Podcast
Questions and Answers
What can be used to prevent a catalyst or a reactant from reacting?
What can be used to prevent a catalyst or a reactant from reacting?
- Poisonous compounds like cyanide (correct)
- A reactant that increases pressure
- High temperatures
- Concentration of gaseous reactants
Which factor primarily affects the rate of heterogeneous reactions?
Which factor primarily affects the rate of heterogeneous reactions?
- Surface area (correct)
- Temperature
- Concentration of reactants
- Pressure
What effect does increasing the surface area have on a solid reactant?
What effect does increasing the surface area have on a solid reactant?
- It accelerates the reaction rate. (correct)
- It slows down the reaction rate.
- It changes the phase of the reactant.
- It has no effect on the reaction rate.
Which statement is true regarding gaseous reactants?
Which statement is true regarding gaseous reactants?
What impact does temperature have on reaction rates?
What impact does temperature have on reaction rates?
What is the primary reason for measuring mass changes in reactions involving solids?
What is the primary reason for measuring mass changes in reactions involving solids?
In the reaction of solid magnesium with hydrochloric acid, which component's mass would decrease if magnesium is periodically removed?
In the reaction of solid magnesium with hydrochloric acid, which component's mass would decrease if magnesium is periodically removed?
Which of the following statements about measuring ionic concentrations is true?
Which of the following statements about measuring ionic concentrations is true?
What effect does the reaction between magnesium and hydrobromic acid have on the concentration of hydrogen ions?
What effect does the reaction between magnesium and hydrobromic acid have on the concentration of hydrogen ions?
Why is it impractical to measure the masses of aqueous substances separately?
Why is it impractical to measure the masses of aqueous substances separately?
In a reaction producing gas, how can the mass change be measured accurately?
In a reaction producing gas, how can the mass change be measured accurately?
What is the impact of a spectator ion on the overall reaction rate?
What is the impact of a spectator ion on the overall reaction rate?
What is indicated by the rate of a reaction involving changes in molar concentration?
What is indicated by the rate of a reaction involving changes in molar concentration?
What is the correct formula to express the rate of a reaction?
What is the correct formula to express the rate of a reaction?
In a reaction, if 20 g of H2SO4 are consumed in 16 minutes, what is the average reaction rate?
In a reaction, if 20 g of H2SO4 are consumed in 16 minutes, what is the average reaction rate?
What color change occurs when Cu(NO3)2 is reacted with Zn?
What color change occurs when Cu(NO3)2 is reacted with Zn?
When converting grams of Mg to moles, what must you consider?
When converting grams of Mg to moles, what must you consider?
What happens to the temperature in an exothermic reaction?
What happens to the temperature in an exothermic reaction?
How do you represent a reaction in ionic form?
How do you represent a reaction in ionic form?
In a sealed container, what effect does an increase in moles of gas in the products have on pressure?
In a sealed container, what effect does an increase in moles of gas in the products have on pressure?
What would be a correct approach to compare rates using a balanced equation?
What would be a correct approach to compare rates using a balanced equation?
If the reaction rate of Mg is 0.034 g/s, how many grams would be used in 6 minutes?
If the reaction rate of Mg is 0.034 g/s, how many grams would be used in 6 minutes?
When considering the pressure changes in a reaction at constant volume, what establishes whether pressure will change?
When considering the pressure changes in a reaction at constant volume, what establishes whether pressure will change?
In a reaction producing 4CO2 and 6H2O from 2C2H6 and 7O2, how many moles of CO2 are produced per mole of C2H6 consumed?
In a reaction producing 4CO2 and 6H2O from 2C2H6 and 7O2, how many moles of CO2 are produced per mole of C2H6 consumed?
What can be used to quantitatively measure the color intensity of a reaction?
What can be used to quantitatively measure the color intensity of a reaction?
Which of the following is true regarding the time units in a rate equation?
Which of the following is true regarding the time units in a rate equation?
What occurs to the volume of a balloon when more gas is produced in a reaction at constant pressure?
What occurs to the volume of a balloon when more gas is produced in a reaction at constant pressure?
What is the net ionic equation of the reaction between Cu(NO3)2 and Zn?
What is the net ionic equation of the reaction between Cu(NO3)2 and Zn?
