Cooling Water Problems: Solutions and Treatments
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Questions and Answers

What is the main method of reducing deposition of solids in cooling water systems?

  • Adding polymeric organics
  • Maintaining high pH levels
  • Adding sulfuric acid
  • Using sequestering agents and chelates (correct)
  • Why is it important to keep the cycles of concentration low in cooling water systems?

  • To promote the deposition of solids
  • To reduce the need for specialty chemicals
  • To minimize deposits (correct)
  • To increase the efficiency of the system
  • What effect does maintaining a lower pH (6.5 to 7) have on solids in suspension?

  • It helps keep solids in suspension (correct)
  • It promotes the deposition of solids
  • It accelerates corrosion of steel and copper
  • It increases the need for specialty chemicals
  • What is added to cooling water systems to keep scale-forming salts in solution at high concentration levels?

    <p>Polymeric organics</p> Signup and view all the answers

    Why do plants that use source water with high hardness add sulfuric acid?

    <p>To keep the pH in the lower range</p> Signup and view all the answers

    What is the drawback of some of the compounds used to keep scale-forming salts in solution at high concentration levels?

    <p>They accelerate corrosion of steel and copper</p> Signup and view all the answers

    What is the purpose of adding chlorine to control biological growth in cooling towers?

    <p>To prevent the formation of calcium scale</p> Signup and view all the answers

    What is the purpose of using crystal modification chemicals in cooling water systems?

    <p>To prevent the formation of calcium scale</p> Signup and view all the answers

    How does make-up proportional blowdown control the cycles of concentration in a cooling tower?

    <p>It allows a proportional blowdown discharge based on the amount of make-up water added</p> Signup and view all the answers

    What is the purpose of applying protective coatings, such as paint or metal plating, in cooling water systems?

    <p>To reduce the rates of corrosion</p> Signup and view all the answers

    What is the purpose of using sacrificial anodes or induced electric currents in corrosion control?

    <p>To reduce the rates of corrosion</p> Signup and view all the answers

    What is the purpose of chemical inhibitors in cooling water systems?

    <p>To reduce the rates of corrosion</p> Signup and view all the answers

    What is the reason for no longer using chromate in systems from which water can escape?

    <p>It causes unacceptable environmental damage when released</p> Signup and view all the answers

    Which alternative to chromate is mentioned as nontoxic?

    <p>Zinc</p> Signup and view all the answers

    How long does it take for polysilicates and molybdates inhibitors to form a protective film?

    <p>Up to 2 weeks</p> Signup and view all the answers

    What is the purpose of installing a Y-strainer or equivalent upstream of the blowdown valve?

    <p>To prevent plugging and erosion</p> Signup and view all the answers

    How do oxidizing chemicals like chlorine operate in protecting against biological fouling?

    <p>They penetrate the cell wall and destroy protein groups</p> Signup and view all the answers

    Which statement about the use of biocides is accurate?

    <p>Biocides tend to increase the corrosive nature of the cooling water</p> Signup and view all the answers

    What is the purpose of shock feeding biocides into the cooling system?

    <p>To create a temporary high concentration of a biocide</p> Signup and view all the answers

    What is an effective method mentioned to control wood deterioration?

    <p>Treat water with biocides</p> Signup and view all the answers

    Study Notes

    Cooling Water Systems

    • The main method of reducing deposition of solids in cooling water systems is to keep the cycles of concentration low.

    Scale Formation and Prevention

    • Maintaining a lower pH (6.5 to 7) helps keep solids in suspension.
    • Polymers or phosphonates are added to cooling water systems to keep scale-forming salts in solution at high concentration levels.
    • Plants that use source water with high hardness add sulfuric acid to remove carbonate alkalinity and reduce pH.
    • The drawback of some compounds used to keep scale-forming salts in solution is that they can break down and lose efficacy over time.

    Biological Growth Control

    • Chlorine is added to control biological growth in cooling towers by oxidizing and breaking down microorganisms.
    • The purpose of using crystal modification chemicals is to prevent scale formation by modifying the crystal structure of minerals.

    Corrosion Control

    • Applying protective coatings, such as paint or metal plating, prevents corrosion by creating a barrier between the metal and corrosive substances.
    • Sacrificial anodes or induced electric currents are used in corrosion control to drive the corrosion reaction away from critical system components.
    • Chemical inhibitors are used to prevent corrosion by forming a protective film on metal surfaces.

    Inhibitor Characteristics

    • Chromate was previously used as an inhibitor but is no longer used due to toxicity concerns.
    • Phosphates and molybdates are alternative, nontoxic inhibitors that form a protective film in 30-90 days.
    • Polysilicates and molybdates inhibitors take 30-90 days to form a protective film.

    System Maintenance

    • Installing a Y-strainer or equivalent upstream of the blowdown valve prevents debris from entering the blowdown line.
    • Oxidizing chemicals like chlorine operate by oxidizing and breaking down microorganisms, preventing biological fouling.
    • Biocides can be shock fed into the cooling system to control biological growth.
    • An effective method to control wood deterioration is to treat cooling water systems with biocides.

    Biocide Use

    • Biocides should be used in a controlled manner to target specific microorganisms and prevent resistance development.

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    Description

    Learn about the common problems in cooling water systems and the treatments used to address them. Understand the importance of following site-specific water treatment procedures and guidelines.

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