Collision Theory and Energy Profiles

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Questions and Answers

What primarily determines if a collision between reactants will lead to product formation?

  • The collision angle and the energy (correct)
  • The volume of the container
  • The color of the reactants
  • The temperature of the surroundings

The transition state represents the highest energy point in a reaction.

True (A)

What is the term for the maximum energy that reactants need to reach the transition state?

activation energy

In an __________ reaction, the products have lower energy than the reactants.

<p>exothermic</p> Signup and view all the answers

Match the type of reaction with the energy change:

<p>Exothermic = Releases energy Endothermic = Absorbs energy</p> Signup and view all the answers

What is the 'collision theory' primarily concerned with?

<p>The energy and orientation of colliding molecules (B)</p> Signup and view all the answers

Increasing the concentration of reactants always guarantees a faster reaction.

<p>True (A)</p> Signup and view all the answers

What is another term for the 'transition state'?

<p>activated complex</p> Signup and view all the answers

An endothermic reaction will feel _________ to the touch as it proceeds.

<p>colder</p> Signup and view all the answers

Match the graph type with the reaction type:

<p>Left graph = Exothermic Right graph = Endothermic</p> Signup and view all the answers

What is the significance of 'activation energy' in a chemical reaction?

<p>It is the minimum energy needed for the reaction to start (A)</p> Signup and view all the answers

In exothermic reactions, energy is absorbed from the surroundings.

<p>False (B)</p> Signup and view all the answers

In a potential energy diagram, what does the peak represent?

<p>transition state</p> Signup and view all the answers

The spatial arrangement of reacting substances is referred to as _________.

<p>orientation</p> Signup and view all the answers

Match the energy levels with the respective reaction

<p>Reactants &gt; Products = Exothermic Reactants &lt; Products = Endothermic</p> Signup and view all the answers

In an exothermic reaction, is the net energy emission from, or absorption to, the system?

<p>Net energy emission (C)</p> Signup and view all the answers

Activation energy lowers in the processes.

<p>False (B)</p> Signup and view all the answers

What type of processes are shown on the graphs in the book?

<p>exothermic and endothermic</p> Signup and view all the answers

The minimum amount of energy needed for a chemical reaction to occur is termed ___________.

<p>activation energy</p> Signup and view all the answers

Choose the sentence with the corresponding process.

<p>Energy is emitted. = Exothermic Energy is absorbed. = Endothermic</p> Signup and view all the answers

Flashcards

Activation Energy

The minimum energy needed to cause an effective collision that breaks bonds.

Transition state / Activated Complex

A compound formed when reactants collide with enough energy to break bonds and rearrange atoms.

Collision Theory

Collisions and spatial orientation of the reactants determine product formation.

Transition State

A state of high energy and instability between reactants and products during a chemical reaction.

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Exothermic Process

Energy released to the environment, resulting in the products having less energy than the reactants.

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Endothermic Process

Energy gained from the environment, resulting in the products having more energy than the reactants.

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Study Notes

Collision Theory

  • According to collision theory, collision energy is a parameter that defines a reaction.
  • Spatial orientation of reactants will impact the formation of products.

Energy Threshold

  • The highest energy threshold reactants have is specific to each process.
  • This is called the transition state, or activation complex.
  • To generate new species, all bonds in the reactants must change.
  • This happens the moment the reactant changes its nature.

Energy Profiles

  • Energy profiles analyze energy based on reaction occurrence.
  • The following are standard graphs of processes with energy emission and consumption.

Exothermic Process

  • The graph accounts for a process where the energy of the products is less than that of the initial reactants.
  • This results in energy emission to the environment.

Endothermic Process

  • The products have more energy than the reactants.
  • This implies a gain for the system from the environment's energy.
  • This graph defines an endothermic process.

Activation Energy

  • Both clarify the activation energy, the maximum energy threshold (activation complex), and the total energy balance.

Chemical Reaction Analysis

  • Every chemical process with new substances forming necessarily involves a collision of particles or reaction substances.
  • Several parameters need analysis and definition.

Reactants

  • Reactants must collide with enough energy to break bonds and generate new substances.
  • If the energy threshold is not met, the reaction does not occur.

Activation Energy

  • Activation energy refers to the minimum energy needed for an effective collision that breaks bonds.
  • Every chemical process needs this threshold for reactants to become stable products.

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