Cobalt Complexes and Oxidation States Quiz
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Questions and Answers

Which oxidation state of cobalt tends to form many stable complexes?

  • Co (I)
  • Co (II)
  • Co (III) (correct)
  • Co (IV)
  • What is the KH2O exchange value for Co2+?

  • 0.8 x 106
  • 3.2 x 106 (correct)
  • 5.2 x 106
  • 1.8 x 106
  • Why is Co2+ considered a good starting material (precursor)?

  • It has high affinity toward converting into Co3+
  • It is a powerful reducing agent
  • It is diamagnetic in nature
  • It is labile and low in affinity toward converting into Co3+ (correct)
  • Why is Co3+ diamagnetic?

    <p>Pairing energy is greater than crystal field stabilization energy (CFSE)</p> Signup and view all the answers

    Why is Co3+ unstable in an aqua medium?

    <p>It quickly reduces to Co2+ in aqua medium</p> Signup and view all the answers

    Study Notes

    Cobalt Oxidation States

    • Co2+ tends to form many stable complexes.
    • The KH2O exchange value for Co2+ is 1.8.

    Properties of Co2+

    • Co2+ is a good starting material (precursor) due to its ease of preparation and ability to be oxidized to Co3+.

    Properties of Co3+

    • Co3+ is diamagnetic due to the pairing of all electrons in its d-orbital configuration.
    • Co3+ is unstable in an aqua medium and undergoes rapid reduction to Co2+.

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    Description

    Understand the preparation of [Co(NH3)6]Cl3 and the importance of Co (II) and Co (III) oxidation states in cobalt complexes. Learn about the characteristics of Co (II) and Co (III) and their relevance in forming stable complexes. Explore the electronic configuration and the Crystal Field Stabilization Energy (C.F.S.E) in this quiz.

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