CH 15: Rates of reaction and factors affecting rate
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Questions and Answers

Which of the following factors can increase the rate of a chemical reaction?

  • Reducing the surface area of the reactants
  • Removing the catalyst from the reaction system
  • Decreasing the temperature of the reaction mixture
  • Increasing the concentration or pressure of reactants (correct)
  • According to the collision theory, which condition is necessary for a chemical reaction to occur?

  • Reactant particles collide with sufficient energy and correct orientation (correct)
  • Reactant particles collide with insufficient energy but correct orientation
  • Reactant particles collide with any amount of energy
  • Reactant particles collide in any orientation
  • Which type of reaction releases energy to the surroundings, typically increasing the temperature?

  • Endothermic reaction
  • Exothermic reaction (correct)
  • Activation energy reaction
  • Catalyst-induced reaction
  • What is the minimum energy barrier that must be overcome for reactants to transform into products?

    <p>Activation energy</p> Signup and view all the answers

    Which experimental technique is useful for measuring the rate of a reaction that produces a gas as a product?

    <p>Measuring the volume of gas evolved</p> Signup and view all the answers

    What is the role of a catalyst in a chemical reaction?

    <p>To lower the activation energy required for the reaction</p> Signup and view all the answers

    Which experimental technique is suitable for monitoring the change in concentration of reactants or products?

    <p>All of the above</p> Signup and view all the answers

    Which type of reaction absorbs energy from the surroundings, resulting in a temperature decrease around the reaction site?

    <p>Endothermic reaction</p> Signup and view all the answers

    Which experimental technique is suitable for reactions involving a gaseous reactant or product that allows for mass change?

    <p>Observing changes in mass</p> Signup and view all the answers

    Which of the following factors can decrease the rate of a chemical reaction?

    <p>Decreasing the temperature of the reaction mixture</p> Signup and view all the answers

    What does the reaction rate quantify in chemistry?

    <p>The change in concentration of reactants or products over time</p> Signup and view all the answers

    How is the rate of reaction for reactants expressed mathematically?

    <p>$\text{Rate} = -\frac{\Delta[\text{Reactants}]}{\Delta t}$ (units: mol·dm⁻³·s⁻¹)</p> Signup and view all the answers

    Which factor affects the reaction rate by increasing the probability of particle collisions?

    <p>Surface Area</p> Signup and view all the answers

    What does the negative sign in the rate expression for reactants indicate?

    <p>A decrease in concentration over time</p> Signup and view all the answers

    Why does increasing the surface area of reactants enhance the reaction rate?

    <p>It increases the probability of particle collisions</p> Signup and view all the answers

    Which factor influences how quickly reactions proceed based on the chemical nature of substances involved?

    <p>Ionic vs. Covalent nature</p> Signup and view all the answers

    In chemical reactions, what does the product rate expression indicate?

    <p>$\text{Rate} = \frac{\Delta[\text{Products}]}{\Delta t}$ (units: mol·dm⁻³·s⁻¹)</p> Signup and view all the answers

    How do reactants and products differ in their rate expressions?

    <p>Reactants have a negative sign, while products don't</p> Signup and view all the answers

    'Nature of Reacting Substances' affecting the reaction rate refers to what aspect?

    <p>'Nature of Reacting' refers to the chemical nature of substances (e.g., ionic vs. covalent)</p> Signup and view all the answers

    'Surface Area' plays a significant role in enhancing reaction rates due to what factor?

    <p>'Surface Area' increases the chance of particle collisions</p> Signup and view all the answers

    Which mathematical expression correctly represents the rate of reaction for products?

    <p>$Rate = \frac{\Delta[Products]}{\Delta t}$</p> Signup and view all the answers

    If the surface area of solid reactants is increased, how will the reaction rate be affected?

    <p>The reaction rate will increase due to a higher probability of particle collisions.</p> Signup and view all the answers

    Which factor primarily influences the reaction rate based on the chemical nature of the reacting substances?

    <p>The ionic or covalent character of the bonds</p> Signup and view all the answers

    What does the negative sign in the rate expression for reactants indicate?

    <p>The reactants are being consumed during the reaction.</p> Signup and view all the answers

    If the rate of a chemical reaction is expressed as $Rate = \frac{\Delta[Products]}{\Delta t}$, what does the rate represent?

    <p>The rate at which products are formed</p> Signup and view all the answers

    Which factor would likely decrease the rate of a chemical reaction?

    <p>Decreasing the temperature of the reaction mixture</p> Signup and view all the answers

    If the rate of a chemical reaction is expressed as $Rate = -\frac{\Delta[Reactants]}{\Delta t}$, what does the rate represent?

