Chemistry Solutions and Mole Concept
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Questions and Answers

What term describes a solution that has a large amount of solute?

  • Homogeneous Solution
  • Dilute Solution
  • Solid Solution
  • Concentrated Solution (correct)

What is the correct definition of solute?

  • Any substance in a solid state
  • The substance that dissolves another (correct)
  • The liquid component of a solution
  • A type of concentrated solution

Which of the following substances can act as a solvent?

  • NaOH
  • Salt
  • Sugar
  • Ethanol (correct)

Molarity (M) is expressed as which of the following?

<p>The number of moles of solute per liter of solution (A)</p> Signup and view all the answers

Which formula correctly represents Normality (N)?

<p>N = No. of equivalents / Volume (L) (B)</p> Signup and view all the answers

What does the term molecular weight refer to?

<p>The sum of the atomic weights of all atoms in a molecule (C)</p> Signup and view all the answers

What is the significance of the mole in chemistry?

<p>It standardizes the amount of substance in terms of particles (D)</p> Signup and view all the answers

What is the characteristic of a homogeneous mixture?

<p>It has a uniform composition throughout (A)</p> Signup and view all the answers

What is the equivalent weight of H2SO4 if its molecular weight is 98 g/mol?

<p>49 g/equiv (C)</p> Signup and view all the answers

Which formula correctly represents the relationship between ppm and molarity (M)?

<p>ppm = M x M.wt x 1000 (B)</p> Signup and view all the answers

In a dilution process, if the initial concentration (N1) is 2 N and the final volume (V2) is 200 mL, what is the initial volume (V1) if the final concentration (N2) is 1 N?

<p>100 mL (D)</p> Signup and view all the answers

What is the equivalent weight of NaOH?

<p>40 g/equiv (B)</p> Signup and view all the answers

What is the correct expression for calculating the equivalent weight of a salt such as CaCl2?

<p>Equivalent weight = M.Wt CaCl2 / 2 (D)</p> Signup and view all the answers

How is specific gravity defined?

<p>Ratio of the density of a solution to the density of an equal volume of water (C)</p> Signup and view all the answers

Given that the molecular weight of H3PO4 is 98 g/mol, what is its equivalent weight?

<p>32.67 g/equiv (D)</p> Signup and view all the answers

If the volume of a solution is 500 mL and the weight of the solute is 0.5 g, what is the concentration in ppm?

<p>1000 ppm (A)</p> Signup and view all the answers

What is the equivalent weight of sodium carbonate (Na2CO3)?

<p>53 gm/eq (A)</p> Signup and view all the answers

How much weight of sodium chloride (NaCl) is needed to prepare a solution of 58000 PPM in 200 ml of water?

<p>11.6 g (A)</p> Signup and view all the answers

What is the molarity of a 58000 PPM sodium chloride solution?

<p>1 M (A)</p> Signup and view all the answers

How can you determine the volume of a solution needed for a given concentration in PPM?

<p>Use the formula V(L) = weight(mg) / PPM (D)</p> Signup and view all the answers

What is the equivalent weight of sodium chloride (NaCl)?

<p>58 gm/eq (D)</p> Signup and view all the answers

In preparing a 2000 PPM solution of CaCl2 from 5 mg, how much volume is obtained?

<p>2.5 mL (C)</p> Signup and view all the answers

What is the molecular weight of ammonia (NH3)?

<p>17 gm/mol (D)</p> Signup and view all the answers

What weight of sodium bicarbonate is needed to prepare 0.25 L of a 1.6 N solution?

<p>14 gm (D)</p> Signup and view all the answers

What is the molarity of concentrated hydrochloric acid with 38% concentration and specific gravity of 1.19?

<p>12.5 M (B)</p> Signup and view all the answers

Which of the following is the correct formula used to determine the volume required when diluting a solution?

<p>M1 x V1 = M2 x V2 (C)</p> Signup and view all the answers

How many milliliters of concentrated sulfuric acid (94% concentration, density 1.831 g/cm³) are needed to prepare 1 liter of a 0.1 M solution?

<p>5.7 mL (D)</p> Signup and view all the answers

What is the normality of a 13% sulfuric acid solution with a specific gravity of 1.090?

<p>2.8 N (B)</p> Signup and view all the answers

If you want to prepare 500 mL of a 0.1 N K2Cr2O7 solution from a 0.250 N solution, what is the required volume of the concentrated solution?

