Chemistry Unit 1 Recap
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What is the frequency of radiation if its wavelength is $5.80 x 10^{-7}$ m? The value of $\lambda$ = ______

$5.80 x 10^{-7}$ m

What is the frequency of radiation if its wavelength is $5.80 x 10^{-7}$ m? The unknown (what you are solving for) is?

frequency

What is the frequency of radiation if its wavelength is $5.80 x 10^{-7}$ m? The symbol for the unknown is?

(\nu)

What is the frequency of radiation if its wavelength is $5.80 x 10^{-7}$ m? What is the equation you will use to solve the problem?

<p>$c = \lambda \nu$</p> Signup and view all the answers

What is the frequency of radiation if its wavelength is $5.80 x 10^{-7}$ m? Any constant you will use, what is it?

<p>c (speed of light)</p> Signup and view all the answers

What is the frequency of radiation if its wavelength is $5.80 x 10^{-7}$ m? What is the value of the constant?

<p>$3.00 x 10^8$ m/s</p> Signup and view all the answers

What is the energy of light if its wavelength is $4.25 x 10^{-7}$ m? The value of $\lambda$ = ______

<p>$4.25 x 10^{-7}$ m</p> Signup and view all the answers

What is the energy of light if its wavelength is $4.25 x 10^{-7}$ m? The unknown (what you are solving for) is?

<p>energy</p> Signup and view all the answers

What is the energy of light if its wavelength is $4.25 x 10^{-7}$ m? The symbol for the unknown is?

<p>E</p> Signup and view all the answers

What is the energy of light if its wavelength is $4.25 x 10^{-7}$ m? The equation you will use to solve problem is?

<p>$E = \frac{hc}{\lambda}$</p> Signup and view all the answers

What is the energy of light if its wavelength is $4.25 x 10^{-7}$ m? Any constants you will use, what are they?

<p>h and c</p> Signup and view all the answers

What is the energy of light if its wavelength is $4.25 x 10^{-7}$ m? What are the values for the constants?

<p>h = $6.626 x 10^{-34}$ J.s, c = $3.00 x 10^8$ m/s</p> Signup and view all the answers

What is the frequency of light if its energy is $4.25 x 10^{-19}$ J? The value of energy = ______

<p>$4.25 x 10^{-19}$ J</p> Signup and view all the answers

What is the frequency of light if its energy is $4.25 x 10^{-19}$ J? The symbol for energy =?

<p>E</p> Signup and view all the answers

What is the frequency of light if its energy is $4.25 x 10^{-19}$ J? The unknown (what you are solving for) is?

<p>frequency</p> Signup and view all the answers

What is the frequency of light if its energy is $4.25 x 10^{-19}$ J? The symbol for the unknown is?

<p>(\nu)</p> Signup and view all the answers

What is the frequency of light if its energy is $4.25 x 10^{-19}$ J? The equation you will use to solve problem is?

<p>$E = h\nu$</p> Signup and view all the answers

What is the frequency of light if its energy is $4.25 x 10^{-19}$ J? Any constant values you will use, what are they?

<p>Plank's constant</p> Signup and view all the answers

If the energy of light is $6.15 x 10^{-19}$ J, what would be the wavelength of this light?

<p>323 nm</p> Signup and view all the answers

Draw an absorption energy level diagram for an electron at the ground state level of n = 2 and transitions to n = 5. Label the parts of the diagram (energy axis, ground state, excited state, light coming in, electron transition)

<p>Refer to diagram</p> Signup and view all the answers

Draw an emission energy level diagram for an electron at an excited state level of n = 4 and transitions to n = 1. Label the parts of the diagram (energy axis, ground state, excited state, light coming out, electron transition)

<p>Refer to diagram</p> Signup and view all the answers

Draw a Bohr diagram for sulfur, S. Include electrons in diagram. # electrons are in sulfur?

<p>16</p> Signup and view all the answers

Draw a Bohr diagram for sulfur, S. Include electrons in diagram. # of energy levels

<p>3</p> Signup and view all the answers

Draw a Bohr diagram for sulfur, S. Include electrons in diagram. # valence electrons?

<p>6</p> Signup and view all the answers

Draw a Bohr diagram for sulfur, S. Include electrons in diagram. Energy level where valence electrons can be found?

<p>3</p> Signup and view all the answers

Draw the following orbitals. Make sure to label the axes: pz

<p>Refer to diagram</p> Signup and view all the answers

If n = 3, what are the possible values of l?

