Chemistry Reactions and Rates Quiz

Choose a study mode

Play Quiz
Study Flashcards
Spaced Repetition
Chat to Lesson

Podcast

Play an AI-generated podcast conversation about this lesson

Questions and Answers

What can be used to prevent a catalyst or a reactant from reacting?

  • Poisonous compounds like cyanide (correct)
  • A reactant that increases pressure
  • High temperatures
  • Concentration of gaseous reactants

Which factor primarily affects the rate of heterogeneous reactions?

  • Surface area (correct)
  • Temperature
  • Concentration of reactants
  • Pressure

What effect does increasing the surface area have on a solid reactant?

  • It accelerates the reaction rate. (correct)
  • It slows down the reaction rate.
  • It changes the phase of the reactant.
  • It has no effect on the reaction rate.

Which statement is true regarding gaseous reactants?

<p>They are usually faster to react than solids. (B)</p> Signup and view all the answers

What impact does temperature have on reaction rates?

<p>It affects the rate of all reactions. (B)</p> Signup and view all the answers

What is the primary reason for measuring mass changes in reactions involving solids?

<p>To track the consumption of a single solid reactant (D)</p> Signup and view all the answers

In the reaction of solid magnesium with hydrochloric acid, which component's mass would decrease if magnesium is periodically removed?

<p>Mass of magnesium (C)</p> Signup and view all the answers

Which of the following statements about measuring ionic concentrations is true?

<p>Concentration can be monitored by titration of periodic samples. (A)</p> Signup and view all the answers

What effect does the reaction between magnesium and hydrobromic acid have on the concentration of hydrogen ions?

<p>The concentration of hydrogen ions decreases. (A)</p> Signup and view all the answers

Why is it impractical to measure the masses of aqueous substances separately?

<p>Aqueous substances are mostly water, complicating the measurement. (C)</p> Signup and view all the answers

In a reaction producing gas, how can the mass change be measured accurately?

<p>By subtracting the initial mass from the final mass of the container and contents (C)</p> Signup and view all the answers

What is the impact of a spectator ion on the overall reaction rate?

<p>It does not change the concentration during the reaction. (C)</p> Signup and view all the answers

What is indicated by the rate of a reaction involving changes in molar concentration?

<p>The speed at which reactants are transformed into products (A)</p> Signup and view all the answers

What is the correct formula to express the rate of a reaction?

<p>rate = Δ amount / Δ time (D)</p> Signup and view all the answers

In a reaction, if 20 g of H2SO4 are consumed in 16 minutes, what is the average reaction rate?

<p>0.833 g/min (C)</p> Signup and view all the answers

What color change occurs when Cu(NO3)2 is reacted with Zn?

<p>The blue color fades as reaction progresses (A)</p> Signup and view all the answers

When converting grams of Mg to moles, what must you consider?

<p>The molar mass of Mg (D)</p> Signup and view all the answers

What happens to the temperature in an exothermic reaction?

<p>The temperature of the surroundings increases (B)</p> Signup and view all the answers

How do you represent a reaction in ionic form?

<p>Dissociate all aqueous compounds (B)</p> Signup and view all the answers

In a sealed container, what effect does an increase in moles of gas in the products have on pressure?

<p>Pressure will increase (A)</p> Signup and view all the answers

What would be a correct approach to compare rates using a balanced equation?

<p>Use coefficient ratios based on moles (C)</p> Signup and view all the answers

If the reaction rate of Mg is 0.034 g/s, how many grams would be used in 6 minutes?

<p>12.24 g (B)</p> Signup and view all the answers

When considering the pressure changes in a reaction at constant volume, what establishes whether pressure will change?

<p>The number of moles of gas in the reactants versus products (D)</p> Signup and view all the answers

In a reaction producing 4CO2 and 6H2O from 2C2H6 and 7O2, how many moles of CO2 are produced per mole of C2H6 consumed?

<p>4 moles (D)</p> Signup and view all the answers

What can be used to quantitatively measure the color intensity of a reaction?

<p>A spectrophotometer (C)</p> Signup and view all the answers

Which of the following is true regarding the time units in a rate equation?

<p>Time units are always in the denominator. (D)</p> Signup and view all the answers

What occurs to the volume of a balloon when more gas is produced in a reaction at constant pressure?

