Chemistry Standard Solutions Quiz
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Questions and Answers

Which compound is used as a primary standard oxidant?

  • Potassium Iodate (correct)
  • Iodine
  • Sodium dichromate
  • Sodium thiosulphate
  • What is the approximate standard first prepared by dissolving a weight of iodine in Kl solution followed by completion to volume?

  • Standard sodium thiosulphate
  • Potassium Iodate
  • Sodium dichromate solution
  • Standard I2 solution (correct)
  • What is the reaction of iodate with potassium iodide in a weak acid medium (0.1-1 N HCl)?

  • $IO3- + I^- \rightarrow I3^-$
  • $IO3- + 6H+ + 6e^- \rightarrow 3H2O + I$
  • $2IO3- + 5I- + 6H^+ \rightarrow 3I2 + 3H2O$ (correct)
  • $IO3- + 6H+ + 4e^- \rightarrow 3H2O + I^+$
  • Why is sodium thiosulphate not a primary standard?

    <p>Due to the presence of water of crystallization</p> Signup and view all the answers

    How is the solution of Standard I2 solution standardized?

    <p>Against sodium thiosulphate using starch as indicator</p> Signup and view all the answers

    Study Notes

    Primary Standard Oxidant

    • Potassium iodate (KIO3) is used as a primary standard oxidant.

    Preparation of Standard I2 Solution

    • The standard I2 solution is prepared by dissolving a weighed amount of iodine in a KI solution, which is then diluted to a specific volume.

    Reaction of Iodate with Potassium Iodide

    • In a weak acid medium (0.1-1 N HCl), iodate reacts with potassium iodide to form iodine and water.

    Sodium Thiosulphate Limitation

    • Sodium thiosulphate is not a primary standard because it is not sufficiently stable and its composition can vary.

    Standardization of I2 Solution

    • The solution of standard I2 is standardized by titrating it against a standard thiosulphate solution.

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    Description

    Test your knowledge of standard solutions in chemistry with this quiz. Topics include the preparation and standardization of standard I2 solution and standard sodium thiosulphate solution.

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