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Questions and Answers

What is the formula for calcium hypochlorite?

Ca(OCl)₂

How many grams of solute are in 450 g of a 25% (w/w) solution?

112.5 g

What is the mass in grams of 250 cm³ of a substance with a density of 1.45 kg/dm³?

362.5 g

What is the volume in cm³ of 250 g of a substance with a density of 1.45 kg/dm³?

<p>172.4 cm³</p> Signup and view all the answers

What is the formula for hydrogen peroxide?

<p>H₂O₂</p> Signup and view all the answers

What is the formula for ozone?

<p>O₃</p> Signup and view all the answers

Which ions cause water hardness?

<p>Mg²⁺, Ca²⁺ (B)</p> Signup and view all the answers

What is the term used to describe water with a high Mg- and Ca-salt content?

<p>Heavy water</p> Signup and view all the answers

What are the components of bleach (with formula)?

<p>NaOCl, H₂O</p> Signup and view all the answers

What is the formula for orthophosphoric acid?

<p>H₃PO₄</p> Signup and view all the answers

What is the formula for nitrogen oxide?

<p>NO</p> Signup and view all the answers

What is the formula for carbon monoxide?

<p>CO</p> Signup and view all the answers

How does the boiling point of a liquid depend on external pressure?

<p>The greater the pressure, the more energy required for liquids to boil, and the higher the boiling point.</p> Signup and view all the answers

What is the definition of equilibrium vapor pressure?

<p>The pressure exerted by a vapor that is in equilibrium with the condensed phase (solid or liquid) at a given temperature in a closed system.</p> Signup and view all the answers

Which factors influence the solubility of a gas in liquids?

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Flashcards

Reaction Rate

The measure of the change in concentration of the reactants or the change in concentration of the products per unit time.

Half-life

The time required for the concentration of the reactant to decrease to halfway between its initial and final values.

Catalyst

A substance that increases the rate of a chemical reaction by opening a new path by which the reaction can take place or by lowering the energy of activation.

Inhibition

A substance that decreases the activity of a catalyst by blocking its 'active site'.

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Electrolysis

Process by which electric current is passed through a substance to effect a chemical change, leading to either loss (oxidation) or gain (reduction) of electrons.

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Galvanic Cell

A cell that uses a chemical redox-reaction to produce electrical energy.

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Oxidation

The loss of electrons during a reaction.

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Reduction

The gaining of electrons during a reaction.

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Hydrolyzing Salt

A process that occurs when salt is mixed into the water and the water breaks the ionic bond, resulting in either acidic or basic aqueous solutions.

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Colloidal Systems

A mixture of two substances, a dispersed phase and a dispersion medium in which the dispersed substance's particle size is between 1nm - 500nm.

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Emulsion

A mixture of two or more liquids that are normally immiscible, resulting in liquid-liquid phase separation.

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Suspension

A heterogeneous mixture of a finely distributed solid in a liquid.

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Adsorption

Change in the concentration of a substance at a phase interface.

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Hydration

A chemical reaction in which a substance combines with water.

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Chemical compound

The result of the combination of atoms that contains the same kind of atoms combined in the same proportions.

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Isotope

Atoms whose nuclei have the same atomic number (same number of protons), but different mass number (different number of neutrons).

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Valence Electrons

Electrons in the outermost shell of an atom that can participate in the formation of a chemical bond (if the shell is not closed).

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Exothermic Process

Any process that gives off heat, transferring thermal energy to its surroundings.

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Endothermic Process

Any process that has to be supplied with heat by its surroundings.

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Heat of Combustion

Heat produced when a substance is combusted in excess of oxygen (completely oxidized).

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Equilibrium Vapor Pressure

The pressure exerted by a vapor that is in equilibrium with the condensed phase (solid or liquid) at a given temperature in a closed system.

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Isotonic Solution

The state when two solutions have equal concentration of solutes across a semipermeable membrane.

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Hypertonic solution

A type of solution that has a higher concentration of solutes on the outside of a cell than on the inside of the cell.

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Hypotonic Solution

A type of solution that has a lower concentration of solutes on the outside of a cell than on the inside of the cell.

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Osmosis

The solvent flows through the membrane to equalize the solute concentration on both sides of the membrane.

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Osmotic Pressure

Equals to the pressure that when applied to the solution just stops osmosis.

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Acids (Arrhenius Theory)

a compound that produces H+-ions in water.

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Bases (Arrhenius Theory)

a compound that produces OH--ions in water.

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Acids (Brönsted-Lowry Theory)

a compound that can donate protons (proton donor)

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Bases (Brönsted-Lowry Theory)

a compound that can accept protons (proton acceptor)

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Buffer Solutions

a solution capable of maintaining its pH at nearly constant value even when small amounts of strong acid/base are added.

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Chelate Complex

a compound that has two or more coordinate or dative bonds between a ligand and a central metal atom.

