Cobalt Complexes and Oxidation States Quiz

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Questions and Answers

Which oxidation state of cobalt tends to form many stable complexes?

Co (III)

What is the KH2O exchange value for Co2+?

3.2 x 106

Why is Co2+ considered a good starting material (precursor)?

It is labile and low in affinity toward converting into Co3+

Why is Co3+ diamagnetic?

<p>Pairing energy is greater than crystal field stabilization energy (CFSE)</p> Signup and view all the answers

Why is Co3+ unstable in an aqua medium?

<p>It quickly reduces to Co2+ in aqua medium</p> Signup and view all the answers

Study Notes

Cobalt Oxidation States

  • Co2+ tends to form many stable complexes.
  • The KH2O exchange value for Co2+ is 1.8.

Properties of Co2+

  • Co2+ is a good starting material (precursor) due to its ease of preparation and ability to be oxidized to Co3+.

Properties of Co3+

  • Co3+ is diamagnetic due to the pairing of all electrons in its d-orbital configuration.
  • Co3+ is unstable in an aqua medium and undergoes rapid reduction to Co2+.

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