Chemistry Unit 1 & 2: Organic and Matter Properties

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Questions and Answers

Which of the following correctly describes an exothermic reaction?

  • Absorbs energy from the surroundings
  • Is a reaction that only occurs under high pressure
  • Releases energy in the form of heat (correct)
  • Always results in a temperature increase of the surroundings

Oxidizing agents are reduced in a redox reaction.

True (A)

What is the primary force that holds ionic solids together?

Electrostatic attraction between oppositely charged ions

The equation for calculating heat transfer is Q = mc______, where c represents the specific heat capacity.

<p>ΔT</p> Signup and view all the answers

Match the following types of solids with their properties:

<p>Ionic = High melting and boiling points, conducts electricity in solution Covalent Network = Very hard, high melting points, typically insoluble Metallic = Good conductors of electricity and heat, malleable Molecular = Lower melting points, can be volatile and soluble in nonpolar solvents</p> Signup and view all the answers

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Flashcards

Oxidation

The process of losing electrons by a substance during a chemical reaction.

Reduction

The process of gaining electrons by a substance during a chemical reaction.

Oxidizing Agent

A substance that causes another substance to be oxidized, while itself being reduced.

Reducing Agent

A substance that causes another substance to be reduced, while itself being oxidized.

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Cell potential (Ecell)

The difference in electrical potential between the two half-cells of an electrochemical cell. It indicates the potential difference that drives the flow of electrons.

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Study Notes

Unit 1: Organic Chemistry

  • Organic compounds: know different functional groups and how to draw/name them
  • Organic reactions: types and how to complete them
  • Properties of organic compounds: state, changes of state, solubility (relate to functional group and intermolecular forces)

Unit 2: Structure and Properties of Matter

  • Atomic history (Pauli, Schrodinger, Hund, Heisenberg, Aufbau)
  • Quantum numbers (n, l, ml, ms): define electron position in orbitals (relate to periodic table)
  • Drawing Lewis & VSEPR diagrams for molecules or ions, bond angles, AXE formula
  • Electron configurations of atoms and ions (complete and condensed)
  • Properties of different types of solids (ionic, molecular, covalent network, metallic) based on polarity and IMFs (intermolecular forces) and bonding
  • Intermolecular forces, VSEPR, bonding, polar molecules, electron configurations, crystalline solids
  • Quantum mechanics: energy level diagrams, electron configurations for any atom or ion
  • Explain hybridization of bonds in a molecule using energy level diagrams

Unit 3: Electrochemistry

  • Assigning oxidation numbers
  • Determine oxidizing/reducing agents, oxidation/reduction half-reactions
  • Redox table used to determine SOA (strong oxidizing agent), SRA (strong reducing agent), spontaneity, E°cell
  • Balancing Redox Equations: half-reaction method and/or oxidation number method (acidic or basic solutions).
  • Drawing and interpreting Electrochemical Cells (galvanic vs electrolytic, anode, cathode, electrolytes, direction of ion and electron flow), line notation

Unit 4: Thermochemistry and Rates of Reactions

  • Endothermic vs exothermic reactions
  • Calculating Q = mcΔt
  • Calculating Enthalpy Change ΔH: calorimetry (Styrofoam and flame calorimeter), enthalpies of formation, bond energies, molar enthalpy, Hess' Law
  • Factors affecting reaction rates (nature of reactants, concentration, surface area, temperature, catalyst) based on collision theory
  • Calculating rates of reaction (stoichiometric, instantaneous, average), rate order, rate law, k
  • Rate determining step, analyze a reaction mechanism
  • Drawing and interpreting Potential Energy graphs (activated complex, intermediates, Ea, reactants, products, enthalpy change)

Unit 5: Equilibrium Systems

  • Dynamic equilibrium
  • Calculating Keq, Q, Ksp, molar solubility
  • Apply LeChatelier's principle
  • Brønsted-Lowry vs. Arrhenius definitions of acids/bases, strong vs. weak acids/bases, conjugate acid-base pairs
  • Calculating pH/pOH, [H+], [OH-] (formulas given)

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