Chemistry Quiz: Oxidation States and Bonding

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Questions and Answers

What is the process by which Pb$^{4+}$ converts to Pb$^{2+}$?

  • Oxidation
  • Ionization
  • Reduction (correct)
  • Decomposition

Pb$^{4+}$ has a high association with anions like I$^{-}$.

False (B)

What type of metals are most electropositive?

Alkali and alkaline earth metals

As the oxidation state increases, the electronegativity __________.

<p>increases</p> Signup and view all the answers

What happens to the metallic character as one moves across a period?

<p>Decreases (C)</p> Signup and view all the answers

Match the following cations to their oxidation states:

<p>Pb$^{4+}$ = Higher oxidation state Sn$^{2+}$ = Lower oxidation state Sn$^{4+}$ = Higher oxidation state Pb$^{2+}$ = Lower oxidation state</p> Signup and view all the answers

The electropositive character of halogens is the highest in their group.

<p>False (B)</p> Signup and view all the answers

Electron gain enthalpy __________ down a group.

<p>decreases</p> Signup and view all the answers

What is the bond order of carbon monoxide (CO)?

<p>3 (D)</p> Signup and view all the answers

Nitric oxide (NO) has no unpaired electrons, making it diamagnetic.

<p>False (B)</p> Signup and view all the answers

Which group of elements exhibits a decrease in electron gain enthalpy down the group?

<p>Halogens</p> Signup and view all the answers

What is the relationship between ionic character and melting point?

<p>Higher ionic character results in a higher melting point.</p> Signup and view all the answers

The Lewis structure of carbon monoxide (CO) is represented as O = C = O, and it is ________ in nature.

<p>diamagnetic</p> Signup and view all the answers

Match the following properties with their respective molecules:

<p>NO = Paramagnetic due to unpaired electron CO = Diamagnetic with bond order of 3 Covalent character = Depends on charge and size of ions Fajan's rule = Describes covalent character in ionic bonds</p> Signup and view all the answers

Which of the following statements is true regarding second period elements like nitrogen and carbon?

<p>They cannot form more than four bonds. (A)</p> Signup and view all the answers

The first ionization energy is always greater than the second ionization energy.

<p>False (B)</p> Signup and view all the answers

What is the maximum valency of sulfur (S)?

<p>6</p> Signup and view all the answers

After losing one electron, sodium ion (Na+) achieves ______ configuration.

<p>noble gas</p> Signup and view all the answers

Why is the removal of an electron from a unipositive cation difficult?

<p>Strong electrostatic attractive forces (D)</p> Signup and view all the answers

Elements in the third period can form more than four bonds.

<p>True (A)</p> Signup and view all the answers

What is the trend in ionization energy as more electrons are removed from an atom?

<p>Ionization energy increases.</p> Signup and view all the answers

In the molecule BF, the bond length between boron and fluorine can be predicted to be ______.

<p>observed B-F bond length</p> Signup and view all the answers

Which element has a +2 oxidation state as the most stable?

<p>Barium (D)</p> Signup and view all the answers

Match the following elements to their electron configuration outcomes after losing an electron:

<p>Sodium (Na) = Noble gas configuration Nitrogen (N) = More difficult to ionize Sulfur (S) = Maximum valency of 6 Carbon (C) = Cannot expand octet</p> Signup and view all the answers

What is the maximum atomic number for element M?

<p>20 (D)</p> Signup and view all the answers

Element M has d-orbital electrons.

<p>False (B)</p> Signup and view all the answers

What is the hybridization present in a molecule with three sigma bonds?

<p>sp</p> Signup and view all the answers

The electronic configuration for an atom with atomic number 21 is [Ar]3s _____ 3p _____ .

<p>2, 1</p> Signup and view all the answers

Match the following molecules with their characteristics:

<p>[TeBr6] = Contains d-orbital electrons [BrF2] = Is non-polar SNF3 = Has a symmetrical geometry [XeF3]- = Has an atomic number greater than 21</p> Signup and view all the answers

Which of the following statements is true about the molecule MX?

<p>It has three sigma bonds. (A)</p> Signup and view all the answers

The molecule having a zero dipole moment indicates that it has asymmetrical geometry.

<p>False (B)</p> Signup and view all the answers

What implies that the molecule MX has a symmetrical geometry?

<p>Zero dipole moment</p> Signup and view all the answers

The element M has a maximum of ____ electrons.

<p>20</p> Signup and view all the answers

Which type of arrangement is possible for sp hybridization?