    <p>The rate at which reactants are consumed</p> Signup and view all the answers

    Which experimental technique would be suitable for monitoring the rate of a reaction involving a gaseous product?

    <p>Measuring the change in volume over time</p> Signup and view all the answers

    Which statement is true regarding the effect of surface area on reaction rates?

    <p>Increasing the surface area of reactants increases the reaction rate due to a higher probability of particle collisions.</p> Signup and view all the answers

    Which factor primarily influences the reaction rate based on the chemical nature of the reacting substances?

    <p>The ionic or covalent character of the bonds</p> Signup and view all the answers

    What effect does increasing the temperature typically have on a chemical reaction?

    <p>Increases the reaction rate by providing more energy to reactant particles</p> Signup and view all the answers

    How do catalysts affect the activation energy required for a reaction?

    <p>Lower the activation energy barrier</p> Signup and view all the answers

    Which factor plays a crucial role in explaining why increasing temperature or concentration can increase reaction rates?

    <p>Correct orientation and collision energy of reactant particles</p> Signup and view all the answers

    In which type of reaction is energy absorbed from the surroundings, resulting in a temperature decrease at the reaction site?

    <p>Endothermic reactions</p> Signup and view all the answers

    What does the concept of activation energy represent in chemical reactions?

    <p>Minimum energy barrier for reactants to turn into products</p> Signup and view all the answers

    Which experimental approach is suitable for observing changes in color or turbidity as an indicator of reaction progress?

    <p>Observing color or turbidity changes</p> Signup and view all the answers

    In exothermic reactions, what happens to energy during the process?

    <p>Emission of energy from reactants to surroundings</p> Signup and view all the answers

    What effect does an increase in concentration have on reaction rates?

    <p>Increases reaction rates by boosting collision frequency</p> Signup and view all the answers

    What does the negative sign in the rate expression for reactants signify?

    <p>A decrease in concentration over time</p> Signup and view all the answers

    How does increasing the surface area of reactants impact the reaction rate?

    <p>Increases the reaction rate due to higher probability of particle collisions</p> Signup and view all the answers

    In chemical reactions, what does the product rate expression indicate?

    <p>Increase in product concentration over time</p> Signup and view all the answers

    Which factor primarily influences the rate of chemical reactions based on the chemical nature of the reacting substances?

    <p>Nature of Reacting Substances</p> Signup and view all the answers

    What is the role of a catalyst in a chemical reaction?

    <p>Decreases the activation energy needed for the reaction</p> Signup and view all the answers

    How can the reaction rate be mathematically expressed for products?

    <p>$Rate = rac{ ext{Change in Products}}{ ext{Change in Time}}$</p> Signup and view all the answers

    According to the passage, which of the following is the primary reason that increasing the temperature typically increases the reaction rate?

    <p>It provides more energy to reactant particles, increasing their kinetic energy and the number of effective collisions.</p> Signup and view all the answers

    Based on the information in the passage, what is the primary role of a catalyst in a chemical reaction?

    <p>Catalysts lower the activation energy required for the reaction.</p> Signup and view all the answers

    According to the collision theory described in the passage, which of the following conditions is necessary for a chemical reaction to occur?

    <p>The reactant particles must collide with sufficient energy (greater than or equal to the activation energy) and in the correct orientation.</p> Signup and view all the answers

    Which of the following experimental techniques would be most suitable for measuring the rate of a reaction that produces a gaseous product?

    <p>Measuring the volume of gas evolved.</p> Signup and view all the answers

    What does the negative sign in the rate expression $Rate = -rac{\Delta[Reactants]}{\Delta t}$ indicate?

    <p>The concentration of the reactants is decreasing over time.</p> Signup and view all the answers

    Which type of chemical reaction, as described in the passage, absorbs energy from the surroundings and results in a temperature decrease around the reaction site?

    <p>Endothermic reactions</p> Signup and view all the answers

    How does the passage describe the relationship between the rate of reaction for reactants and the rate of reaction for products?

    <p>The rate of reaction for reactants and products are inversely proportional.</p> Signup and view all the answers

    Which of the following factors, according to the passage, is the primary influence on the reaction rate based on the chemical nature of the reacting substances?

    <p>The activation energy required for the reaction.</p> Signup and view all the answers

    What does the concept of activation energy, as described in the passage, represent in chemical reactions?

    <p>The minimum energy barrier that must be overcome for reactants to transform into products.</p> Signup and view all the answers

    Which experimental technique described in the passage would be most suitable for observing changes in color or turbidity as an indicator of reaction progress?

    <p>Monitoring the change in concentration of reactants or products using titration, spectroscopy, or chromatography.</p> Signup and view all the answers

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