<p>The volume will increase (B)</p> Signup and view all the answers

What is the net ionic equation of the reaction between Cu(NO3)2 and Zn?

<p>Cu(aq) + Zn(s) → Zn(aq) + Cu(s) (D)</p> Signup and view all the answers

In the example of NO2 and CO reacting, what is the change in pressure observed when equal moles of gas are present in reactants and products?

<p>Pressure will not change (B)</p> Signup and view all the answers

What is a reaction intermediate?

<p>A species that is formed and used up in a reaction. (B)</p> Signup and view all the answers

Which statement accurately describes the activated complex?

<p>It is a very unstable and short-lived structure. (C)</p> Signup and view all the answers

What does a higher bump in a potential energy diagram indicate?

<p>A higher activation energy for the step. (B)</p> Signup and view all the answers

What does the vertical distance from reactants to the highest peak in a potential energy diagram represent?

<p>The activation energy for the forward overall reaction. (C)</p> Signup and view all the answers

In a reaction mechanism, what can be said about intermediates?

<p>They are formed in one step and consumed in another. (D)</p> Signup and view all the answers

What will always be true about the rate-determining step (RDS) in a reaction mechanism?

<p>It occurs at the highest energy level. (B)</p> Signup and view all the answers

Which step would be considered the fastest step in a reaction mechanism?

<p>The step with the lowest activation energy. (B)</p> Signup and view all the answers

What would characterize an exothermic reaction in terms of the potential energy diagram?

<p>The energy of products is lower than that of reactants. (A)</p> Signup and view all the answers

What effect does a catalyst have on the activation energy of a reaction?

<p>It lowers the activation energy. (D)</p> Signup and view all the answers

In a catalyzed reaction, how does the energy required for the reverse reaction compare to the uncatalyzed reaction?

<p>It is lower than the activation energy of the uncatalyzed reaction. (B)</p> Signup and view all the answers

Which statement is true regarding the change in potential energy (PE) of reactants and products when a catalyst is introduced?

<p>The PE of reactants and products remains unchanged. (A)</p> Signup and view all the answers

What is the typical effect of a catalyst on the overall reaction mechanism?

<p>It usually involves more steps with a lower activation energy. (B)</p> Signup and view all the answers

What is implied by an overall exothermic reaction in terms of reaction energy?

<p>The energy of products is lower than that of reactants. (A)</p> Signup and view all the answers

In a potential energy diagram for a two-step reaction mechanism, which step is characterized as being fast?

<p>The first step of the mechanism. (C)</p> Signup and view all the answers

If a catalyst is added to a system with an uncatalyzed reaction, what happens to the uncatalyzed reaction?

<p>It continues at its own slow rate. (B)</p> Signup and view all the answers

What is the role of a catalyst in the context of providing an alternative mechanism?

<p>To allow the reaction to proceed with a lower activation energy. (C)</p> Signup and view all the answers

Flashcards

Reaction Kinetics

The study of how fast chemical reactions occur and the factors that influence their speed.

Reaction Rate

The change in the amount (grams, moles, liters, etc.) of a reactant or product over time.

Ionic Form

The process of breaking down aqueous compounds (those dissolved in water) into their individual ions.

Comparing Rates using Balanced Equations

Using the coefficients from a balanced chemical equation to compare the rates of consumption or production of different reactants and products.

Signup and view all the flashcards

Molar Volume of a Gas (STP)

The volume occupied by one mole of any gas at standard temperature and pressure (STP).

Signup and view all the flashcards

Standard Temperature and Pressure (STP)

A fixed set of conditions: 0°C (273 K) and 1 atm pressure.

Signup and view all the flashcards

Mole

A quantity expressing the number of particles in a substance.

Signup and view all the flashcards

Molar Mass

The mass of one mole of a substance.

Signup and view all the flashcards

Color Change Reaction

A chemical reaction where the color of a solution changes over time. This change is monitored by a spectrophotometer, which measures the intensity of light absorbed by the solution.

Signup and view all the flashcards

Exothermic Reaction

A reaction that releases heat into the surroundings, causing the temperature to increase.

Signup and view all the flashcards

Endothermic Reaction

A reaction that absorbs heat from the surroundings, causing the temperature to decrease.