<p>0, 1, 2</p> Signup and view all the answers

Draw an energy level diagram that include the orbitals, 1s, 2s, 2p, 3s, 3p, 3d, 4s, and 4p. Then fill the orbitals with electrons (arrows) corresponding to the element chromium. (Hint: start with the lowest energy)

<p>Refer to diagram</p> Signup and view all the answers

Write the electron configuration and the orbital diagrams for Carbon, C

<p>Refer to diagram</p> Signup and view all the answers

Write the electron configuration and the orbital diagrams for Oxygen, O

<p>Refer to diagram</p> Signup and view all the answers

Write the electron configuration and the orbital diagrams for Sodium, Na

<p>Refer to diagram</p> Signup and view all the answers

Write the electron configuration and the orbital diagrams for Phosphorus, P

<p>Refer to diagram</p> Signup and view all the answers

Write the electron configuration and the orbital diagrams for Titanium

<p>Refer to diagram</p> Signup and view all the answers

Write the electron configuration and the orbital diagrams for Arsenic, As

<p>Refer to diagram</p> Signup and view all the answers

Determine the number of valence electrons for Magnesium

<p>2</p> Signup and view all the answers

Determine the number of valence electrons for Chlorine

<p>7</p> Signup and view all the answers

Determine the number of valence electrons for Silicon

<p>4</p> Signup and view all the answers

Circle the ions that are isoelectronic with argon, Ar.

<p>S2- (A), Cl- (D), K+ (E), Ca2+ (G)</p> Signup and view all the answers

For each pair, circle the element or ion that has a larger radius: Mg or Al

<p>Mg (A)</p> Signup and view all the answers

The decrease in the atomic radii of the elements in this table can best be explained by:

<p>As the number of protons increases, the attraction between the positive nucleus and the negative electron cloud increases, thus pulling the electrons toward the nucleus and decreasing the radii. (D)</p> Signup and view all the answers

Sulfur is in group 4B of the Periodic Table and normally holds 4 valence electrons before it reacts with other elements. Which of the following electron configurations matches sulfur?

<p>$1s^22s^22p^63s^23p^4$ (C)</p> Signup and view all the answers

Calcium has an electron configuration of $1s^22s^22p^63s^23p^64s^2$. Based on this information, how many valence electrons does calcium have?

<p>2 (C)</p> Signup and view all the answers

Flashcards

Wavelength (λ)

The distance between successive peaks in a wave.

Frequency (ν)

The number of waves that pass a point in a second.

Energy (E)

The capacity to do work; in light, related to frequency and wavelength.

Planck's constant (h)

A fundamental constant used to relate energy and frequency.

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c (Speed of light)

The speed at which light travels in a vacuum, approximately 3.00 x 10^8 m/s.

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Energy-Wavelength Relationship

E = hc/λ describes how energy relates to wavelength.

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Ionization Energy

The energy required to remove an electron from an atom.

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Atomic Radius

The size of an atom, measured from the nucleus to the outermost electron.

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Valence Electrons

Electrons in the outermost shell that participate in chemical bonding.

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Isoelectronic

Atoms or ions that have the same electron configuration.

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Absorption Spectrum

Pattern formed when atoms absorb specific wavelengths of light.

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Emission Spectrum

Light emitted by excited atoms as they return to lower energy states.

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Electron Configuration

The arrangement of electrons in an atom's energy levels.

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Nuclear Charge

The total charge of the nucleus due to protons.

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Periodic Trend

Patterns in properties like atomic size and ionization energy across periods and groups.

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Ground State

The lowest energy state of an atom with electrons in the lowest available orbitals.

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Excited State

A state where an electron has absorbed energy and moved to a higher energy level.

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P, d Orbitals

Specific shapes of electron clouds where electrons reside.

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Electron Transition

Movement of an electron between energy levels.

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Chemical Bond

A lasting attraction between atoms that enables the formation of chemical compounds.

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Electronegativity

A measure of an atom's ability to attract and hold onto electrons in a bond.

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Chemical Radius Effect

Atomic radius generally decreases across a period due to increased nuclear charge.

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Larger Radius Elements

Elements lower in groups tend to have larger atomic radii.

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Valence Electron Count

Number of electrons in the outermost shell of an atom.

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Energy Level Diagrams

Visual representation of the arrangement of electrons in energy levels.

