packing and cubic close packing</p> Signup and view all the answers

    What does the term 'lattice parameter' typically refer to in crystallography?

    <p>The dimensions of the unit cell</p> Signup and view all the answers

    What does the vector notation [111] represent in terms of direction within a crystal lattice?

    <p>A direction that crosses all three axes of the unit cell</p> Signup and view all the answers

    Study Notes

    Crystal Structure

    • Crystals have a defined, repetitive arrangement of atoms, molecules, or ions.
    • This arrangement gives crystals their unique shape and properties.

    Bravais Lattice

    • The Bravais lattice is the basic unit used to describe crystals.
    • It is defined using a unit cell.
    • There are 14 distinct Bravais lattices that are further classified into seven crystal systems.
    • The unit cell is the smallest repeating unit of the crystal structure.
    • The lattice parameters (a, b, c) represent the lengths of the unit cell sides, and angles ( α, β, γ) between them define the shape.

    The Role of Unit Cell in Crystal Structure

    • The unit cell consists of a lattice and a basis.
    • The lattice describes the repeating pattern of atoms or points.
    • The basis defines what is being repeated within the unit cell.

    Crystal Directions

    • Directions within a crystal are represented using the notation [hkl].
    • h, k, and l represent the reciprocals of the points where the vector exits the unit cell.
    • The origin of all vectors is defined as [000].
    • For example, the direction along the a-axis is [100].
    • represents a family of directions that are equivalent in length and atom types.

    Description of Crystal Structures

    • Crystal structures are often described by the unit cell size, shape, and atom/ion positions.
    • Methods like close packing are used to understand extended structures.

    Close Packed Structures

    • Close packing maximizes the density of a crystal by arranging atoms in the most compact way.
    • Two common close-packed structures are:
      • Hexagonal Close Packing (HCP)
      • Cubic Close Packing (CCP)

    Crystal System

    • There are seven crystal systems based on the lattice structure and symmetry.
    • They are:
      • Cubic
      • Orthorhombic
      • Trigonal (Rhombohedral)
      • Monoclinic
      • Triclinic
      • Hexagonal
      • Tetragonal

    Atom Positions and Crystal Axes

    • Atom positions within the unit cell are described using two coordinate systems:
      • Cartesian coordinates (X, Y, Z) represent atom positions as distances from the origin.
      • Fractional coordinates (x, y, z) represent atom positions as fractions of the unit cell dimensions.

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    Related Documents

    Crystal Structure PDF

    Description

    Explore the fascinating world of crystal structures and the essential role of Bravais lattices. Understand the arrangement of atoms, the definition of unit cells, and the representation of crystal directions. This quiz covers the fundamental concepts in crystallography that are crucial for grasping material science.

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