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Macrocyclic Chelate

large, cyclic ligands with three or more donor sites

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Metal Complex

a central cation or anion and ligands

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Heavy Water

water that has a high Mg- and Ca-salt content

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Metal Corrosion

the process whereby metals are oxidized to their oxides and sulphides

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Local Cell

a galvanic cell that is formed due to physical or chemical differences between areas on a metal surface in an electrolyte

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Study Notes

Unit Conversions

  • Mass conversions: mg to g to kg (1000 mg = 1 g, 1000 g = 1 kg)
  • Volume conversions: cm³ to dm³ to m³ (1000 cm³ = 1 dm³, 1000 dm³ = 1 m³)
  • Amount of substance conversions: mmol to mol (1000 mmol = 1 mol)
  • Density conversions: g/cm³ to kg/m³ (1 g/cm³ = 1000 kg/m³)
  • Pressure conversions: MPa to kPa to Pa (1 MPa = 1000 kPa, 1 kPa = 1000 Pa)

Simple Calculation Tasks

  • Mass percentage/mass fraction: Calculate mass fraction or mass percentage using the formula:
    Mass fraction = mass of substance / (mass of substance + mass of water) Mass percentage = (mass of substance / (mass of substance + mass of water)) * 100
  • Molar percentage/molar fraction Calculate molar fraction or molar percentage using the formula: Molar fraction = moles of substance / (moles of substance + moles of water) Molar percentage = (moles of substance / (moles of substance + moles of water)) * 100
  • Amount concentration: Amount concentration (c) = moles of substance / volume of solution (in liters)
  • Density: Density (ρ) = mass of substance / volume of solution (in appropriate units)
  • Mass concentration: Mass concentration (y) = mass of substance / volume of solution (in appropriate units)

Use of Mixing Equation

  • Example calculations involve determining solute quantities in solutions given solution mass and percentage, density, and volume.

Formulas of Inorganic Compounds

  • Key ionic compounds are provided for determining formulas
    • Nitrite (NO₂⁻), Nitrate (NO₃⁻), Iron (II) (Fe²⁺), Iron (III) (Fe³⁺), Carbonate (CO₃²⁻), Ammonium (NH₄⁺), etc.

Inorganic Chemistry

  • Chlorine containing disinfectants include Sodium hypochlorite (NaOCl), Calcium hypochlorite (Ca(OCl)₂), and Hypochlorous acid (HOCl)
  • Chlorine free disinfectants include Iodine, Ozone, and Hydrogen peroxide
  • Ions that cause water hardness include Mg²⁺ and Ca²⁺
  • "Heavy water" is water with a high concentration of Mg and Ca salts
  • Bleach components include NaOCl and H₂O
  • Chlorinated lime formula is Ca(OCl)₂

Kinetics

  • Reaction rate describes the change in reactant/product concentrations per unit time
  • Reaction rate can be influenced by temperature, pressure, and concentration
  • Half-life is the time for a reactant concentration to decrease by half
  • Catalysis speeds up reactions by opening alternative paths or lowering activation energy
  • Inhibition counteracts catalysis by blocking the catalyst's active site

Electrolysis

  • Electrolysis is using an electric current to cause a chemical change
  • Galvanic cells use chemical reactions to generate electrical energy
  • Anode is the negative electrode (where oxidation occurs)
  • Cathode is the positive electrode (where reduction occurs)
  • Cations move from anode to cathode through the salt bridge
  • Anions move from cathode to anode through the salt bridge
  • Oxidation involves the loss of electrons
  • Reduction involves gaining electrons
  • Components of pH measurement involve glass electrode (sensitive to H⁺ concentration) and a reference electrode (constant). Metal corrosion is the oxidation of metals to their oxides/sulfides. Local cells form at varying metal surface areas exposed to an electrolyte.

Equilibria

  • Mass action law describes the equilibrium constant (K) for a reversible reaction
  • Le Chatelier's Principle states how a system in equilibrium responds to changes in conditions. The system adjusts to minimize the effect of the change
  • Arrhenius theory defines acids as substances that release H+ ions, and bases as substances that release OH- ions.
  • Brönsted-Lowry theory defines acids as proton donors, and bases as proton acceptors.
  • Ion Product of water(Kw) is the concentration of hydronium and hydroxide ions in water. pH is the negative logarithm of the hydrogen ion concentration. pOH is the negative logarithm of the hydroxide ion concentration.
  • Weak acids partially dissociate in solution, while strong acids completely dissociate
  • Substances that prevent large changes in pH are called buffers and are made of a weak acid/base and a salt. Hydrophilic salts dissolve in water and can be acidic or basic based on their chemistry.

Colloids

  • Colloidal systems are mixtures with particles between 1 and 500 nm in size
  • Emulsions are mixtures of immiscible liquids
  • Suspensions involve finely dispersed solids in liquids
  • Adsorption is a concentration change at a phase boundary
  • Hydration involves a substance combining with water

Miscellaneous

  • Chemical compounds result from combining atoms in specific proportions
  • Isotopes are atoms of the same element with different numbers of neutrons but the same number of protons
  • Valence electrons are located in the outermost electron shell; they are involved in forming chemical bonds.
  • Hydrogen bonds occur when electronegative atoms (F, O, N) are bound to hydrogen

States of Matter

  • Boiling point increases with external pressure because more energy is required to overcome the increased opposition
  • Equilibrium vapor pressure is the pressure exerted by a vapor and the condensed phase at a given temperature in a closed system
  • Factors affecting gas solubility in liquids are temperature, pressure, and the nature of the solute and solvent
  • Osmosis is the movement of a solvent through a membrane to equalize solute concentrations
  • Osmotic pressure is the pressure needed to halt osmosis
  • Isotonic solutions have equal solute concentrations
  • Hypertonic solutions have a higher solute concentration outside the cell than inside
  • Hypotonic solutions have a lower solute concentration outside the cell than inside

Heat of Combustion

  • Exothermic processes release heat to the surroundings
  • Endothermic processes absorb heat from the surroundings
  • Heat of combustion is the heat released when a substance reacts completely with oxygen

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