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Step by Step Problem Solving

Methodical approach to solving chemistry problems involving calculations.

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Periodic Table Organization

Elements are arranged by increasing atomic number, showing trends in properties.

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Chemical Properties of Nonmetals

Nonmetals generally have high ionization energy and high electronegativity.

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Ionization Energy Trend

Ionization energy increases across a period and decreases down a group.

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Group Trends

Similar properties observed in elements of the same group in the periodic table.

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Study Notes

Chemistry Unit 1 Recap

  • Unit Conversions: 1 nm = 1.00 x 10⁻⁹ m
  • Equations:
    • E = hv
    • c = 3.00 x 10⁸ m/s
    • h = 6.626 x 10⁻³⁴ J⋅s
    • E = hc/λ
    • c = λν

Problem Solving Steps (General Example)

  • Understand the Question: Identify the given information (variables) and what needs to be calculated (unknown variable)
  • Identify Unknown Variable: Determine what you are solving for—frequency (ν), energy (E), or wavelength (λ).
  • Choose the Correct Equation: Select the relevant equation from the provided equations (e.g. E =hv, E=hc/λ )
  • Identify Constants: Determine the values of any constants needed (like c and h)
  • Plug in Values and Solve: Substitute the known values into the equation and solve for the unknown variable.
  • Show Steps: Clearly show all steps of your calculations.

Problem 1: Frequency of Radiation

  • Given wavelength (λ) = 5.80 x 10⁻⁷ m
  • Unknown: Frequency (ν)
  • Equation: c = λν
  • Constants: c = 3.00 x 10⁸ m/s
  • Solve: Calculate ν by rearranging the equation: ν = c/λ; ν = (3.00 x 10⁸ m/s) / (5.80 x 10⁻⁷ m) = 5.17 x 10¹⁴ Hz

Problem 2: Energy of Light

  • Given wavelength (λ) = 4.25 x 10⁻⁷ m
  • Unknown: Energy (E)
  • Equation: E = hc/λ
  • Constants:
    • h = 6.626 x 10⁻³⁴ J⋅s
    • c = 3.00 x 10⁸ m/s
  • Solve: Calculate E by plugging in known values and solving the equation. E = (6.626 x 10⁻³⁴ J⋅s)(3.00 x 10⁸ m/s) / (4.25 x 10⁻⁷ m) = 4.68 x10⁻¹⁹ J.

Problem 3: Frequency of Light from Energy

  • Given energy (E) = 4.25 x 10⁻¹⁹ J
  • Unknown: Frequency (ν)
  • Equation: E = hv
  • Constants: h= 6.626 x 10⁻³⁴ J⋅s
  • Solve forν: ν = E/h = 4.25 x 10⁻¹⁹ J/ 6.626 x 10⁻³⁴ J⋅s = 6.42 x10¹⁴ Hz

Problem 4: Wavelength of Light from Energy

  • Given energy (E) = 6.15 x 10⁻¹⁹ J
  • Unknown: Wavelength (λ)
  • Equation: E=hc/λ
  • Constants: h, c
  • Solve for λ : λ = hc/E = (6.626 x 10⁻³⁴ J⋅s *3.00 x 10⁸ m/s) / (6.15 x 10⁻¹⁹ J) = 3.22 x10⁻⁷ m

Additional Concepts

  • Energy Level Diagrams: Diagrams illustrating energy levels of electrons in atoms. Transitions between energy levels correspond to absorption or emission of light.
  • Bohr Diagrams: Diagrams showing the structure of atoms, including the nucleus & electron distribution in energy levels.
  • Atomic Orbitals: Specific regions in space where electrons have a high probability of being found. (e.g. 1s, 2s, 2p, 3s, 3p, 3d, 4s, 4p).
  • Electron Configurations and Orbital Diagrams: Representations of the arrangement of electrons in atoms' orbitals.
  • Isoelectronic: Ions having the same electron configuration as a neutral noble gas (e.g. Ar).
  • Atomic Radius: The size of an atom. Trends include increase down a group and decrease across a period.
  • Ionization Energy: Energy required to remove an electron from an atom in the gaseous state. Trends in ionization increase across a period while decrease down a group.

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Description

Test your understanding of key concepts from Chemistry Unit 1. This quiz covers important unit conversions and equations needed to solve problems related to frequency, energy, and wavelength. Utilize the provided problem-solving steps to guide you through the calculations.

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