Chemistry Reaction Rates Overview
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Chemistry Reaction Rates Overview

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@MarvelousPascal

Questions and Answers

What 4 main things affect the rate of reaction?

Temperature, concentration, surface area, catalyst (such as enzymes)

How does temperature affect the rate of reaction?

Higher temperatures mean there is more energy therefore the particles move faster and collide more often and more violently.

How does concentration affect the rate of reaction?

Increased concentration of the reactants means there are more particles in the same volume therefore more collisions occur each second.

Why does surface area affect the rate of reaction?

<p>Increased surface area increases the number of particles of the solid in contact with the other reactant in solution increasing the number of particle collisions.</p> Signup and view all the answers

What are catalysts and why do they speed up reactions?

<p>Catalysts are substances that increase the rate of reactions without being used up in the process. Catalysts speed up reactions by providing an alternative pathway with lower activation energy for the reactants.</p> Signup and view all the answers

What is an enzyme and how do they work?

<p>Enzymes are biological catalysts which work best under certain conditions of temperature and pH. Other conditions can lead to them being denatured.</p> Signup and view all the answers

What is activation energy?

<p>The minimum amount of energy needed to break the initial bonds in the reactants for a chemical reaction to take place.</p> Signup and view all the answers

What is a reaction?

<p>When particles react with enough energy and correct orientation for bonds to be broken.</p> Signup and view all the answers

What does a steep gradient in a graph mean?

<p>A fast reaction.</p> Signup and view all the answers

What does a horizontal line on a graph mean?

<p>The reaction has stopped.</p> Signup and view all the answers

What is the rate of reaction?

<p>The speed of a reaction: how fast the products are formed from the reactants.</p> Signup and view all the answers

What is the limiting reagent?

<p>The reactant not in excess that stops the reaction when it is used up.</p> Signup and view all the answers

Give two examples of fast reactions.

<p>Salt dissolving in water and combustion of magnesium.</p> Signup and view all the answers

Give two examples of slow reactions.

<p>Photosynthesis and electrolysis.</p> Signup and view all the answers

What equation is used to calculate the rate of reaction?

<p>Amount of reactant or amount of product divided by time.</p> Signup and view all the answers

What is the balanced symbol equation for the reaction between calcium carbonate and hydrochloric acid and what are the products of the reaction?

<p>CaCO3(s) + 2HCl(aq) -&gt; CaCl2(aq) + H2O(l) + CO2(g)</p> Signup and view all the answers

Describe the disappearing cross reaction to investigate the effect of temperature on rate of reaction in a reaction between hydrochloric acid and sodium thiosulphate solution.

<p>Measure out x amount of hydrochloric acid and leave it in the measuring cylinder. Measure out x amount of sodium thiosulphate solution and pour it into a conical flask, heating it to X degrees with either a Bunsen burner or water bath using a thermometer to measure temperature. When the temperature has reached X, take the flask off the heat and put it onto a piece of paper with an X drawn on it. Pour the acid into the flask and time how long it takes for the X to disappear with a stopwatch. Repeat the investigation at 3 other temperatures to test the rates at different temperatures.</p> Signup and view all the answers

How do you calculate rate?

<p>1/time taken.</p> Signup and view all the answers

How do you convert from Celsius to Kelvin?

<p>Add 273.</p> Signup and view all the answers

What is meant by an exponential relationship?

<p>Rate dramatically increases with temperature.</p> Signup and view all the answers

Why does the rate of reaction increase with temperature?

<p>The particles move faster as they have more energy. This means the frequency of collisions increases. There are more collisions of the correct orientation and amount of activation energy; therefore, more particles possess activation energy and more successful collisions occur.</p> Signup and view all the answers

How do you recover a solid catalyst from a reaction mixture?

<p>Filter the residue and the catalyst will catch in the filter paper - insoluble solid.</p> Signup and view all the answers

What is the best catalyst for decomposing hydrogen peroxide?

<p>Manganese dioxide.</p> Signup and view all the answers

What is the symbol equation for the decomposition of hydrogen peroxide?

<p>2H2O2 -&gt; (MnO2) -&gt; 2H2O + O2.</p> Signup and view all the answers

Why is it important to use catalysts in industry?

<p>To save money as many substances have very high activation energy.</p> Signup and view all the answers

Study Notes

Factors Affecting Reaction Rate

  • Rate of reaction is influenced by temperature, concentration, surface area, and catalysts.

Temperature and Reaction Rate

  • Higher temperatures result in increased particle energy, leading to faster motion and more frequent collisions.

Concentration and Reaction Rate

  • Increased concentration of reactants raises particle number in a given volume, causing more collisions per second.

Surface Area and Reaction Rate

  • Greater surface area enhances contact between solid particles and reactants in solution, increasing collision frequency.

Catalysts

  • Catalysts are substances that accelerate reactions without being consumed, providing alternative pathways with lower activation energy.

Enzymes

  • Enzymes are specific biological catalysts effective under particular temperature and pH conditions; extreme conditions can denature them.

Activation Energy

  • Activation energy is the minimum energy needed to break initial bonds for a chemical reaction to initiate.

Reaction Definition

  • A reaction occurs when particles collide with sufficient energy and proper orientation to break bonds.

Graph Interpretation

  • A steep gradient in a reaction rate graph indicates a fast reaction, while a horizontal line signifies that the reaction has ceased.

Rate of Reaction

  • Rate of reaction measures how quickly products form from reactants.

Limiting Reagent

  • The limiting reagent is the reactant that is used up first, halting the reaction.

Fast Reactions

  • Examples of fast reactions include salt dissolving in water and the combustion of magnesium.

Slow Reactions

  • Examples of slow reactions are photosynthesis and electrolysis.

Calculating Rate of Reaction

  • Rate of reaction can be calculated as the amount of reactant or product divided by time taken.

Balanced Reaction Equation

  • The reaction between calcium carbonate and hydrochloric acid is: CaCO3(s) + 2HCl(aq) -> CaCl2(aq) + H2O(l) + CO2(g)

Disappearing Cross Experiment

  • Investigating temperature effects involves measuring hydrochloric acid and sodium thiosulphate, heating to a target temperature, and timing the disappearance of a marked 'X'.

Rate Calculation

  • Rate can also be calculated as the inverse of time taken (1/time).

Temperature Conversion

  • To convert Celsius to Kelvin, add 273.

Exponential Relationship

  • An exponential relationship indicates that reaction rate significantly increases with temperature.

Temperature Impact on Rate

  • Increased temperature accelerates particle movement, enhancing collision frequency, orientation, and activation energy availability, leading to more successful collisions.

Recovering Solid Catalysts

  • Solid catalysts can be recovered through filtration, where they remain on the filter paper as insoluble solids.

Best Catalyst for Hydrogen Peroxide

  • Manganese dioxide serves as the most effective catalyst for decomposing hydrogen peroxide.

Decomposition of Hydrogen Peroxide Equation

  • The symbolic equation is: 2H2O2 --(MnO2)--> 2H2O + O2.

Industrial Importance of Catalysts

  • Catalysts are vital in industry to reduce costs by lowering the high activation energy required for many reactions.

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Description

This quiz explores the various factors affecting the rate of chemical reactions, including temperature, concentration, surface area, and catalysts. Delve into how each factor plays a crucial role in influencing reaction dynamics and the importance of enzymes in biological processes.

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