<p>200 mL (D)</p> Signup and view all the answers

What is the molarity of a solution containing 10 gm of H2SO4 in 250 ml?

<p>0.4 M (C)</p> Signup and view all the answers

What is the molarity of a concentrated sulfuric acid solution if its density is 1.831 g/cm³ and it is 94% concentrated?

<p>17.5 M (C)</p> Signup and view all the answers

What is the normality of the NaOH solution containing 6 gm in 500 ml?

<p>0.3 N (C)</p> Signup and view all the answers

When preparing a solution, if the required concentration is 0.2 M for a volume of 0.5 L, what is the equation used to find the volume of the concentrated hydrochloric acid needed?

<p>V1 = (0.2 x 500) / 12.5 (A)</p> Signup and view all the answers

What is the molarity of a solution with 25 gm of AgNO3 in 1L of solution?

<p>0.14 M (B)</p> Signup and view all the answers

The molar weight of sulfuric acid (H2SO4) is calculated as which of the following?

<p>98 g/mol (B)</p> Signup and view all the answers

What is the normality of the AgNO3 solution if the molarity is 0.14 M?

<p>0.14 N (B)</p> Signup and view all the answers

How many grams of NaCl are needed to prepare a 0.2 N solution in 250 ml of water?

<p>5.85 g (D)</p> Signup and view all the answers

What volume of concentrated sulphuric acid is needed to prepare 0.6 L of a 0.2 M solution?

<p>67.99 ml (A)</p> Signup and view all the answers

What is the normality of the KCl solution prepared as 0.3 N in 500 ml?

<p>0.3 N (C)</p> Signup and view all the answers

What is the final concentration in molarity of a solution if 100 mL of 0.5 N AgNO3 is diluted to make a 0.3 N solution?

<p>0.3 M (C)</p> Signup and view all the answers

Flashcards

Solution

A homogeneous mixture of two or more substances, where the concentration of each substance can vary within limits.

Solute

The substance dissolved in a solution. Examples: Sugar, salt, NaOH, Na2CO3

Solvent

The substance that dissolves another substance to form a solution. Examples: Water, acetone, ether, ethanol.

Mole

A fundamental unit of mass used by chemists. This term refers to a large number of elementary particles (atoms, molecules, ions, electrons, etc.) of any substance.

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Molecular Weight (M.wt)

The sum of the atomic weights of all the atoms in a molecule of a substance. Measured in (grams/mol).

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Molarity (M)

The concentration of a solution expressed as the number of moles of solute per liter of solution. It's effectively how much solute is packed into a given volume.

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Normality (N)

The concentration of a solution expressed as the number of gram equivalents of solute per liter of solution.

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Gram Equivalent

A unit used to describe the amount of a substance that can react with a certain amount of another substance.

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Equivalent weight of an Acid

The equivalent weight of an acid is calculated by dividing its molecular weight by the number of replaceable hydrogen ions (H+) it can donate in a reaction.

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Equivalent weight of a Base

The equivalent weight of a base is calculated by dividing its molecular weight by the number of replaceable hydroxide ions (OH-) it can donate in a reaction.

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Equivalent weight of a Salt

The equivalent weight of a salt is calculated by dividing its molecular weight by the total positive or negative charge of its ions.

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Part per million (ppm)

Part per million (ppm) is a unit of concentration that represents the number of milligrams of solute per liter of solution.

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Relationship between M, N, and ppm

The relationship between molarity (M), normality (N), and ppm is: ppm = M x M.wt x 1000 or ppm = N x Eq.wt x 1000. It indicates how to convert between different concentration units.

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Relationship between M and N

Normality (N) is directly proportional to molarity (M) and the number of replaceable ions (n): N = n x M. N is especially useful when dealing with reactions involving acid-base titrations.

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Density

Density is the weight of a substance per unit volume, typically expressed as grams per milliliter (gm/mL) or grams per cubic centimeter (gm/cm3). It tells us how compact a substance is.

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Specific Gravity

Specific gravity is a ratio that compares the density of a substance to the density of water at a specific temperature (usually 4°C). It indicates how much denser a substance is compared to water.

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Percent by mass (%)

The number of grams of a substance dissolved in 100g of the solvent.

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Dilution Equation (M1V1 = M2V2)

A mathematical formula used to calculate the volume of concentrated solution needed for dilution.

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Calculating Weight of Solute

The mass of a solute that dissolves in a specific volume of solvent to create a solution of a known concentration.