<p>Triagonal planar (D)</p> Signup and view all the answers

Which of the following statements accurately describes the relationship between E1 and E2?

<p>E1 &lt; E2 (B)</p> Signup and view all the answers

The energy required to pull out the second electron E2 is less than the energy required to pull out the first electron E1.

<p>False (B)</p> Signup and view all the answers

Identify the least reactive non-metal based on the given energy information.

<p>The least reactive non-metal is A.</p> Signup and view all the answers

In increasing order of their sizes, the sequence for the ions is Mg 2+ > Na + > F - > O 2- < ______.

<p>N 3-</p> Signup and view all the answers

Match the ions with their respective charges:

<p>N 3- = Negative three charge Na + = Positive one charge F - = Negative one charge Mg 2+ = Positive two charge O 2- = Negative two charge</p> Signup and view all the answers

Which energy value corresponds to the highest energy requirement for electron removal?

<p>3374 (B)</p> Signup and view all the answers

E1 is observed to be equal to E2 in all cases for the given elements.

<p>False (B)</p> Signup and view all the answers

Flashcards

Ionization Energy

The energy required to remove an electron from an atom in its gaseous state. This energy is a measure of how tightly the electron is held by the atom.

Ionization

The process of losing an electron from an atom or molecule, resulting in the formation of a positively charged ion (cation).

First Ionization Energy (E1)

The energy required to remove the first electron from an atom in its gaseous state.

Second Ionization Energy (E2)

The energy required to remove the second electron from an atom in its gaseous state, after the first electron has already been removed.

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Electron Affinity

The process where an atom gains an electron resulting in the formation of a negatively charged ion (anion).

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Electronegativity

The ability of an atom to attract a bonding pair of electrons. It is a measure of the atom's electronegativity.

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Ionic Size

The size of an ion. This is determined by the number of electron shells and the number of protons in the nucleus.

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Orbital Overlap Restriction

Two opposite symmetry orbitals in a molecule cannot overlap. This occurs because of the different spatial arrangements of electrons in the orbitals.

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Paramagnetism

The presence of unpaired electrons in a molecule makes it paramagnetic, meaning it is attracted to a magnetic field.

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Diamagnetism

A molecule with all paired electrons is diamagnetic and is not attracted to a magnetic field.

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Ionic Character and Melting Point

The strength of the attraction between oppositely charged ions in an ionic compound influences its melting point. Higher ionic character leads to stronger attraction and a higher melting point.

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Fajan's Rule

Fajan's rule describes the extent of covalent character in an ionic bond. This character increases with the size of the cation and the charge of the anion.

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Electropositivity

The tendency of an element to lose electrons and form positive ions.

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Electropositive Elements

Elements in the periodic table that have the tendency to lose electrons easily.

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Electronegative Elements

The tendency of an element to gain electrons and form negative ions.

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Metallic Character

Metals typically have low ionization energies and high electropositivity.

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E2 > E1

Second ionization energy is always greater than the first ionization energy.

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Second Period Octet Rule

Elements in the second period (Li to Ne) cannot expand their octet beyond 8 electrons.

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Third Period Octet Expansion

Elements in the third period (Na to Ar) and beyond can form more than four bonds due to the presence of vacant d-orbitals.

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Formal Charge

The formal charge on an atom in a molecule is the difference between the number of valence electrons in a free atom and the number of electrons assigned to that atom in the Lewis structure.

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Coordination Complex

A central atom surrounded by ligands. The central atom can be a metal or a non-metal.

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Ligands

The atoms or molecules that are directly bonded to the central atom in a coordination complex.

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Coordination Number

The number of bonds that a central atom forms with its ligands in a coordination complex.

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Charge of a Coordination Complex

The overall charge of a coordination complex.

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Coordination Geometry

In a coordination complex, the geometry is determined by the spatial arrangement of ligands around the central atom.

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Central Metal Atom

The central metal atom in a coordination complex is the atom to which the ligands are attached.

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Oxidation State of the Central Metal Atom

The central atom in a coordination complex can have a specific oxidation state, which indicates its charge.

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Monodentate and Bidentate Ligands

Ligands can be classified based on their ability to donate one or more electron pairs to the central metal atom. Monodentate ligands donate one electron pair, and bidentate ligands donate two.

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Ligand Field Theory

The theory that explains how ligands form coordinate covalent bonds with the central atom.

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Homoleptic Complex

A complex in which the central metal atom is surrounded by only one type of ligand.

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