Chemistry Reaction Heat Graph

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Questions and Answers

Before the equivalence point, the reaction involving HNO₃ is considered ______.

exothermic

As more HNO₃ is added before the equivalence point, the temperature ______.

increases

After the equivalence point, the addition of HNO₃ results in a ______ of temperature.

decrease

The cooling effect decreases as the temperature difference between HNO₃ and the reaction ______ decreases.

<p>mixture</p> Signup and view all the answers

A constant amount of heat energy released with each additional volume of HNO₃ causes a smaller ______ increase.

<p>temperature</p> Signup and view all the answers

Fill a ______ burette with HNO₃.

<p>50.00 cm³</p> Signup and view all the answers

Use a 25.0 cm³ ______ to transfer the Ba(OH)₂ solution.

<p>pipette</p> Signup and view all the answers

Record the ______ temperature of the mixture after adding HNO₃.

<p>maximum</p> Signup and view all the answers

Place the lid with a hole for the ______ on the Styrofoam cup.

<p>thermometer</p> Signup and view all the answers

The equivalence point is indicated when the maximum temperature stops ______.

<p>rising</p> Signup and view all the answers

The objective of the experiment is to determine the volume of HNO₃ required for ______.

<p>neutralization</p> Signup and view all the answers

The volume of Ba(OH)₂ used in the experiment is ______.

<p>25.0 cm³</p> Signup and view all the answers

Each addition of HNO₃ is ______ cm³.

<p>5.00</p> Signup and view all the answers

To analyze the data, a graph is plotted with the maximum temperature on the y-axis and the total volume of HNO₃ on the ______.

<p>x-axis</p> Signup and view all the answers

It is important to ensure the bulb of the thermometer is immersed at least ______ cm³ in the solution.

<p>20</p> Signup and view all the answers

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Study Notes

Graph Shape

  • The graph shows the temperature change of the reaction mixture as HNO₃ is added.
  • Before the equivalence point, the temperature increases.
  • The increase in temperature is due to the exothermic reaction between HNO₃ and Ba(OH)₂.
  • Each addition of HNO₃ releases a constant amount of heat energy.
  • The temperature increase becomes smaller as more HNO₃ is added because the total volume of the mixture increases.
  • After the equivalence point, the temperature decreases.
  • This decrease is because the reaction is complete and no more heat is produced.
  • The HNO₃ added is at a lower temperature than the reaction mixture.

Experiment Outline

  • The experiment determines the volume of HNO₃ required for neutralization.
  • The materials needed include a thermometer, Ba(OH)₂ solution, and HNO₃ solution.
  • The experiment involves plotting a graph of maximum temperature versus total HNO₃ volume.
  • Two trend lines are drawn, one for increasing temperature and one for decreasing temperature.
  • The point where the two lines intersect indicates the volume of HNO₃ required for neutralization.
  • The maximum temperature reached is also recorded.

Procedure for Determining The Equivalence Point

  • The experiment involves using a burette to add HNO₃ to a solution of Ba(OH)₂.
  • The temperature of the mixture is monitored using a thermometer placed in a lid with a hole.
  • The procedure involves adding 5.00 cm³ of HNO₃ at a time and recording the maximum temperature reached after each addition.
  • The equivalence point is reached when the maximum temperature stops rising, indicating that all of the Ba(OH)₂ has reacted with the HNO₃.

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