CHM 2045 Fall 2022 Exam 1

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Questions and Answers

How many grams of NO2 can be formed from 10.0 g of NO if the percent yield of the first step is 35.0% and the second step is 40.0%?

  • 2.80 g
  • 4.29 g (correct)
  • 2.15 g
  • 11.5 g

What volume of 1.0 M magnesium chloride solution must be added to produce 20.0 g of precipitate?

  • 70 mL
  • 140 mL (correct)
  • 280 mL
  • 20 mL

If 50.0 mL of 0.200 M NaOH is required to neutralize 10.0 mL of H2SO4, what is the molarity of the acid solution?

  • 1.00 M
  • 0.100 M
  • 0.500 M
  • 2.00 M (correct)

Which equation is classified as a reduction/oxidation reaction?

<p>2 AgNO3(aq) + Cu(s) → Cu(NO3)2(aq) + 2 Ag(s) (D)</p> Signup and view all the answers

What is the density of argon gas at 55.0°C and 765 mmHg?

<p>1.49 g/L (A)</p> Signup and view all the answers

What is the temperature of a gas in a 4.0-L flask reduced to 442 mmHg from an initial pressure of 884 mmHg?

<p>47.0°C (C)</p> Signup and view all the answers

After 45% of H2 leaks from a balloon filled with equal amounts of H2 and N2, what percentage of N2 remains?

<p>83% (D)</p> Signup and view all the answers

What volume of 0.75 M calcium nitrate solution must be diluted to produce 1.00 L of 0.45 M nitrate ion solution?

<p>167 mL (C)</p> Signup and view all the answers

How many of the following quantities have five significant figures: 0.1055 g, 53,080 mL, 0.0020 L, 0.0000081200 cm³, 0.00004813 m?

<p>two (A)</p> Signup and view all the answers

What is the mass of the second isotopic form of bromine if 79Br has a mass of 78.9 amu and accounts for 50.3% of bromine atoms?

<p>80.1 amu (B)</p> Signup and view all the answers

Classify the following substances: sweat, carbon dioxide, aluminum.

<p>mixture, heterogeneous; pure substance, compound; pure substance, element (C)</p> Signup and view all the answers

Identify which of the following formulas and names are correct for chemical compounds.

<p>CoCl2 -- cobalt chloride (A), P2I4 -- diphosphorus tetraiodide (C)</p> Signup and view all the answers

What is the symbol for an isotope containing 82 protons and 122 neutrons?

<p>204Pb (A)</p> Signup and view all the answers

How many atoms of oxygen are in 5.0 grams of Ca3(PO4)2?

<p>7.8x10^22 (B)</p> Signup and view all the answers

Which of the following describes a pure substance?

<p>Sugar is a pure compound. (B)</p> Signup and view all the answers

Which of the following statements correctly identifies a characteristic of isotopes?

<p>Isotopes differ in their neutron count and thus mass number. (B), Isotopes of an element have the same number of protons but different masses. (D)</p> Signup and view all the answers

What is the sum of the coefficients when balancing the equation Ca3(PO4)2 + SiO2 + C → CaSiO3 + P4 + CO?

<p>26 (B)</p> Signup and view all the answers

Which of the following is the net ionic equation for the reaction between Ca(OH)2 and FeSO4?

<p>2OH^−^ + Fe^2+^ → Fe(OH)<del>2</del> (D)</p> Signup and view all the answers

Identify the oxidizing agent in the reaction: 2 NaMnO4 (aq) + 3 Na2C2O4(aq) + 4 NaOH (aq) → 2 MnO2(s) + 6 Na2CO3(aq) + 2 H2O(l).

<p>NaMnO<del>4</del> (D)</p> Signup and view all the answers

Which of the following has the correct oxidation state listed for Mn?

<p>+6 in K<del>2</del>MnO<del>4</del> (C)</p> Signup and view all the answers

If a chalcocite ore contains 75.0% copper (I) sulfide by mass, how many kilograms of copper can be extracted from 80.0 kg of chalcocite?

<p>39.9 kg (A)</p> Signup and view all the answers

What is the volume of 10^6 bacterial cells, given that the volume of one bacterial cell is 3.25 µm^3?

<p>3.25 x 10^-3 L (C)</p> Signup and view all the answers

Convert the rate R = 0.0406 kPa km^-1 to mJ m^-4.

<p>0.0406 J m^-4 (D)</p> Signup and view all the answers

Determine the moles of the excess reactant remaining when 12.0 moles of F2 and 7.0 moles of N2 react completely in the equation 3 F2(g) + N2(g) → 2 NF3.

<p>4.0 moles (B)</p> Signup and view all the answers

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Study Notes

Exam Overview

  • Exam covers Chapters 1-5, involving significant figures, isotopes, chemical classification, formulas, isotopes, stoichiometry, net ionic equations, oxidation states, and gas laws.
  • Structure includes two sections: Questions 1-10 are worth 5 points each, Questions 11-25 worth 10 points each.

Significant Figures

  • Identify quantities with five significant figures:
    • Examples: 0.1055 g (4 sig figs), 53,080 mL (5 sig figs), 0.0020 L (3 sig figs), 0.0000081200 cm³ (6 sig figs), 0.00004813 m (4 sig figs).

Isotopes

  • Bromine has two isotopes; ^79Br has 78.9 amu, accounting for 50.3% of atoms.
  • Calculating the mass of the second isotope is essential for understanding isotopic distribution.

Pure Substances vs Mixtures

  • Classify substances:
    • Sweat: Mixture, heterogeneous
    • Carbon Dioxide (COâ‚‚): Pure substance, compound
    • Aluminum (Al): Pure substance, element

Chemical Formulas and Names

  • Important formulas and their names:
    • CoClâ‚‚: Cobalt chloride
    • Pâ‚‚Iâ‚„: Diphosphorus tetraiodide
    • Hâ‚‚PO₃: Phosphorous acid

Isotope Symbol Notation

  • Protons and neutrons determine isotope symbol:
    • 82 protons, 122 neutrons give symbols like ^204_82Pb.

Stoichiometry

  • Calculate moles of oxygen in compounds like Ca₃(POâ‚„)â‚‚ and balance chemical equations accurately.

Ionic Equations

  • Identify net ionic equations such as the reaction between Ca(OH)â‚‚ and FeSOâ‚„, focusing on actual chemical changes.

Oxidation and Reduction

  • Recognize oxidizing agents in chemical reactions, using examples like NaMnOâ‚„.

Gas Law Applications

  • Problems related to gas properties, determinations of density, and effects of temperature and pressure.

Solutions and Concentrations

  • Calculation of molarity and relationships in neutralization reactions, exemplified by titrations with NaOH and Hâ‚‚SOâ‚„.

Precipitation and Acid/Base Reactions

  • Understand classification of reactions, such as precipitation vs. acid/base theories.

Volume and Concentration Calculations

  • Convert between units and calculate volumes needed for certain molarities, applying the dilution equation.

Percent Composition and Yield Calculations

  • Work through combustion analysis to determine empirical and molecular formulas from product masses.

Decomposition Reactions

  • Analyze decompositions involving complex compounds like XeOâ‚„, applying concepts of yield and purification methods.

Each bullet detail is critical for mastering the relevant chemistry concepts presented in the exam content. Being familiar with these details will enhance understanding and performance on the exam.

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