In the example of NO2 and CO reacting, what is the change in pressure observed when equal moles of gas are present in reactants and products?
In the example of NO2 and CO reacting, what is the change in pressure observed when equal moles of gas are present in reactants and products?
What is a reaction intermediate?
What is a reaction intermediate?
Which statement accurately describes the activated complex?
Which statement accurately describes the activated complex?
What does a higher bump in a potential energy diagram indicate?
What does a higher bump in a potential energy diagram indicate?
What does the vertical distance from reactants to the highest peak in a potential energy diagram represent?
What does the vertical distance from reactants to the highest peak in a potential energy diagram represent?
In a reaction mechanism, what can be said about intermediates?
In a reaction mechanism, what can be said about intermediates?
What will always be true about the rate-determining step (RDS) in a reaction mechanism?
What will always be true about the rate-determining step (RDS) in a reaction mechanism?
Which step would be considered the fastest step in a reaction mechanism?
Which step would be considered the fastest step in a reaction mechanism?
What would characterize an exothermic reaction in terms of the potential energy diagram?
What would characterize an exothermic reaction in terms of the potential energy diagram?
What effect does a catalyst have on the activation energy of a reaction?
What effect does a catalyst have on the activation energy of a reaction?
In a catalyzed reaction, how does the energy required for the reverse reaction compare to the uncatalyzed reaction?
In a catalyzed reaction, how does the energy required for the reverse reaction compare to the uncatalyzed reaction?
Which statement is true regarding the change in potential energy (PE) of reactants and products when a catalyst is introduced?
Which statement is true regarding the change in potential energy (PE) of reactants and products when a catalyst is introduced?
What is the typical effect of a catalyst on the overall reaction mechanism?
What is the typical effect of a catalyst on the overall reaction mechanism?
What is implied by an overall exothermic reaction in terms of reaction energy?
What is implied by an overall exothermic reaction in terms of reaction energy?
In a potential energy diagram for a two-step reaction mechanism, which step is characterized as being fast?
In a potential energy diagram for a two-step reaction mechanism, which step is characterized as being fast?
If a catalyst is added to a system with an uncatalyzed reaction, what happens to the uncatalyzed reaction?
If a catalyst is added to a system with an uncatalyzed reaction, what happens to the uncatalyzed reaction?
What is the role of a catalyst in the context of providing an alternative mechanism?
What is the role of a catalyst in the context of providing an alternative mechanism?
Flashcards
Reaction Kinetics
Reaction Kinetics
The study of how fast chemical reactions occur and the factors that influence their speed.
Reaction Rate
Reaction Rate
The change in the amount (grams, moles, liters, etc.) of a reactant or product over time.
Ionic Form
Ionic Form
The process of breaking down aqueous compounds (those dissolved in water) into their individual ions.
Comparing Rates using Balanced Equations
Comparing Rates using Balanced Equations
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Molar Volume of a Gas (STP)
Molar Volume of a Gas (STP)
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Standard Temperature and Pressure (STP)
Standard Temperature and Pressure (STP)
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Mole
Mole
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Molar Mass
Molar Mass
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Color Change Reaction
Color Change Reaction
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Exothermic Reaction
Exothermic Reaction
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Endothermic Reaction
Endothermic Reaction
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Calorimeter
Calorimeter
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Pressure Increase Reaction
Pressure Increase Reaction
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Pressure Decrease Reaction
Pressure Decrease Reaction
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Reaction that Increases MOG
Reaction that Increases MOG
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Reaction that Decreases MOG
Reaction that Decreases MOG
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Rate of reaction using mass change (solid reactant)
Rate of reaction using mass change (solid reactant)
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Rate of reaction using mass change (gas product)
Rate of reaction using mass change (gas product)
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Rate of reaction using specific ion concentration
Rate of reaction using specific ion concentration
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Spectator Ion
Spectator Ion
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Rate of reaction using specific ion concentration change
Rate of reaction using specific ion concentration change
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Spectrophotometer to determine ion concentration
Spectrophotometer to determine ion concentration
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Titration for ion concentration determination