Signup and view all the flashcards

Calorimeter

A container used to measure the heat change in a chemical reaction. It helps isolate the reaction from the environment to accurately measure temperature changes.

Signup and view all the flashcards

Pressure Increase Reaction

A reaction that increases the pressure of a closed container.

Signup and view all the flashcards

Pressure Decrease Reaction

A reaction that decreases the pressure of a closed container.

Signup and view all the flashcards

Reaction that Increases MOG

A reaction that produces more gas molecules than it consumes.

Signup and view all the flashcards

Reaction that Decreases MOG

A reaction that consumes more gas molecules than it produces.

Signup and view all the flashcards

Rate of reaction using mass change (solid reactant)

A method to determine reaction rate by measuring the mass of a solid reactant used up over time. This is suitable when one solid reactant gets consumed, and its mass can be readily measured.

Signup and view all the flashcards

Rate of reaction using mass change (gas product)

A technique for measuring the rate of a reaction where a gas is produced. The mass of the container and its contents is measured over time, reflecting the escape of the gas.

Signup and view all the flashcards

Rate of reaction using specific ion concentration

The change in concentration of a specific ion over time, specifically measured using the molar concentration of that ion.

Signup and view all the flashcards

Spectator Ion

Ions that remain unchanged throughout a chemical reaction. They are not involved in forming new substances.

Signup and view all the flashcards

Rate of reaction using specific ion concentration change

Analyzing the change in concentration of a specific ion over time, particularly useful when a substance's concentration is difficult to measure directly.

Signup and view all the flashcards

Spectrophotometer to determine ion concentration

A technique that utilizes a spectrophotometer to monitor and measure the change in concentration of a specific ion over time, providing valuable insight into the reaction rate.

Signup and view all the flashcards

Titration for ion concentration determination

The process of taking periodic samples of a reaction mixture and analyzing them to determine the concentration of a specific ion using techniques like titration.

Signup and view all the flashcards

Rate of reaction by analyzing ion concentration change

A technique for determining the rate of a reaction by analyzing the change in concentration of a specific ion over time, using methods like spectrophotometry or titration.

Signup and view all the flashcards

Surface Area and Heterogeneous Reactions

The rate of a heterogeneous reaction is directly proportional to the surface area of the solid reactant. More surface area allows for more reactant molecules to interact with the other phase.

Signup and view all the flashcards

Catalyst Inhibitor

A substance that inhibits the rate of a chemical reaction without being consumed in the process. Examples include poisons, antibiotics, and sunscreens.

Signup and view all the flashcards

Factors Affecting Reaction Rate

The rate of a chemical reaction is affected by factors like temperature, concentration, and surface area. Each factor influences the rate in a specific way.

Signup and view all the flashcards

Heterogeneous Reaction

Chemical reactions that involve reactants in different physical states (e.g., solid and liquid) are called heterogeneous reactions. The reaction only occurs at the interface, or surface, between these phases.

Signup and view all the flashcards

Concentration and Reaction Rate

The rate of a chemical reaction is influenced by the concentration of the reactants. Higher concentration generally leads to a faster reaction rate.

Signup and view all the flashcards

Reaction Intermediate

A species that is produced in an earlier step of a reaction mechanism and then used up in a later step. It appears on the right side of one step and on the left side of another step.

Signup and view all the flashcards

Activated Complex

The highest energy point on the potential energy diagram for a reaction. It represents the transition state where bonds are breaking and forming.

Signup and view all the flashcards

Rate Determining Step

The step in a reaction mechanism that has the highest activation energy (Ea). It is the slowest step and determines the overall rate of the reaction.

Signup and view all the flashcards

Activation Energy (Ea) for Overall Reaction

The difference in potential energy between the reactants and the transition state of the rate-determining step.

Signup and view all the flashcards

Potential Energy Diagram for a Reaction Mechanism

A reaction mechanism with multiple steps, each with its own activation energy. The steps are shown as bumps on the potential energy diagram.

Signup and view all the flashcards

Catalyst

A species that is present in the starting material (reactants) and is also present in the final product. It does not appear as a reaction intermediate.

Signup and view all the flashcards

Rate-Determining Step (RDS)

A chemical reaction that involves multiple steps, with one step being significantly slower than the others. This slowest step determines the overall rate of the reaction.

