Class 12th Chemistry CBSE Exam Topics

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Questions and Answers

What is a significant characteristic of coordination compounds?

  • They are always ionic in nature.
  • They exclusively form in aqueous solutions.
  • They contain a central metal atom bonded to surrounding ligands. (correct)
  • They can never exhibit geometrical isomerism.

Which statement correctly describes haloalkanes?

  • They are non-polar substances.
  • They generally have low boiling points compared to hydrocarbons.
  • They primarily undergo nucleophilic substitution reactions. (correct)
  • They react only through elimination reactions.

Which compound is classified as a phenol?

  • Cresol (correct)
  • Benzaldehyde
  • Ethanol
  • Acetic acid

What fundamental reaction characterizes aldehydes and ketones?

<p>Nucleophilic addition reactions (B)</p> Signup and view all the answers

Which type of biomolecule is primarily involved in genetic information?

<p>Nucleic acids (D)</p> Signup and view all the answers

Which of the following correctly identifies a characteristic of crystalline solids?

<p>They exhibit anisotropic properties. (A)</p> Signup and view all the answers

Which concentration unit is defined as the number of moles of solute per liter of solution?

<p>Molarity (C)</p> Signup and view all the answers

What is the main function of a catalyst in a chemical reaction?

<p>To speed up the reaction rate without being consumed. (C)</p> Signup and view all the answers

Which electrochemical cell converts chemical energy into electrical energy?

<p>Galvanic cell (B)</p> Signup and view all the answers

In the context of adsorption, what differentiates physisorption from chemisorption?

<p>Chemisorption is typically irreversible, whereas physisorption is reversible. (A)</p> Signup and view all the answers

What is the primary purpose of the Ellingham diagram in metallurgy?

<p>To show the relationship between temperature and reaction spontaneity. (B)</p> Signup and view all the answers

Which of the following properties is commonly observed in d-block elements?

<p>Forming colored compounds and displaying variable oxidation states. (C)</p> Signup and view all the answers

Which of the following statements regarding colligative properties is true?

<p>They depend solely on the number of solute particles in a solution. (D)</p> Signup and view all the answers

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Flashcards

Coordination Compounds

Compounds formed when a central metal atom or ion is surrounded by ligands (molecules or ions with lone pairs of electrons) that donate electrons to form coordinate covalent bonds.

Geometric Isomerism

A type of isomerism in coordination compounds where the arrangement of the ligands around the central metal ion differs, but the same ligands are present.

Haloalkanes/Haloarenes

Organic compounds containing a halogen atom (F, Cl, Br, or I) bonded to a carbon atom.

Nucleophilic Substitution Reaction

A reaction where a nucleophile (electron-rich species) replaces a leaving group (usually a halogen) on a haloalkane.

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Aldehydes and Ketones

Aldehydes and ketones are organic compounds containing a carbonyl group (C=O). Aldehydes have the carbonyl group at the end of a carbon chain, while ketones have it within the chain.

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Crystalline Solid

A type of solid with a regular, repeating arrangement of atoms or molecules, resulting in a long-range order.

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Amorphous Solid

A solid with a disordered arrangement at the atomic or molecular level, lacking the long-range order found in crystalline solids.

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Packing Efficiency

The ratio of the volume occupied by atoms in a unit cell to the total volume of the unit cell, expressed as a percentage.

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Coordination Number

A measure of the number of nearest neighbors that an atom or ion has in a crystal structure.

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Concentration

A measure of how much solute is dissolved in a given amount of solvent.

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Colligative Properties

Properties of solutions that depend on the number of solute particles, not their identity.

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Redox Reaction

A chemical reaction involving both oxidation and reduction occurring simultaneously.

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Standard EMF

The difference in potential between two half-cells in an electrochemical cell, measured under standard conditions.

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Study Notes

Important Topics for Class 12th Chemistry CBSE Board Exam

  • Solid State:

    • Understand different types of solids (crystalline and amorphous) and their structures
    • Know packing efficiency in different crystal systems (e.g., cubic)
    • Learn about defects in solids and their impact on properties
    • Define and calculate characteristics of unit cells, lattice points, and coordination number
    • Study the relationship between structure and properties of solids
  • Solutions:

    • Focus on various aspects of solutions, including concentration units (molarity, molality, mole fraction)
    • Understand factors affecting solubility
    • Study colligative properties (relating to the number of solute particles) and their applications (e.g., freezing point depression, boiling point elevation, osmotic pressure)
  • Electrochemistry:

    • Master concepts of redox reactions, electrochemical cells (galvanic and electrolytic)
    • Understand EMF calculations and the Nernst equation
    • Understand applications of electrochemical cells, like batteries and corrosion
    • Pay close attention to EMF calculation aspects
  • Chemical Kinetics:

    • Study the rate of chemical reactions, rate laws, order and molecularity of reactions
    • Understand factors influencing reaction rates (temperature, catalyst, concentration)
    • Learn integrated rate equations
    • Understand the concept of half-life of a reaction
  • Surface Chemistry:

    • Understand adsorption, factors affecting adsorption, methods of adsorption, and applications of adsorption
    • Know the differences between physisorption and chemisorption
    • Focus on catalysis and its importance in industrial processes
  • General Principles and Processes of Isolation of Elements:

    • Study different methods of metal extraction (e.g., metallurgy) based on the reactivity series
    • Understand electrolytic methods, refining processes, and the concept of Ellingham diagrams
  • p-Block Elements:

    • Focus on general characteristics, trends, and properties of important p-block element compounds
    • Be prepared for practical applications involving p-block element properties
    • Consider the anomalous behavior of elements
  • d and f Block Elements:

    • Understand general characteristics of transition elements, redox properties of relevant ions, and important d-block element compounds
    • Be familiar with the chemistry of inner transition elements (lanthanides and actinides)
    • Focus on preparation, properties, and uses of key compounds related to d and f block elements (e.g., coordination complexes)
    • Grasp concepts related to metal complexes and coordination compounds
  • Coordination Compounds:

    • Focus on basic principles, nomenclature, isomerism, and applications of coordination compounds
    • Be versed in different types of isomerism
  • Haloalkanes and Haloarenes:

    • Review important reactions (nucleophilic substitution reactions) and properties of haloalkanes and haloarenes
  • Alcohols, Phenols and Ethers:

    • Focus on properties, reactions, and distinctions between alcohols, phenols, and ethers
    • Be familiar with essential reactions between these organic compounds
  • Aldehydes, Ketones and Carboxylic Acids:

    • Study important reactions (nucleophilic addition reactions), chemical properties and reactions of aldehydes, ketones and carboxylic acids
  • Organic Compounds Containing Nitrogen:

    • Review properties and reactions of amines, amides, nitro compounds, and diazonium salts
    • Understand nucleophilic substitution reactions
  • Biomolecules:

    • Understand structure, properties, and biological significance of carbohydrates, proteins, and nucleic acids
  • Polymers:

    • Know different types of polymers, their synthesis, properties, and applications
  • Chemistry in Everyday Life:

    • Focus on applications of chemistry in medicine, agriculture, and industries
    • Be prepared to explain the utility of various chemical products in everyday life

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