Titration for ion concentration determination
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Rate of reaction by analyzing ion concentration change
Rate of reaction by analyzing ion concentration change
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Surface Area and Heterogeneous Reactions
Surface Area and Heterogeneous Reactions
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Catalyst Inhibitor
Catalyst Inhibitor
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Factors Affecting Reaction Rate
Factors Affecting Reaction Rate
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Heterogeneous Reaction
Heterogeneous Reaction
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Concentration and Reaction Rate
Concentration and Reaction Rate
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Reaction Intermediate
Reaction Intermediate
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Activated Complex
Activated Complex
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Rate Determining Step
Rate Determining Step
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Activation Energy (Ea) for Overall Reaction
Activation Energy (Ea) for Overall Reaction
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Potential Energy Diagram for a Reaction Mechanism
Potential Energy Diagram for a Reaction Mechanism
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Catalyst
Catalyst
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Rate-Determining Step (RDS)
Rate-Determining Step (RDS)
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Activation Energy (Ea)
Activation Energy (Ea)
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Enthalpy Change (ΔH)
Enthalpy Change (ΔH)
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Activation Energy (Ea) for the reverse reaction
Activation Energy (Ea) for the reverse reaction
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Enthalpy Change (ΔH) for the reverse reaction
Enthalpy Change (ΔH) for the reverse reaction
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Study Notes
Introduction to Reaction Kinetics
- Reaction kinetics is the study of reaction rates and factors affecting those rates.
- Reaction rate is defined as the amount of reactant or product over time.
- Time units are always in the denominator of the rate equation.
Calculations Involving Reaction Rates
- Use molar mass to convert between grams and moles.
- Use 22.4 L/mol for gas conversions at standard temperature and pressure (STP).
- Ensure units cancel out correctly when converting.
- Follow the general approach of writing a plan for calculations.
Comparing Rates Using Balanced Equations
- Use ratios of coefficients in a balanced equation.
- Use mol/s, not g/s when comparing rates of consumption or production.
Methods of Measuring Reaction Rates
- Properties monitored to determine reaction rates include:
- Color changes (intensity measured with a spectrophotometer)
- Temperature changes (measured in a calorimeter)
- Pressure changes (constant volume)
- Volume changes (constant pressure)
- Mass changes
- Changes in molar concentration of specific ions
- Changes in pH
Factors Affecting Reaction Rates
-
Temperature: Higher temperatures generally increase reaction rates.
-
Concentration: Higher concentrations generally increase reaction rates (more likely collisions with adequate energy)
-
Nature of reactants: Strong bonds are generally harder to break, resulting in slower reactions
-
Pressure: Increased pressure affects reactions with gases, increasing rates.
-
Surface area: Increasing surface area generally increases reaction rate
-
Catalyst: Adding a catalyst speeds up reactions by lowering activation energy.
Reaction Rates and Collision Theory
- Reactions require collisions between molecules with sufficient kinetic energy to break bonds and form new ones.
- Increased temperature means higher average kinetic energy among molecules leading to more collisions per unit time.
- Concentration of reactants influences the chance of collisions, increasing with more reactants.
- The number and kinds of bonds affect reaction time
Enthalpy Changes in Chemical Reactions
- Enthalpy (H) is heat content of a substance.
- Enthalpy change (ΔH) is the heat absorbed or released in a reaction at constant pressure.
- In an exothermic reaction, ΔH is negative (heat released).
- In an endothermic reaction, ΔH is positive (heat absorbed)
Kinetic Energy Distributions
- Different molecules have different kinetic energies.
- A distribution curve shows the relative number of molecules with specific kinetic energy values.
- High energy molecules react faster
- Increases in temperature increase the fraction of high-energy molecules
- The distribution curves' total area under the curve does not change
Activation Energies
- Activation energy (Ea) is the minimum energy molecules need for a collision to result in a reaction.
- Activation energy is influenced by reaction nature
- Adding a catalyst lowers the activation energy required, increasing the reaction rate
Reaction Mechanisms
- Reaction mechanisms are the steps involved in chemical reactions.
- Intermediates are formed during the process.
- The slowest step in the reaction mechanism is known as the rate-determining step, which is the rate limiting step and represents the overall limiting step of the reaction rate
- Catalysts work by creating alternate pathways with lower activation energy.
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