Signup and view all the flashcards

Activation Energy (Ea)

The minimum amount of energy required for reactants to overcome the energy barrier and form products. It's like the 'hill' that reactants need to climb to become products.

Signup and view all the flashcards

Enthalpy Change (ΔH)

The energy difference between the reactants and products of a reaction. It tells us whether the reaction releases or absorbs energy.

Signup and view all the flashcards

Activation Energy (Ea) for the reverse reaction

The minimum amount of energy required for reactants to overcome the energy barrier and form products in the reverse reaction. It's the 'hill' that products need to climb to become reactants.

Signup and view all the flashcards

Enthalpy Change (ΔH) for the reverse reaction

The energy change for the reverse reaction taking the products back to reactants. It's the negative of ΔH for the forward reaction.

Signup and view all the flashcards

Study Notes

Introduction to Reaction Kinetics

  • Reaction kinetics is the study of reaction rates and factors affecting those rates.
  • Reaction rate is defined as the amount of reactant or product over time.
  • Time units are always in the denominator of the rate equation.

Calculations Involving Reaction Rates

  • Use molar mass to convert between grams and moles.
  • Use 22.4 L/mol for gas conversions at standard temperature and pressure (STP).
  • Ensure units cancel out correctly when converting.
  • Follow the general approach of writing a plan for calculations.

Comparing Rates Using Balanced Equations

  • Use ratios of coefficients in a balanced equation.
  • Use mol/s, not g/s when comparing rates of consumption or production.

Methods of Measuring Reaction Rates

  • Properties monitored to determine reaction rates include:
    • Color changes (intensity measured with a spectrophotometer)
    • Temperature changes (measured in a calorimeter)
    • Pressure changes (constant volume)
    • Volume changes (constant pressure)
    • Mass changes
    • Changes in molar concentration of specific ions
    • Changes in pH

Factors Affecting Reaction Rates

  • Temperature: Higher temperatures generally increase reaction rates.

  • Concentration: Higher concentrations generally increase reaction rates (more likely collisions with adequate energy)

  • Nature of reactants: Strong bonds are generally harder to break, resulting in slower reactions

  • Pressure: Increased pressure affects reactions with gases, increasing rates.

  • Surface area: Increasing surface area generally increases reaction rate

  • Catalyst: Adding a catalyst speeds up reactions by lowering activation energy.

Reaction Rates and Collision Theory

  • Reactions require collisions between molecules with sufficient kinetic energy to break bonds and form new ones.
  • Increased temperature means higher average kinetic energy among molecules leading to more collisions per unit time.
  • Concentration of reactants influences the chance of collisions, increasing with more reactants.
  • The number and kinds of bonds affect reaction time

Enthalpy Changes in Chemical Reactions

  • Enthalpy (H) is heat content of a substance.
  • Enthalpy change (ΔH) is the heat absorbed or released in a reaction at constant pressure.
  • In an exothermic reaction, ΔH is negative (heat released).
  • In an endothermic reaction, ΔH is positive (heat absorbed)

Kinetic Energy Distributions

  • Different molecules have different kinetic energies.
  • A distribution curve shows the relative number of molecules with specific kinetic energy values.
    • High energy molecules react faster
    • Increases in temperature increase the fraction of high-energy molecules
  • The distribution curves' total area under the curve does not change

Activation Energies

  • Activation energy (Ea) is the minimum energy molecules need for a collision to result in a reaction.
  • Activation energy is influenced by reaction nature
  • Adding a catalyst lowers the activation energy required, increasing the reaction rate

Reaction Mechanisms

  • Reaction mechanisms are the steps involved in chemical reactions.
  • Intermediates are formed during the process.
  • The slowest step in the reaction mechanism is known as the rate-determining step, which is the rate limiting step and represents the overall limiting step of the reaction rate
  • Catalysts work by creating alternate pathways with lower activation energy.

Studying That Suits You

Use AI to generate personalized quizzes and flashcards to suit your learning preferences.

Quiz Team

Related Documents

More Like This

Chemistry Reaction Rates Overview
25 questions
Chemical Kinetics Overview
40 questions

Chemical Kinetics Overview

UnlimitedSerpentine7415 avatar
UnlimitedSerpentine7415
Use Quizgecko on...
Browser
Browser