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NaCl

The chemical formula for sodium chloride, a common salt.

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Equivalent Weight (Eq.Wt)

The weight of one equivalent of a substance. It's derived by dividing the molecular weight by the number of replaceable hydrogen ions or hydroxide ions.

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Standard Solution

A solution with a known concentration that is used to determine the concentration of an unknown solution.

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Number of replaceable ions (n)

The number of replaceable ions (n) in a molecule is the number of ions that can participate in a chemical reaction.

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Equivalent weight

The equivalent weight of a substance is its molecular weight divided by the number of replaceable ions (n). It quantifies the amount that reacts with a specific quantity of another substance.

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Study Notes

Solution Definitions

  • A solution is a homogeneous mixture of two or more substances; concentrations can vary within limits.
  • Concentrated solutions contain a high amount of solute.
  • Dilute solutions contain a small amount of solute.
  • A solute dissolves in a solvent to form a solution.

Components of a Solution

  • Solute: The substance that dissolves in the solution (e.g., sugar, salt, NaOH, Na₂CO₃).
  • Solvent: The substance that dissolves the solute to form a solution (e.g., water, acetone, ether, ethanol).
  • Solution: A mixture of two or more pure substances where one substance is dissolved in another homogeneously. A solution has the same concentration throughout.

Mole Concept

  • Mole: A fundamental unit of mass used by chemists to represent a large number of elementary particles (atoms, molecules, ions, electrons, etc.) of any substance.
  • Mole = weight (gram) / Molecular Weight (gram/mol)

Molecular Weight

  • Molecular Weight (M.wt): The sum of the atomic weights of all atoms in a molecule of a substance, measured in gram/mol.
  • Examples provided include CH₄, SO₃, NH₃, H₂O, (NH₄)₂CrO₄, and Ba(NO₃)₂ with their calculated molecular weights.

Molarity (M)

  • Molarity (M): The concentration of a solution expressed as the number of moles of solute per liter of solution.
  • M = Mole / Volume(L)
  • M = (weight × 1000) / (M.Wt × volume(ml))

Normality (N)

  • Normality (N): The concentration of a solution expressed as the number of gram equivalents of solute per liter of solution.
  • N = No. of equivalents (eq) / Volume (L)
  • N = (weight × 1000) / (eq. wt × volume(ml))

Equivalent Weights

  • Acid: eq.wt acid = M.Wt acid / No. of active H⁺. Examples include H₂SO₄, H₃PO₄, and HCl.
  • Base: eq.wt base = M.Wt base / No. of active OH⁻. Examples include NaOH and Ca(OH)₂.
  • Salts: eq.wt = M.Wt / (number of cation or anion * its charge). Examples include NaCl and CaCl₂.

Part Per Million (ppm)

  • ppm: Milligrams of solute per liter of solution.
  • ppm = wt(mg) / V(L)
  • ppm = wt(g) × 10⁶ / V(mL)

Relationship Between Molarity (M), Normality (N), and ppm

  • ppm = M × M.wt × 1000
  • ppm = N × Eq.wt × 1000
  • N = n × M (where n = number of H⁺ for acids or number of OH⁻ for bases).

Density and Specific Gravity

  • Density: Weight per unit volume at a specified temperature (usually g/mL or g/cm³).
  • Specific Gravity (sp. gr.): The ratio of the mass of a substance to the mass of an equal volume of water at a specific temperature (often 20°C or 4°C).
  • M = (% × density × 1000) / M.wt; and M = (% × sp. gr. × 1000) / M.wt

Dilution

  • Dilution: The process of adding more solvent to a solution to lower its concentration. The same amount of solute is present, but it's distributed in a larger volume of solvent.
  • N₁ × V₁ = N₂ × V₂
  • M₁ × V₁ = M₂ × V₂

Examples of Preparing Standard Solutions (calculations provided)

  • Examples demonstrate the calculations for preparing various standard solutions (e.g., NaOH, Na₂CO₃, NaCl, H₂SO₄, HCl, and others).

Homework Problems

  • Homework problems are presented requiring the calculation of molarity, normality, or volumes for solutions (e.g., specific concentration and volume needed).

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General Chemistry Lec 4+5 PDF

Description

Test your knowledge on the definitions and components of solutions, as well as the mole concept in chemistry. This quiz covers essential terms such as solute, solvent, and molecular weight. Perfect for those studying chemistry at any level!

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